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Chemistry Test - 27

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Chemistry Test - 27
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  • Question 1
    1 / -0

    Which has least melting point?

    Solution

    \(\begin{array}{cccc} & L i & N a & K \\ \text { Melting point }\left({ }^{0} C\right) & 180 & 98 & 64\end{array}\)
    Hence, the correct option is (C)

  • Question 2
    1 / -0

    Which of the following will have the largest size in water?

    Solution

    Among the given ions, Li+ ion has the maximum charge density due to its small ionic size. Hence, it undergoes hydration to maximum extent. Thus, the size of hydrated Li+ ion is the maximum among the given ions.

    Small size has high hydration energy.
    Hence, the correct option is (D)

  • Question 3
    1 / -0

    Decreasing order of enol content of the following compounds in liquid/solution phase is:

     

    Solution

    The correct order is, 1>2>3>4. As phenol is aromatic (100% enol), then 2 will have a higher enol content because of acidic hydrogen.

    Then 3 and 4. 4 is the least enolic due to higher stability of ketone.
    Hence, the correct option is (B)

  • Question 4
    1 / -0

    How many optically active stereoisomers are possible for butan-2, 3-diol?

    Solution

    The number of optically active stereoisomers possible for 2,3−diol2,3−diol is 2. They are d,l isomers which are optically active. The meso- compound is optically inactive due to internal compensation. Hence, option B is correct.

  • Question 5
    1 / -0

    During estimation of nitrogen in the organic compound by Kjeldahls method, the ammonia evolved from 0.5 g of the compound in Kjeldahls estimation of nitrogen, neutralised 10 mL of 1M H2SO4. Find out the percentage of nitrogen in the compound.

    Solution

    In Kjeldahls method,

    1M of 10ml H2SO4 gives 1M of 20 ml NH3

    For 1000 ml of 1M NH3 contains 14g of nitrogen gas

    For 20 ml of 1M NH3 contains (14/1000)×20g=0.28g of nitrogen gas

    Percentage of nitrogen will be (0.28/0.5)×100=56%
    Hence, the correct option is (C)

  • Question 6
    1 / -0

    PhCOOH and PhCH3 can be separated by:

    Solution

    PhCOOH dissolves in aq.NaHCO3solution but toluene is not soluble in aq. NaHCO3 but dissolves in n-hexane.
    Hence, the correct option is (B)

  • Question 7
    1 / -0

    Zeolite used to soften hardness of water is , hydrated :

    Solution

    Zeolites are complex inorganic salts like hydrated sodium aluminium silicates, Na2Al2Si2O8, which are used to remove the hardness of water.
    Hence, the correct option is (B)

  • Question 8
    1 / -0

    Itching causing ______ crystals are found in colocasia leaves.

    Solution

    Itching causing calcium oxalate crystals are found in colocasia leaves. Some varieties of raw or uncooked taro contain tiny crystals of a substance called calcium oxalate which causes itching. If taro is properly cooked, itching can be avoided.
    Hence, the correct option is (B)

  • Question 9
    1 / -0

    The process which is employed to separate the ingredients of the mixture of two miscible liquids differing in their boiling points is:

    Solution

    Fractional distillation is the separation of a mixture into its component parts, or fractions, separating chemical compounds by their boiling point by heating them to a temperature at which one or more fractions of the compound will vaporize.
    Hence, the correct option is (A)

  • Question 10
    1 / -0

    When solution of sodium chloride containing ethyl alcohol is electrolysed, it finally forms :

    Solution

    Sodium chloride on electrolysis produces chlorine and chlorine oxidizes ethyl alcohol to acetaldehyde.

    2NaCl→2Na+Cl2

    CH3CH2OH+Cl2→CH3CHO+2HCl
    Hence, the correct option is (D)

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