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Some Basic Concepts of Chemistry Test - 75

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Some Basic Concepts of Chemistry Test - 75
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  • Question 1
    1 / -0
    3g3 g of activated charcoal was added to 50mL50 mL of acetic acid solution (0.06N0.06 N) in a flask. After an hour it was filtered and the strength of the filtrate was found to be 0.042N0.042 N. The amount of acetic acid absorbed (per gram of charcoal) is ?
    Solution

    Given:

    The initial mass of charcoal=3g = 3g

    Vol. of acetic acid =50mL50mL  Normality=0.06N = 0.06N

    Strength of filtrate after reaction=0.042N = 0.042N

    We know,

    Molarity of acetic acid soln=Wt/MVol of soln = \cfrac{{Wt/M}}{{Vol\ of\ so{l^n}}}

    Wt=0.06×60×0.05=0.180g \Rightarrow Wt = 0.06 \times 60 \times 0.05 = 0.180g

    Also, normality after reaction, 0.042=W60×0.050.042 = \cfrac{W}{{60 \times 0.05}}

    W=0.126gW = 0.126g

    Change in mass=0.1800.126=0.054g=54mg = 0.180 - 0.126 = 0.054g = 54mg

    Amount of charcoal available=3g = 3g

    Amount of acetic acid absorbed =54mg3.0g×1.0g=18g = \cfrac{{54mg}}{{3.0g}} \times 1.0g = 18g

    Correct option is A.

  • Question 2
    1 / -0
    A substance contains 3.4%SS. if it contain two atom of sulphur per molecule then minimum molecular weight of substance will be:
    Solution
    According to question-
    3.4gS=100g3.4g S=100g insulin
     32g S=100×323.4\therefore  32g\ S= \dfrac{100\times 32}{3.4}
    941.176\Rightarrow 941.176
    For two atoms of SS
    941.176×2=1882.4\Rightarrow 941.176\times 2 = 1882.4

    Here correct unit is 18882.410=188.2\dfrac{18882.4}{10}=188.2
    Insulin must contain at least Two atom of S in its one molecule.
    Hence (A)(A) is the correct answer.
  • Question 3
    1 / -0
    The number of H3O+H_{3}O^{+} ions present in 10ml of water at 25C25^{\circ}C is:
    Solution
    No. of hydronium ions present in 1010ml water at 250C{ 25 }^{ 0 }C.

    pH=7pH=7 at 250C{ 25 }^{ 0 }C

    [H+]=107M\left[ { H }^{ + } \right] ={ 10 }^{ -7 }M

    No. of moles == Concentration ×\times Volume

                          =(107)(10)×103=\left( { 10 }^{ -7 } \right) \left( 10 \right) \times { 10 }^{ -3 }

                          =109={ 10 }^{ -9 }moles

    1 mole has 6.023×10236.023\times { 10 }^{ 23 } ions of hydronium.

    6.023×1023×109\Rightarrow \quad 6.023\times { 10 }^{ 23 }\times { 10 }^{ -9 } ions in 1010ml water

    6.023×1014\Rightarrow 6.023\times { 10 }^{ 14 } ions are there in 1010ml water at 250C{ 25 }^{ 0 }C.

    Hence, option B is correct.
  • Question 4
    1 / -0
    The volume of 0.1 M H2SO40.1\ M\ H_2SO_4 required to neutralize 30 mL of 2.0 M NaOH2.0\ M\ NaOH is:
    Solution
    Solution:- (B) 300  mL300 \; mL
    Let VV be the volume of H2SO4{H}_{2}S{O}_{4} required.
    Given:-
    MH2SO4=0.1M{M}_{{H}_{2}S{O}_{4}} = 0.1 M
    MNaOH=2M{M}_{NaOH} = 2 M
    VNaOH=30  mL{V}_{NaOH} = 30 \; mL
    Now, as we know that
    N1V1=N2V2{N}_{1} {V}_{1} = {N}_{2} {V}_{2}
    N=n×M\because N = n \times M
    Whereas nn is the valence factor
    Therefore,
    n1M1V1=n2M2V2{n}_{1} {M}_{1} {V}_{1} = {n}_{2} {M}_{2} {V}_{2}
    For H2SO4;  n=2{H}_{2}S{O}_{4}; \; n = 2
    For NaOH;  n=1NaOH; \; n = 1
    Therefore,
    2×0.1×V=1×2×302 \times 0.1 \times V = 1 \times 2 \times 30
    V=600.2\Rightarrow V = \cfrac{60}{0.2}
    V=300  mL\Rightarrow V = 300 \; mL
    Hence 300  mL300 \; mL of H2SO4{H}_{2}S{O}_{4} is required to neutralize 30  mL30 \; mL of 2M  NaOH2 M \; NaOH.
  • Question 5
    1 / -0
    Two oxide of metal contain 27.6% and 30% oxygen respectively. If the formula of first oxide is M3O4M_3O_4 then formula of second oxide is -
  • Question 6
    1 / -0
    81gm81gm mixture of MgCO3(s)MgC{O_3}\left( s \right) NH2COONH4(s)N{H_2}COON{H_4}\left( s \right) in equimolar ratio is heated in open to constant mass. If vapour density of gaseous mixture evolved was found to be 614\cfrac{61}{4}, then find the mole % of MgCO3MgCO_3 in original sample.

    Given that: MgCO3(s)ΔMgO(s)+CO2(g)MgC{O_3}\left( s \right)\xrightarrow{\Delta }MgO\left( s \right) + C{O_2}\left( g \right) 

    H2COONH4(s)Δ2NH3(g)+CO2(g)N{H_2}COON{H_4}\left( s \right)\xrightarrow{\Delta }2N{H_3}\left( g \right) + C{O_2}\left( g \right)N
  • Question 7
    1 / -0
    Substance
    Boiling point (0C){ ( }^{ 0 }C)
    Melting point (0C){ ( }^{ 0 }C)
    A-183-219
    B445119
    C78-15

    Point out the physical states of A, B, and C at room temperature (300C)({ 30 }^{ 0 }C).
    Solution
    (i)(i) If Boiling point >> Room Temperature >> Melting Point
    Then the physical state is liquid.

    (ii)(ii) If Room temperature >> Boiling point
    Then the physical state is gas.

    (iii)(iii) If Room temperature << Melting point
    Then the physical state is solid.

    Therefore, 
    for AA\Rightarrow Physical state is gas.
    For BB\Rightarrow Physical state is solid.
    For CC\Rightarrow Physical state is liquid.
  • Question 8
    1 / -0
    A mixture of C2H2{ C }_{ 2 }{ H }_{ 2 } AND  C3H8{ C }_{ 3 }{ H }_{ 8 } occupied a certain volume at 80 mm Hg . The mixture wsa completely burnt to CO2{ CO }_{ 2 } and H2O{ H }_{ 2 }O (l). When the pressure of CO2{ CO }_{ 2 } was found to be 230 mm Hg at the same temperature and volume, the mole fraction of C3H8{ C }_{ 3 }{ H }_{ 8 }  in the mixture is 
    Solution

  • Question 9
    1 / -0
    Vapour density of the equilibrium mixture of NO2NO_2 and N2O4N_2O_4 is found to be 4040 for the equilibrium. Calculate percentage of NO2NO_2 in the mixture:  N2O42NO2N_2O_4 \leftrightharpoons 2 NO_2
    Solution

  • Question 10
    1 / -0
    0.1 g of a solution containing Na2{ Na }_{ 2 } Co3 { Co }_{ 3 } and NaHCO3{ NaHCO }_{ 3 } requires 10 mL of 0.01 N HCl for neutralization using phenolphthalein as an indicator.Wt.% of  Na2{ Na }_{ 2 } Co3 { Co }_{ 3 } in the mixture is
    Solution

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