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Some Basic Concepts of Chemistry Test - 75

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Some Basic Concepts of Chemistry Test - 75
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  • Question 1
    1 / -0
    $$3 g$$ of activated charcoal was added to $$50 mL$$ of acetic acid solution ($$0.06 N$$) in a flask. After an hour it was filtered and the strength of the filtrate was found to be $$0.042 N$$. The amount of acetic acid absorbed (per gram of charcoal) is ?
    Solution

    Given:

    The initial mass of charcoal$$ = 3g$$

    Vol. of acetic acid =$$50mL$$  Normality$$ = 0.06N$$

    Strength of filtrate after reaction$$ = 0.042N$$

    We know,

    Molarity of acetic acid soln$$ = \cfrac{{Wt/M}}{{Vol\ of\ so{l^n}}}$$

    $$ \Rightarrow Wt = 0.06 \times 60 \times 0.05 = 0.180g$$

    Also, normality after reaction, $$0.042 = \cfrac{W}{{60 \times 0.05}}$$

    $$W = 0.126g$$

    Change in mass$$ = 0.180 - 0.126 = 0.054g = 54mg$$

    Amount of charcoal available$$ = 3g$$

    Amount of acetic acid absorbed $$ = \cfrac{{54mg}}{{3.0g}} \times 1.0g = 18g$$

    Correct option is A.

  • Question 2
    1 / -0
    A substance contains 3.4%$$S$$. if it contain two atom of sulphur per molecule then minimum molecular weight of substance will be:
    Solution
    According to question-
    $$3.4g S=100g$$ insulin
    $$\therefore  32g\ S= \dfrac{100\times 32}{3.4}$$
    $$\Rightarrow 941.176$$
    For two atoms of $$S$$
    $$\Rightarrow 941.176\times 2 = 1882.4$$

    Here correct unit is $$\dfrac{18882.4}{10}=188.2$$
    Insulin must contain at least Two atom of S in its one molecule.
    Hence $$(A)$$ is the correct answer.
  • Question 3
    1 / -0
    The number of $$H_{3}O^{+}$$ ions present in 10ml of water at $$25^{\circ}C$$ is:
    Solution
    No. of hydronium ions present in $$10$$ml water at $${ 25 }^{ 0 }C$$.

    $$pH=7$$ at $${ 25 }^{ 0 }C$$

    $$\left[ { H }^{ + } \right] ={ 10 }^{ -7 }M$$

    No. of moles $$=$$ Concentration $$\times$$ Volume

                          $$=\left( { 10 }^{ -7 } \right) \left( 10 \right) \times { 10 }^{ -3 }$$

                          $$={ 10 }^{ -9 }$$moles

    1 mole has $$6.023\times { 10 }^{ 23 }$$ ions of hydronium.

    $$\Rightarrow \quad 6.023\times { 10 }^{ 23 }\times { 10 }^{ -9 }$$ ions in $$10$$ml water

    $$\Rightarrow 6.023\times { 10 }^{ 14 }$$ ions are there in $$10$$ml water at $${ 25 }^{ 0 }C$$.

    Hence, option B is correct.
  • Question 4
    1 / -0
    The volume of $$0.1\ M\ H_2SO_4$$ required to neutralize 30 mL of $$2.0\ M\ NaOH$$ is:
    Solution
    Solution:- (B) $$300 \; mL$$
    Let $$V$$ be the volume of $${H}_{2}S{O}_{4}$$ required.
    Given:-
    $${M}_{{H}_{2}S{O}_{4}} = 0.1 M$$
    $${M}_{NaOH} = 2 M$$
    $${V}_{NaOH} = 30 \; mL$$
    Now, as we know that
    $${N}_{1} {V}_{1} = {N}_{2} {V}_{2}$$
    $$\because N = n \times M$$
    Whereas $$n$$ is the valence factor
    Therefore,
    $${n}_{1} {M}_{1} {V}_{1} = {n}_{2} {M}_{2} {V}_{2}$$
    For $${H}_{2}S{O}_{4}; \; n = 2$$
    For $$NaOH; \; n = 1$$
    Therefore,
    $$2 \times 0.1 \times V = 1 \times 2 \times 30$$
    $$\Rightarrow V = \cfrac{60}{0.2}$$
    $$\Rightarrow V = 300 \; mL$$
    Hence $$300 \; mL$$ of $${H}_{2}S{O}_{4}$$ is required to neutralize $$30 \; mL$$ of $$2 M \; NaOH$$.
  • Question 5
    1 / -0
    Two oxide of metal contain 27.6% and 30% oxygen respectively. If the formula of first oxide is $$M_3O_4 $$ then formula of second oxide is -
  • Question 6
    1 / -0
    $$81gm$$ mixture of $$MgC{O_3}\left( s \right)$$ $$N{H_2}COON{H_4}\left( s \right)$$ in equimolar ratio is heated in open to constant mass. If vapour density of gaseous mixture evolved was found to be $$\cfrac{61}{4}$$, then find the mole % of $$MgCO_3$$ in original sample.

    Given that: $$MgC{O_3}\left( s \right)\xrightarrow{\Delta }MgO\left( s \right) + C{O_2}\left( g \right)$$ 

    $${H_2}COON{H_4}\left( s \right)\xrightarrow{\Delta }2N{H_3}\left( g \right) + C{O_2}\left( g \right)N$$
  • Question 7
    1 / -0
    Substance
    Boiling point $${ ( }^{ 0 }C)$$
    Melting point $${ ( }^{ 0 }C)$$
    A-183-219
    B445119
    C78-15

    Point out the physical states of A, B, and C at room temperature $$({ 30 }^{ 0 }C)$$.
    Solution
    $$(i)$$ If Boiling point $$>$$ Room Temperature $$>$$ Melting Point
    Then the physical state is liquid.

    $$(ii)$$ If Room temperature $$>$$ Boiling point
    Then the physical state is gas.

    $$(iii)$$ If Room temperature $$<$$ Melting point
    Then the physical state is solid.

    Therefore, 
    for $$A\Rightarrow$$ Physical state is gas.
    For $$B\Rightarrow$$ Physical state is solid.
    For $$C\Rightarrow$$ Physical state is liquid.
  • Question 8
    1 / -0
    A mixture of $${ C }_{ 2 }{ H }_{ 2 }$$ AND  $${ C }_{ 3 }{ H }_{ 8 }$$ occupied a certain volume at 80 mm Hg . The mixture wsa completely burnt to $${ CO }_{ 2 }$$ and $${ H }_{ 2 }O$$ (l). When the pressure of $${ CO }_{ 2 }$$ was found to be 230 mm Hg at the same temperature and volume, the mole fraction of $${ C }_{ 3 }{ H }_{ 8 }$$  in the mixture is 
    Solution

  • Question 9
    1 / -0
    Vapour density of the equilibrium mixture of $$NO_2$$ and $$N_2O_4$$ is found to be $$40$$ for the equilibrium. Calculate percentage of $$NO_2$$ in the mixture:  $$N_2O_4 \leftrightharpoons 2 NO_2$$
    Solution

  • Question 10
    1 / -0
    0.1 g of a solution containing $${ Na }_{ 2 }$$$$ { Co }_{ 3 }$$ and $${ NaHCO }_{ 3 }$$ requires 10 mL of 0.01 N HCl for neutralization using phenolphthalein as an indicator.Wt.% of  $${ Na }_{ 2 }$$$$ { Co }_{ 3 }$$ in the mixture is
    Solution

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