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The p-Block Elements Test - 16

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The p-Block Elements Test - 16
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Weekly Quiz Competition
  • Question 1
    1 / -0
    Which compound is solid ?
    Solution
    $$CO_2$$, $$NH_3$$, $$PH_3$$ are all gases in their natural forms whereas silica is found as various crystallographic forms - quartz, crystobalite, tridymite etc.
  • Question 2
    1 / -0
    Which is the amorphous form of silica?
    Solution
    Quartz, tridymite and cristobalite are all crystalline forms of silica however, onyx is a crypto-crystalline form of silica (Cryptocrystalline is a rock texture made up of such minute crystals that its crystalline nature is only vaguely revealed even microscopically  by transmitted polarized light). Keisulghur is an amorphous form of silica.
  • Question 3
    1 / -0
    Which is not true about $$SiO_{2}$$:
    Solution
    Silica is attacked only by HF and NaOH and it is unreactive to most other acids, metals and halogens. However, the basic structural unit of silica is $$SiO_4^{4-}$$.
    So, correct option is 'D'

  • Question 4
    1 / -0
    Whcih one of the following is used as an acidic flux in metallurgy?
    Solution
    Silica is used as acidic flux because it is almost non-reactive due to the very high bond enthalpy of $$Si-O$$ bond. It resists the attack by halogens, dihydrogen and most of the acids and metals even at the elevated temperature. However, $$HF$$ and $$NaOH$$ react with them to form $$SiF_4$$ and $$Na_2CO_3$$ respectively. 
  • Question 5
    1 / -0
    When $$SiO_{2}$$ is reacted with sodium carbonate, the gas liberated is :
    Solution
    The reaction is as follows:
    $$SiO_2 + Na_2CO_3 \rightarrow Na_2SiO_3 + CO_2$$
    This reaction is an example of corrosion of glass.
  • Question 6
    1 / -0
    When  $$\alpha$$-quartz is heated to 575$$^{\circ}$$C, it changes to:
    Solution
    $$\alpha$$-quartz when heated at 575$$^{\circ}$$C to form $$\beta$$-quartz. This phenomena is called inversion.
  • Question 7
    1 / -0
    The purest form of silica is:
    Solution
    Quartz is the crystalline form of Silica and hence is the purest form of Silica.
  • Question 8
    1 / -0
    Which oxide has three dimensional strucutre ?

    Solution
    CO, $$CO_2$$ are linearly shaped molecules whereas $$SO_2$$ is a bent shaped molecule. $$SiO_2$$ has a three dimensional structure as Si in $$SiO_2$$ is $$sp_3$$ hybridised with no lone pairs.
  • Question 9
    1 / -0
    The final product formed when silica reacts with hydrogen fluoride is :
    Solution
    The final product formed when silica $$(SiO_2)$$ reacts with hydrogen fluoride $$(HF)$$ is $$H_2SiF_6$$. 

    The reactions are as follows:

    $$SiO_2+4HF \rightarrow SiF_4 + 2H_2O$$
    $$3SiF_4 + 4H_2O \rightarrow 2H_2SiF_6 + H_4SiO_4$$
  • Question 10
    1 / -0
    The number of Oxygen atoms bonded to each
    silicon atom in silica crystal is :

    Solution
    every Silicon atom in silica forms 4 sigma bonds with oxygen atoms.

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