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States of Matter Test - 19

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States of Matter Test - 19
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  • Question 1
    1 / -0
    The volume of a gas is ______ when the pressure is reduced to half and the absolute temperature is doubled.
    Solution
    $$\cfrac { { P }_{ 2 }{ V }_{ 2 } }{ { T }_{ 2 } } =\cfrac { { P }_{ 1 }{ V }_{ 1 } }{ { T }_{ 1 } } \Longrightarrow \cfrac { { V }_{ 2 } }{ V_{ 1 } } =\cfrac { { P }_{ 1 } }{ P_{ 2 } } \cdot \cfrac { { T }_{ 1 } }{ T_{ 2 } } =2\cdot 2=4$$
    Therefore, the volume of the gas is quadrupled.
  • Question 2
    1 / -0
    If the velocity of an electron in the second orbit of the hydrogen atom is x, the velocity in fourth orbit will be:
    Solution
    $$mv{ r }_{ n }=\cfrac { nh }{ 2\pi  } and\quad { r }_{ n }=\cfrac { { n }^{ 2 }{ h }^{ 2 } }{ 4{ \pi  }^{ 2 }m{ e }^{ 2 } } $$ (since Z=1 for hydrogen atom)
    $$\therefore v=\cfrac { 1 }{ { r }_{ n } } \cdot \cfrac { nh }{ 2\pi m } =\cfrac { 4{ \pi  }^{ 2 }m{ e }^{ 2 } }{ { n }^{ 2 }{ h }^{ 2 } } \cdot \cfrac { nh }{ 2\pi m } =\cfrac { 1 }{ n } \cdot \cfrac { 2\pi { e }^{ 2 } }{ h } \\ \therefore v\propto \cfrac { 1 }{ n } \\ { v }_{ n=2 }=x\quad and\quad { v }_{ n=4 }=?$$
    Now, $${ v }_{ n=2 }\times 2={ v }_{ n=4 }\times 4\Longrightarrow 2x={ v }_{ n=4 }\times 4\Longrightarrow { v }_{ n=4 }=0.5x$$
  • Question 3
    1 / -0
    Which of the following pair of gases cannot be separated by diffusion method?
    Solution
    Previously we told that, $$D\propto \cfrac { 1 }{ \sqrt { M }  } $$
    Now, $${ M }_{ C{ O }_{ 2 } }$$ $$=2\times 16+12=44$$ g/mol
              $${ M }_{ { N }_{ 2 }O }$$ $$=2\times 14+16=44$$ g/mol
    $$\therefore { D }_{ C{ O }_{ 2 } }={ D }_{ { N }_{ 2 }O }$$, as diffusion coefficient of $$CO_{2}$$ and $$N_{2}O$$ is equal, $$CO_{2}$$ and $$N_{2}O$$ cannot be separated by diffusion method.
  • Question 4
    1 / -0
    Statement I
    The volume of a gas at 100 deg C and 600 mmHg will be lower at STP
    Because
    Statement II
    Decreasing temperature and increasing pressure will cause the volume of a gas to decrease
    Solution
    Answer(D)

    Using ideal gas law $$PV$$$$=$$$$nRT$$
    for given amount of a gas volume $$V$$$$=$$$$kT/P$$ ,where $$k$$ is a constant.
    so $$V$$$$=$$$$K*373/600$=$$$$0.621k$$
    at $$STP$$ volume  $$V$$$$=$$$$k*273/760$$$$=$$$$=$$$$.35k$$
    so The volume of a gas at 100 deg C and 600 mmHg will be higher than at STP,so this statement is not true
    Decreasing temperature and increasing pressure will cause the volume of a gas to decrease,this is correct
  • Question 5
    1 / -0
    The value of the Avogadro constant is:
    Solution

    Correct Answer: Option C

    Explanation:

    The value of the Avogadro constant is $$6.022 \times 10^{23}$$.

    It is a number of atoms or molecules or ions or particles present in one mole of a substance.

    Hence, the correct answer is option $$C$$.

  • Question 6
    1 / -0
    Which statement is NOT compatible with the ideal gas law?
    Solution
    (A) True: Gas particles have no definite volume.
    (B) True: Gas temperature depends on particles mass and velocity.
    (C) True: Gas particles are in constant, random motion.
    (D) False: Gas particle has mass.

    The correct option is (D).
  • Question 7
    1 / -0
    Which gas law uses pressure, number of moles, temperature, volume and the gas constant (R)?
    Solution
    The ideal gas low equation uses all the terms,
    $$PV=nRT$$
    where $$P$$ is the pressure
               $$V$$ is the volume
               $$T$$ is the temperature
               $$n$$ is the mole of gas.
  • Question 8
    1 / -0
    Statement I: In the kinetic theory of gases, collisions between gas particles and the walls of the container are considered elastic.
    Statement II: Gas molecules are considered pointlike, volumeless particles with no intermolecular forces and in constant, random motion.
    Solution
    Gas particles are constantly colliding with each other and the walls of a container. These collisions are elastic; that is, there is no net loss of energy from the collisions.Temperature remains the same, so the average kinetic energy and the rms speed should remain the same.
    In Kinetic theory Gas molecules are considered pointlike, volumeless particles with no intermolecular forces and in constant, random motion.
  • Question 9
    1 / -0
    Two gases A and B are taken in same volume containers under similar conditions of temperature and pressure. In container A, there are '2N' molecules of gas A. How many number molecules does container B have? 
    Solution
    Avogadro's law: Equal volumes of gases at the same temperature and pressure contain equal numbers of molecules.
    Thus ans is 2N.
  • Question 10
    1 / -0

    Directions For Questions

    In the above experiment, the vapor pressure of isopropanol is determined. Throughout the experiment, the temperature was held constant at $$\displaystyle { 25 }^{ \circ  }C$$ and the atmospheric pressure remained at $$760\ mm\ of\ \displaystyle Hg$$.

    ...view full instructions

    The initial pressure inside the flask is:

    Solution
    Since here in the figure given the mercury is at the same height in both the arms containing the sample and the arm is atom to the atmosphere, the pressure inside the flask initially is $$760mHg$$.
    Option (C) is correct.
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