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States of Matter Test - 46

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States of Matter Test - 46
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  • Question 1
    1 / -0
    In the gas equation $$PV = nRT$$ , the value of $$R$$ depends upon:
    Solution
    $$R$$ is the universal gas constant. It has a fixed value which depends upon the units in which $$P, V, n$$ and $$T$$ are expressed in the ideal gas equation, $$PV = nRT$$.

    It's values are 

    $$0.0821\  L\cdot atm\cdot mol^{-1}\cdot K^{-1}$$ , 

    $$8.314\ J\cdot mol^{-1}\cdot K^{-1}$$  or  

    $$2 \ cal\cdot mol^{-1}\cdot K^{-1}$$ 

    Thus, option C is correct.
  • Question 2
    1 / -0
    Mass of a given gas occupies two litre at STP. By keeping the pressure constant, at what temperature the gas will occupy 4 litre?
    Solution
    At constant pressure, 

    $$V \propto T$$

    $$V= KT$$ 

    So if volume becomes double then temperature also becomes double.

    Initial temperature at STP is 273 K which becomes 546 K.

    Hence, option A is correct.
  • Question 3
    1 / -0
    When the pressure of 5L of $$N_2$$ is double and its temperature is raised from 300K to 600K, the final volume of the gas would be:
    Solution
    Since $$\dfrac{PV}{T}=nR=constant$$

    $$\Rightarrow \dfrac{P_1V_1}{T_1}=\dfrac{P_2V_2}{T_2}$$

    $$\Rightarrow \dfrac{P_1\times5}{300}=\dfrac{2P_1\times V_2}{600}$$

    $$\Rightarrow V_2=5\ L$$
  • Question 4
    1 / -0
    If  $$500ml$$  of a gas  $$A$$  at  $$1000$$ torr, and  $$1000ml$$  of gas  $$B$$  at  $$800$$  torr  are placed in  $$2L$$  container the final pressure will be -
    Solution
    According to Boyle's Law (Modified)
    $$P_1V_1+P_2V_2+........=P_fV_f$$
    Given,
    $$P_1=1000;\quad V_1=500$$ $$mL$$
    $$P_2=800;\quad V_2=1000$$ $$mL$$
    $$P_f=?;\quad V_f=2000$$ $$mL$$
    $$\implies P_1V_1+P_2V_2=P_fV_f$$
    $$\implies (1000)(500)+(800)(1000)=(P_f)(2000)$$
    $$\implies \cfrac {1300}{2}=P_f$$
    $$\implies P_f=650$$ $$torr$$
  • Question 5
    1 / -0
    The vapour pressure of a solution containing 5 g of a non electrolyte in 100 g of water at a particular temperature is $$2985 N{m}^{-2}$$. If the vapour pressure of pure water is $$3000 N{m}^{-2}$$, the molecular weight of solute is:
    Solution
    we have formula of $$\text{Relative lowering of vapour pressure}$$ which is

    $$\dfrac{P_o-P}{P_o}=X_{solute}=\dfrac{n_{solute}}{n_{solute}+n_{solvent}}\approx\dfrac{n_{solute}}{n_{solvent}}$$


    Now, pute the values

    $$\dfrac{3000-2985}{3000}=\dfrac{\dfrac{5}{M}}{\dfrac{100}{18}}$$

    $$\dfrac{15}{3000}=\dfrac{5\times 18}{100\times M}$$


    $$M=180$$

    correct answer is C.
  • Question 6
    1 / -0
    The temperature and pressure at which ice, liquid. water and water vapour can exist together are ?
    Solution
    The temperature and pressure at which ice, liquid, water and water vapour exist together at triple point of water.
    Triple point of water is $$0^\circ C \ and \ 4.7mm$$
    Hence, Option "C" is the correct answer.
  • Question 7
    1 / -0
    Which of the following is an anti-knocking compound, that has been phased out in many countries so far?
    Solution
    Given :Which of the following is an anti-knocking compound, that has been phased out in many countries so far?

    Solution : 
    An anti-knocking agent is a chemical compound that, when added to gasoline, raises the octane value of the gasoline.
    Tetra Ethyl Lead  is an anti-knocking compound, that has been phased out in many countries so far.
    The Correct Opt = B
  • Question 8
    1 / -0
    A gas is said to behave like an ideal gas when the relation $$\dfrac{PV}{T} =$$ constant. When do you expect a real gas to behave like an ideal gas?
    Solution
    Generally, a gas behaves more like an ideal gas at higher temperature and lower pressure, as the potential energy due to inter molecular forces becomes less significant compared with the particles' kinetic energy, and the size of the molecules becomes less significant compared to the empty space between them.
    Hence option $$D$$ is correct answer.
  • Question 9
    1 / -0
    According to the equipartition principle, each degree of freedom contribute following amount to the translational kinetic energy of molecule: (hence k = Boltzmann constant)
    Solution
    According to the equipartition principle, each degree of freedom contributes an amount of $$\dfrac{1}{2}kT$$ to the kinetic energy of the molecule.
  • Question 10
    1 / -0
    The solubility of a specific non-volatile salt is  $$4\mathrm { g }$$  in $$100\mathrm { g }$$  of water at  $$25 ^ { \circ } \mathrm { C } .$$  If  $$2.0 g,$$  $$4.0\mathrm g$$  and  $$6.0 g$$  of the salt added of  $$100 g$$  of water at  $$25 ^ { \circ } \mathrm { C } ,$$  in system  $$X , Y$$  and  $$Z .$$  The vapour pressure would be in the order:
    Solution

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