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States of Matter Test - 50

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States of Matter Test - 50
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  • Question 1
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    Directions For Questions

    The intermolecular forces of attraction (i.e., H-bonding and van der Waals' forces) exist among polar and non-polar species which affect melting point, boiling point, solubility and viscosity of covalent compounds :

    ...view full instructions

    The type of molecular force of attraction present in the following compound is :

    Solution

  • Question 2
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    Directions For Questions

    The intermolecular forces of attraction (i.e., H-bonding and van der Waals' forces) exist among polar and non-polar species which affect melting point, boiling point, solubility and viscosity of covalent compounds :

    ...view full instructions

    Select the incorrect order of boiling point between the following compounds :
    Solution
    $$\rightarrow$$ Boiling point of $$HN_3 > CH_3N_3$$ as in hydrazoic acid ($$HN_3$$) intermolecular H-bonding occurs and its bond energy is higher than weak dipole-dipole interactions present in $$CH_3N_3$$. 
     $$\rightarrow$$ Boiling point of $$BI_3$$ is greater than that of $$BF_3$$ as molecular weight of $$BI_3$$ is higher than that of $$BF_3$$. 
     $$\rightarrow$$ Due to intermolecular H-bonding in $$H_2SO_4$$ its boiling point is higher than $$Me_2SO_4$$. 
     $$\rightarrow$$  Similarly due to intermolecular H-bonding in $$B(OH)_3$$ its boiling point is higher. than that of $$Me_3BO_3$$.
  • Question 3
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    At a certain pressure, volume of the gas at $$27^\circ C$$ is $$20$$ litre. If the pressure and temperature are doubled, the volume will be 
    Solution
    According to question:

    $$P_1 =P$$,    $$V_1 =20L$$,     $$T_1 =T$$

    $$P_2=2P$$,    $$V_2=?$$,   $$T_2= 2T$$

    Now,

    $$\dfrac{P_1V_1}{T_1}=\dfrac{P_2V_2}{T_2}$$

    $$\dfrac{P \times 20}{T}=\dfrac{2P \times V_2}{2T}$$

    $$\Rightarrow V_2=20\,L$$
  • Question 4
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    Kinetic theory of gases presumes the collision between the molecules to be perfectly elastic because:
    Solution
    The kinetic theory of gases presumes the collision between the molecules to be perfectly elastic because the molecules are tiny. If the molecules are tiny, the energy and momenta of the molecules are conserved during the collisions. Consequently, the temperature remains constant irrespective of collisions.
  • Question 5
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    Which of the given laws of chemical combination is satisfied by the figure?

    Solution

  • Question 6
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    "Equal volumes of all gases at the same temperature and pressure contain equal number of particles." This statement is a direct consequence of:
    Solution
    Avogadro's Law states that "Equal volumes of all gases at the same temperature and pressure contain equal number of particles."

    Hence, Option "A" is the correct answer.
  • Question 7
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    Match the following :
    List -IList-II
    A. Boyle’s law1. $$P_{wet}=P_{dry}+P_{water\ vapour}$$
    B. Avogadro law2. $$V_{1}=n_{1}\left ( \dfrac{V_{2}}{n_{2}} \right )$$
    C. Charles law3. $$V_{1}=V_{0}\left (1+ \dfrac{t}{273} \right )$$
    D. Dalton’s law4. $$V_{1}=P_{2}\left ( \dfrac{V_{2}}{P_{1}} \right )$$
    The correct match is:
    Solution
    Boyle's law: At constant temperature, $$PV=$$ constant

    $$\therefore P_1V_1 = P_2V_2$$


    Avogadro's law states that "equal volumes of all gases, at the same temperature and pressure, have the same number of molecules".

    $$\therefore \dfrac{V_1}{n_1} = \dfrac{V_2}{n_2}$$


    Charles law states that the volume occupied by a fixed amount of gas is directly proportional to its absolute temperature if the pressure remains constant.

    $$= V_{1}=V_{0}\left (1+ \dfrac{t}{273} \right )$$


    Dalton's law: Net vapour pressure is the addition of vapour pressure of individual components.

    $$\therefore P_{wet} = P_{dry} + P_{water\ vapour}$$

    Hence, the correct answer is option $$\text{D}$$.
  • Question 8
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    2.5 L of a sample of a gas at $$27^\circ C$$ and 1 bar pressure is compressed to a volume of 500 mL keeping the temperature constant, the percentage increase in the pressure is :
    Solution

  • Question 9
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    Dalton's law of partial pressures is not applicable to which one of the following?
    Solution
    According to Dalton's law of partial pressures, for a mixture of $$\text{non-reacting}$$ gases, the total pressure is equal to the sum of the partial pressures of the individual gases.

    This law is not applicable to the mixtures $$H_{2}+Cl_{2},  NH_{3}+HCl $$ and  $$SO_{2}+Cl_{2}$$ as they react with each other.

    For example, hydrogen and chlorine react to form hydrogen chloride, ammonia and hydrochloric acid forms ammonium chloride while sulphur dioxide reacts with chlorine to form $$SO_2Cl_2$$.

    Hence, the correct answer is option $$\text{D}$$.
  • Question 10
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    At the same temperature, HCl gas and NH$$_{3}$$ gas are present in two vessels of same volume at a pressure of 'P' atmospheres each. When one jar is inverted over the other so that the two will mix, after some time the pressure in the vessels will become:
    Solution
    $$NH_3 + HCl \rightarrow NH_4Cl(solid)$$

    Due to the formation of a solid, final pressure in the vessel will become zero.

    Hence, the correct answer is option $$\text{C}$$.
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