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States of Matter Test - 72

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States of Matter Test - 72
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Weekly Quiz Competition
  • Question 1
    1 / -0
    The density of air 380K and 722 mm of Hg is 1g/$${ cm }^{ 3 }$$. If air is cooled to 100K and 1 atm  the final density is:
  • Question 2
    1 / -0
    What is the total pressure (atm) in the chamber ?
  • Question 3
    1 / -0
    For which of the following reactions, Gay Lussac's law is not applicable:
    Solution

  • Question 4
    1 / -0

    Directions For Questions

    The apparatus shown consists of three temperature jacketed $$1.642$$ L bulbs connected by stopcocks. Bulb A contains a mixture of $$H_2O(g), CO_2(g)$$ and $$N_2(g)$$ at $$27^o$$C and a total pressure of $$570$$ mm Hg. Bulb B is empty and held at a temperature of $$-73^o$$C. Bulb C is also empty and is held at a temperature of $$-193^o$$C. The stopcocks are closed and the volume of the lines connecting the bulbs is zero. $$CO_2$$ sublimes at $$-78^o$$C and $$N_2$$ boils at $$-196^o$$C. Neglect the volume of any solid, if formed.

    ...view full instructions

    Both stopcocks are opened and the system is again allowed to come at equilibrium. The pressure throughout the system is $$33.5$$ mm Hg. What do bulbs A, B and C contain?

  • Question 5
    1 / -0
    A steel rigid vessel of volume $$1 l$$ is filled with a mixture of methane and oxygen at a total pressure of one atm at $$27^o$$C. The gas mixture is exploded. What would be the final pressure of the products at $$127^o$$C? Aqueous tension at $$27^o$$C$$=0.04$$ atm.
  • Question 6
    1 / -0
    Which of the following behaviour is true about the ideal binary liquid solution of liquids A and B if $$ P^0_A < P^0_B $$?
    Solution

  • Question 7
    1 / -0

    Directions For Questions

    The apparatus shown consists of three temperature jacketed $$1.642$$ L bulbs connected by stopcocks. Bulb A contains a mixture of $$H_2O(g), CO_2(g)$$ and $$N_2(g)$$ at $$27^o$$C and a total pressure of $$570$$ mm Hg. Bulb B is empty and held at a temperature of $$-73^o$$C. Bulb C is also empty and is held at a temperature of $$-193^o$$C. The stopcocks are closed and the volume of the lines connecting the bulbs is zero. $$CO_2$$ sublimes at $$-78^o$$C and $$N_2$$ boils at $$-196^o$$C. Neglect the volume of any solid, if formed.

    ...view full instructions

    The stopcock between A and B is opened and the system is allowed to come to equilibrium. The pressure in A and B is now $$0.21$$ atm. 
    How many moles of $$H_2O$$ are in the system?

    Solution
    No. of moles in flask A

    Given:
    P= 570 mm of Hg = 570/ 760 atm, V=1.642 L, T = 300 K

    $$n=\dfrac{PV}{RT}=\dfrac{570\times 1.642}{760\times 0.082\times 300}$$

    $$n=0.05$$ moles

    $$n_{N_2}+n_{CO_2}+n_{H_2O}=0.05$$ moles

    Upon opening the stop cock, the gases will dispose

    In flask A: $$CO_2+N_2=(n_{CO_2}+n_{N_2})$$ ……$$(1)$$

    In flask B: $$CO_2+N_2+H_2O=(n_{CO_2}+n_{H_2}+n_{H_2O})$$ ……….$$(2)$$

    $$(2) - (1)$$

    $$\Rightarrow n_{CO_2}+n_{N_2}+n_{H_2O}-(n_{CO_2}+n_{N_2})=n_{H_2O}$$
    in flask A

    no. of moles$$=\dfrac{0.21\times 1.642}{0.082\times 300}=0.014$$
    in flask B

    no. of moles$$=\dfrac{0.21\times 1.642}{0.082\times 200}=0.021$$

    Total moles$$=(0.014+0.021)=n_{H_2O}$$

    $$n_{H_2O}=0.05-0.035$$

    $$=0.015$$ Option B.
  • Question 8
    1 / -0
    If water vapor comprises 3.5 percent of an air parcel whose total pressure is 1,000 mb, the water vapor pressure would be:
    Solution
    The water vapor pressure would be 35 mb because if the water vapor comprises 3.5 percent of the air parcel and the amount of the total pressure would be 1,000 mb. The temperature of the air parcel decreases due to the cause of work and expansion of the raised air parcel. The humidity increases until it reaches 100% inside the air parcel and the largest aerosol particles forming the excess water vapor during the cloud droplets in the beginning. It makes less sense as it rises during the expansion of the air parcel and increases in altitude because the air pressure starts decreasing around the parcel. But sometimes it became less dense when the temperature of the rising parcel was found in the coolest state.
    hence answer is the option b 
  • Question 9
    1 / -0
    One monoatomic gas is expanded adibatically from $$2L$$ to $$10L$$ at $$1\ atm$$ external pressure find $$\triangle U$$ (in atm $$L$$)?
    Solution
    Process is adiabatic $$\therefore Q = 0$$
    $$\therefore \triangle U = W = -P_{ext} \triangle V$$
    $$= -1 (10 - 2)\ atm \ L$$
    $$= -8\ atm\ L$$.
  • Question 10
    1 / -0
    When the air temperature is below freezing, the saturation vapor pressure over water is _______.
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