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Thermodynamics ...

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  • Question 1
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    The specific heat capacity of water is:

  • Question 2
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    Which of the following sets represent the normal physical states of the elements concerned at $$25^{\circ}C$$ and one bar pressure, with $$\Delta H^\circ$$ (formation)$$=0$$

  • Question 3
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    Which of the following are not state functions?
    (I) $$q+w$$ 

    (II) $$q$$
    (III) $$w$$ 
    (IV) $$H-TS$$

  • Question 4
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    $$n \ moles$$ of gas an ideal monatomic gas is confined in a cylinder A of volume $$V_{0}$$, pressure $$P_{0}$$ and temperature $$T_{0}$$, this cylinder is connected to another cylinder B with the help of tube of a negligible volume. The cylinder B is fitted with a movable piston which can be adjusted from outside. Initially, the piston is adjusted so that volume of B is 7$$V_{0}$$ and B is evacuated and then stopcork is opened so that gas expands and occupies the volume $$8V_{0}$$. [System is thermally isolated from the surroundings].


    During this free expansion, the internal energy of the system

  • Question 5
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    A sample of oxygen gas expands its volume from $$3\ L\ to\ 5\ L$$ against a constant pressure of $$3\ atm$$. If work done during expansion is used to heat 10 mole of water initially present at $$290\ K$$, its final temperature will be (specific heat capacity of water = 4.18 J/kg):

  • Question 6
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    Water of mass $$m_2$$ = 1 kg is contained in a copper calorimeter of mass $$m_1$$  = 1 kg. Their common temperature t = $$10^{0}C$$. Now a piece of ice of mass $$m_3$$  = 2 kg and temperature is $$-11^{0}C$$ dropped into the calorimeter. Neglecting any heat loss, the final temperature of system is. [specific heat of copper = 0.1 Kcal/ kg$$^{0}C$$, specific heat of water = 1 Kcal/kg$$^{0}C$$, specific heat of ice = 0.5 Kcal/kg$$^{0}C$$, latent heat of fusion of ice = 78.7 Kcal/kg]

  • Question 7
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    Specific heat of a gas undergoing adiabatic change is

  • Question 8
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    A liquid boils at such a temperature at which the saturated vapour pressure, as compared to atmospheric pressure, is 

  • Question 9
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    Specific heat may be defined as:

  • Question 10
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    The temperature at which the reaction $$AgO(s)  \rightarrow Ag(s) + \frac{1}{2} O_2(g)$$ is at equilibrium is?
    Given  $$\Delta H = 30.5  KJ  mol^{-1}$$ and $$\Delta  S = 0.066 KJK^{-1}  mol^{-1}$$

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