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Thermodynamics ...

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  • Question 1
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    For the reaction  : 


    3N2+H22NH33N_{2} + H_{2} \rightarrow 2NH_{3},   

    H=24kcal\triangle H = - 24 kcal at 4270C427^{0}C and 200atm200 atm

    Calculate magnitude of internal enerrgy change in KcalKcal (U\triangle U), if 168 g N2N_{2} gas and 30 g H2H_{2} gas are allowed to react completely (100% reaction yield) to form NH3NH_{3} gas at 4270C427^{0}C and 200 atm. 

  • Question 2
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    Which of the following are spontaneous?

  • Question 3
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    One mole of an ideal monatomic gas undergoes a process described by the equation PV3PV^{3} = constant. The heat capacity of the gas during this process is:

  • Question 4
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    A reaction A(g) +B(g) \rightarrow C(g) +D(g). ΔH\Delta H= (-) ve is found to have positive entropy change. the reaction will be: 

  • Question 5
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    The correct thermodynamic conditions for the spontaneous reaction at all temperatures is ______________________.

  • Question 6
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    7.5 KJ heat is added to a closed system and its internal energy decreases by 12 KJ. So,______ of work is done ____ the system ,for a new process , if the work is zero, then____of heat is ______ for the same changes in state of system

  • Question 7
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    An ideal monoatomic gas is taken through a process in which dQ=2dUd Q = 2 d U . The molar heat capacity of the gas for the process is

  • Question 8
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    Correct desending order of deprotonation in the following compound:

  • Question 9
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    100g100g of water is heated from 30oC{30}^{o}C to 50oC{50}^{o}C. Ignoring the slight expansion of water, the change in its internal energy is (Specific heat of water is 4200J4200J kg1{kg}^{-1} K1{K}^{-1})

  • Question 10
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    If ΔG298\Delta G_{298} for reaction:
    2H2(9,1atm)+O2(g)(1atm)2H2O(g)(1atm)2H_{2 (9, 1 atm)} + O_{2(g)(1atm)} \to 2H_2O(g)(1 atm)
    is 240KJ-240KJ, what will be the ΔG298\Delta G_{298} for reaction
    H2O(g,0.2atm)H2(g,4atm)+12O2(g,0.9atm)H_2O_{(g, 0.2atm)} \to H_{2(g, 4atm)} + \dfrac{1}{2}O_{2(g, 0.9 atm)}

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