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Redox Reactions Test - 28

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Redox Reactions Test - 28
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  • Question 1
    1 / -0
    Determine the. oxidation state of chromium in the finfll product formed by the reaction between KI and acidified potassium dichromate solution.
    Solution
    K would not be expected to be in the final NET equation since K+ is a spectator ion; i.e., it does not react. When you put KI into water it dissolves and splits up into K+ and I- ions. Only the I- participates in the redox reaction. It wouldn't matter whether you used KI or NaI. 
    Oxidation: $$2I^- \rightarrow I^2 + 2e^- $$
    Reduction: $$Cr_2O_7^{2-} + 14H^+ + 6e^- \rightarrow 2Cr^{3+} + 7H_2O$$

    The final product formed is :
    $$6I^- + Cr_2O_7^{2-} + 14H^+ ----> 3I_2 + 2Cr^{3+} + 7H_2O$$
    Calculating the oxidation state of chromium  we get + 3


  • Question 2
    1 / -0
    Which of the following processes does not involve either oxidation or reduction ?
    Solution
    Here, in this reaction
    $$CaO+ H_2O \rightarrow Ca(OH)_2$$
    oxidation number doesn't change so its not a redox reaction.
  • Question 3
    1 / -0
    The oxidation number of $$Mn$$ is $$+8$$ in the compound:
    Solution
    In $$MnO_4$$ manganese oxidation number is $$+8$$. 
    Oxidation number of oxygen is $$-2$$. $$MnO_4$$ is neutral molecule so total oxidation number of molecule is zero.
    Oxidation number of $$Mn+4(-2)=0$$
    Oxidation number of $$Mn =+8$$.
    So answer is B.
  • Question 4
    1 / -0
    Arrange the following in correct order of oxidation number of Mn
    (i) $$Mn^{2+}$$                    (ii) $$MnO_2$$
    (III) $$KMnO_4$$                (iv) $$K_2MnO_4$$
    Solution
    i) Oxidation number of Mn in $$Mn^{2+} = +2$$
    (ii) Let oxidation number of Mn in $$MnO_2 = x$$
    $$\therefore x + (-2 \times 2) = 0 , x = +4$$
    (iii) Let oxidation number of Mn in KMno_4 = x 
    $$\therefore +1 +x +(-1 \times 4 ) = 0, \therefore x += + 7$$
    (iv) Let oxidation number of Mn in $$K_2MnO_4$$ = x
    $$\therefore (+1 \times 2 ) + x + (-2 \times \times 4 _ = 0$$
    or x + 2 - 8 = 0
    $$\therefore $$ x = +6
    $$\therefore $$ the order of oxidation state is (i) < (ii) < (iv) < (iii) 
  • Question 5
    1 / -0
    The oxidation number of oxygen in hydrogen peroxide is:
  • Question 6
    1 / -0
    Identify redox reaction among the following:
    Solution
    Metal displacement reactions are redox reactions in which both oxidation and reduction takes place.Example; $$Mg + ZnSO_{4} \rightarrow MgSO_{4} + Zn$$
    Here Mg is undergoing oxidation with an increase in oxidation number from 0 to +2 and Zn is undergoing reduction with a decrease in oxidation number.
  • Question 7
    1 / -0
    The oxidation number of chlorine in $$NaCl{O}_{3}$$ is:
    Solution
    The overall charge of molecule is zero (because it's not an ion). Since sodium is a 1A family member, you can assume that the charge is $$+1$$. The charge of oxygen is almost always $$-2$$ so you can assume that as well. 
    $$(+1) +$$ oxidation of $$Cl + 3(-2) = 0 $$
    So the oxidation of chlorine in that problem is $$+5$$.
    So answer is C.
  • Question 8
    1 / -0
    Identify X in the equation given below. $$FeCl_3 + SO_2 + H_2O \rightarrow FeCl_2 + HCl + X$$
    Solution
    The balanced equation can be written as:
    $$2FeCl_{3} + SO_{2} + 2H_{2}O \rightarrow 2FeCl_{2} + 2HCl + H_{2}SO_{4}$$
    Thus X = $$ H_{2}SO_{4}$$
  • Question 9
    1 / -0
    The oxidation state of nitrogen in $$Na{NO}_{3}$$ is :
    Solution
    The overall charge is zero (because it is not an ion). Since sodium is a 1A family member, the charge is +1. The charge of oxygen is almost always -2.
    Hence, $$1+ OS \ of\ N + (3 \times -2)=0$$
    So, the oxidation of nitrogen in that problem is +5.
  • Question 10
    1 / -0
    Oxidation number of S in $$SO_4^{2-}$$:
    Solution
    Let oxidation state of S in $$SO_4^{2-} = x$$
    $$\therefore x+ (4 \times - 2) = - 2$$
    or $$x - 8 = - 2$$    $$\therefore$$ $$x = +6$$
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