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Thermodynamics Test - 16

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Thermodynamics Test - 16
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  • Question 1
    1 / -0
    Transit of work takes place when any property other than $$\underline{\hspace{0.5in}}$$ differs 
    Solution
    Zeroth law states that temperature difference leads to transit of heat energy.
    Hence temperature is the required property.
  • Question 2
    1 / -0
    Heat and work are equivalent. This means,
  • Question 3
    1 / -0
    The ratio of specific heat capacity to molar heat capacity of a body
    Solution
    Specific heat capacity(C) is the amount of heat required per unit mass to raise the temperature by 1K.
    Molar heat capacity(s) is the amount of heat required per mole to raise the temperature by 1K.
    Thus $$\dfrac{C}{s}=\dfrac{moles}{mass}=\dfrac{1}{M_o}$$
  • Question 4
    1 / -0
    The internal energy of 1 mol of an ideal gas depends on
    Solution
    Internal energy is $$mc\Delta T$$, so it depends on temperature.
  • Question 5
    1 / -0

    That 'Entropy of a system increases in all spontaneous processes' is  known as

    Solution
    The second law of thermodynamics states that the entropy of an isolated system never decreases, because isolated systems spontaneously evolve toward thermodynamic equilibriumthe state of maximum entropy
  • Question 6
    1 / -0
    The molar heat capacity of an ideal gas
    Solution

    Hint: The quantity of heat energy required to increase the temperature of 1 mole of a substance is known as molar heat capacity or molar specific heat capacity.
    Explanation:

    • The formula of change in heat is given by: $$dQ = n C dT$$
    where $$C$$ is molar heat capacity, $$n$$ is the number of moles. For various processes, values of $$dQ$$ and $$dT$$ will be different.
    • For the isothermal process, $$dT$$ is $$0$$. So, for non-zero value of $$dQ, C$$ will be infinite.
    • For the adiabatic process, change in heat $$dQ = 0$$. For that $$C$$ will be zero.

    For other processes like at constant volume and at constant pressure $$C$$ will be and respectively. Which will depend on the degree of freedom that is f. So, molar heat capacity also depends on the nature of the gas and its atomicity.

    So, molar heat capacity has any value between $$- \infty $$ and $$+\infty$$

    And, if from saturated vapors when a certain quantity of heat is removed, at that time due to an increase in temperature specific heat will have a negative value.

    Answer:

    Hence, option D is the correct answer.

  • Question 7
    1 / -0
    A system is given $$400\ cal$$ of heat and $$1000\ J$$ of work is done by the system, then the change in internal energy of the system will be
    Solution
    $$1\ cal=4.184\ J, thus\ 400\ cal = 1673.6\ J$$.
    The change in internal energy is $$\Delta U=\Delta Q- \Delta W$$
    or $$\Delta U=1673.6-1000=673.6\approx 680\ J$$
  • Question 8
    1 / -0
    In a certain process $$500\ cal$$ of heat is given to a system and the system does $$100\ J$$ of work. The increase in internal energy of the system is
    Solution
    $$1\ cal=4.184\ J, thus\ 500\ cal = 2092 \ J$$.
    The change in internal energy is $$\Delta U=\Delta Q- \Delta W$$
    or $$\Delta U=2093-100=1993 \ J$$
  • Question 9
    1 / -0
    Which of the following is the best container for gas during adiabatic process?
    Solution
    A thermos flask does not allow for the heat transfer to take place through its walls.
  • Question 10
    1 / -0
    For an adiabatic expansion of perfect gas, the value of $$\displaystyle \left ( \frac{\Delta P}{P} \right )$$ is equal to
    Solution
    In an adiabatic expansion of gas,
    $$P{ V }^{ \gamma  }=constant$$
    Taking logarithm on both sides 
    $$ln(P)+\gamma ln(V)=ln(C)$$

    On differentiating:
    $$\dfrac { \Delta P }{ P } +\gamma \dfrac { \Delta V }{ V } =0\\ \Rightarrow \dfrac { \Delta P }{ P }=-\gamma \dfrac { \Delta V }{ V } $$
    Hence, option C is correct.
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