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Thermodynamics Test - 54

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Thermodynamics Test - 54
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  • Question 1
    1 / -0
    A diatomic gas does $$80\ J$$ of work when expanded isobarically. The heat given to the gas during this process is
    Solution

    it is given that $$W=80\,J$$

    from ideal gas equation

    $$ P\Delta V=nR\Delta T $$

    $$ \because W=P\Delta T $$

    $$ \Delta T=\dfrac{80}{nR}..........(1) $$

    Change in internal energy is given by the relation as follows

     $$ \Delta U=n{{c}_{v}}\Delta T $$

    $$ =n\dfrac{R}{\gamma -1}\Delta T..........(2) $$

    Here, diatomic gas is given so $$\gamma =\dfrac{7}{5}$$

    Equation (2) becomes

    $$ \Delta U=\dfrac{nR}{\dfrac{2}{5}}\Delta T $$

    $$ =\dfrac{5nR}{2}\times \dfrac{80}{nR} $$

    $$ =200\,J $$

    The heat given to the gas during this process is

    $$ \Delta Q=\Delta U+W $$

    $$ \Delta Q=200+80 $$

    $$ \Delta Q=280\,J $$

     

  • Question 2
    1 / -0
    The higher and lower fixed points on a thermometer are separated by $$ I80mm$$ . When the length of the thread above the lower temperature 90mm , the temperature reading would be
    Solution
    Given :
    $$1^oC=1mm$$
    T=90mm
    LFP=0
    UFP=180mm

    Solution:
    We have a relation for this type of problem as $$\dfrac{T-LFP}{UFP-LFP}=\dfrac{K}{100}$$

    we need K here so by substituting all the values in the formula we get 
    $$\dfrac{90-0}{180-0}=\dfrac{K}{100}$$

    $$K=50^oC$$

    The Correct Opt=A

  • Question 3
    1 / -0
    For a first order reaction rate constant is $$1 \times {10^{ - 5}}{\sec ^{ - 1}}$$ having $${E_a} = 1800\ kJ/mol$$ . Then the value of $$\ell nA$$ at$$T = 600\ K$$ is:-
    Solution
    acc. to arrhenius equation
    $$k=A{ e }^{ -Ea/RT }\quad $$
    rate constant $$1\times { 10 }^{ -5 }{ sec }^{ -1 }$$
    $$Ea=1800kJ/mol$$
    $$\log { k } =\log { A } -\cfrac { Ea }{ RT } $$
    $$\log { \left( 1\times { 10 }^{ -5 } \right)  } =\log { A } -\cfrac { Ea }{ RT } $$
    $$\log { A } =\log { \left( 1\times { 10 }^{ -5 } \right)  } +\cfrac { 1800 }{ 1\times { 10 }^{ -5 }\times 600 } =151.7$$
  • Question 4
    1 / -0
    $$0.1 \,{m^3}$$ of water at $${80^ \circ }$$ is mixed with $$0.3 {m^3}$$ of water at $${60^ \circ }$$. The final temperature of mixture is :
    Solution
    $${ m }_{ 1 }{ s }_{ 1 }{ dt }_{ 1 }={ m }_{ 2 }{ s }_{ 2 }{ dt }_{ 2 }$$
    $$P\left[ 0.1 \right] \times 1\times \left[ 80-t \right] =P\left[ 0.3 \right] \times \left[ 1 \right] \times \left[ t-60 \right] $$
    $$80-t=3t-180$$
    $$4t=260=t=6{ 5 }^{ 0 }c$$
  • Question 5
    1 / -0
    Air is filled in a tube of the wheel of a car at $$27^{\circ } C$$ and 2 atm pressure if the tube is suddenly bursts, the final temperature of air will be-
    $$(\gamma =1.5, 2^{1/3}=1.251)$$
    Solution
    Given,
    $$T_1=27+273=300K$$
    $$P_1=2atm$$
    $$\gamma=1.5$$  $$2^{1/3}=1.251$$
    In the process
    $$T_1^{\gamma}P_1^{\gamma-1}=T_2^{\gamma}P_2^{\gamma-1}$$
    $$(\dfrac{T_1}{T_2})^{\gamma}=(\dfrac{P_2}{P_1})^{\gamma-1}$$
    $$(\dfrac{300}{T_2})^{3/2}=(\dfrac{2}{1})^{1/2}$$
    $$T_2=\dfrac{300}{2^{1/3}}=240^0C$$
    The correct option is D.
  • Question 6
    1 / -0
    $$V = k \left(\dfrac{P}{T}\right)^{0.33}$$ where k is constant. It is an:
    Solution

    The process in which change in volume and temperature of a gas take place at a constant pressure is called an isobaric process.

    Consider some gas contained in a barrel. Supply some quantity of heat to increase its temperature from T1 to T2 without changing its pressure ‘P’. It will be observed that the gas expand. The change is said to be isobaric change

  • Question 7
    1 / -0
    A box of negligible mass containing $$2$$ moles of an ideal gas of molar mass $$M$$ and adiabatic exponent $$\gamma$$ moves with constant speed $$v$$ on a smooth horizontal surface. If the box suddenly stops, then change in temperature of gas will be
    Solution

    $$\textbf {Hint :}$$ Use $$ U=n{{c}_{v}}\Delta T $$


    $$\textbf{Step 1: }$$Kinetic energy of molecules is given by $$\dfrac{1}{2}nM{{v}^{2}}$$

    Relation between $${{c}_{v}}$$ and internal energy $$U$$is given by

    $$ U=n{{c}_{v}}\Delta T $$

    $$ {{c}_{v}}=\dfrac{U}{n\Delta T}........(1) $$

    $$ \because \,\dfrac{{{c}_{p}}}{{{c}_{v}}}-1=\lambda -1 $$

    $$ \dfrac{{{c}_{p}}-{{c}_{v}}}{{{c}_{v}}}=\lambda -1 $$

    $$ \dfrac{R}{{{c}_{v}}}=\lambda -1 $$

    $$ {{c}_{v}}=\dfrac{R}{\lambda -1}........(2) $$

    $$\textbf{Step 2: }$$From (1) and (2)$$ \dfrac{U}{n\Delta T}=\dfrac{R}{\lambda -1} $$

    $$ U=\dfrac{Rn\Delta T}{\lambda -1} $$

    Now the internal energy is equal to the change in KE

     $$ \dfrac{Rn\Delta T}{\lambda -1}=\dfrac{1}{2}nM{{v}^{2}} $$

    $$ \dfrac{R\Delta T}{\lambda -1}=\dfrac{1}{2}nM{{v}^{2}} $$

    $$ \Delta T=\dfrac{M{{v}^{2}}}{2R}(\lambda -1) $$If the box suddenly stops, then change in temperature of gas will be $$\Delta T=\dfrac{M{{v}^{2}}}{2R}(\lambda -1)$$

     

    $${\textbf{Correct option: D}}$$

  • Question 8
    1 / -0
    The value closest to the thermal velocity of a Helium atom at room temperature (300 K) in $$ms^{-1}$$ is : [$$k_B = 1.4 \times 10^{-23} \ J/K ; \ m_{He} = 7\times 10^{-27} \ kg$$ ]
    Solution
    Given,
    $$T=300K$$
    $$m=7\times 10^{-27}kg$$
    $$k_B=1.4\times 10^{-23}J/K$$
    The thermal velocity of helium is given by
    $$v=\sqrt{\dfrac{3k_BT}{m}}$$
    $$v=\sqrt{\dfrac{3\times 1.4\times 10^{-23}\times 300}{7\times 10^{-27}}}$$
    $$v=1.3\times 10^3m/s$$
    The correct option is B.
  • Question 9
    1 / -0
    The thermal efficiency of a heat engine for which the work output is $$2500 J/cycle$$ and the heat input is $$10000 J/cycle$$, is:
    Solution
    $$\textbf{Given:- }$$ The work output of the engine is,$$W = 2500 J/cycle$$
                      The heat input to the engine is, $$Q = 10000J/cycle$$

    $$\textbf{Solution:-} $$

    Express the relation for the efficiency of a thermal heat engine.

    $$\eta  = \dfrac{W}{Q} \times 100$$

    Here $$\eta$$ is the efficiency of the engine.

    Substitute $$2500 \ J/cycle$$ for W and $$10000 \ J/cycle$$ for Q to find the value of $$\eta .$$

    $$\eta  = \dfrac{{2500J/cycle}}{{10000J/cycle}} \times 100$$

    $$\eta  = \dfrac{{1J/cycle}}{{4J/cycle}} \times 100$$

    $$\eta  = 25$$%   or

    $$\eta  = 0.25$$

    $$\textbf{Hence the correct option is D}$$
  • Question 10
    1 / -0
    A closed system undergoes a change of state by process $$1\rightarrow 2$$ for which $${Q}_{12}=10J$$ and $${W}_{12}=-5J$$. The system is now returned to its initial state by a different path $$2\rightarrow 1$$ for which $${Q}_{21}$$ is $$-3J$$. The work done by the gas in the process $$2\rightarrow 1$$ is:
    Solution
    According to the question,
    $$ \triangle Q_1 = \triangle U + W_1$$
    $$\Rightarrow 10 = U_2 - U_1 + (-5)$$
    $$\Rightarrow U_2 - U_1 = 15J$$

    $$ \triangle Q_2 = \triangle U + W_2$$
    $$\Rightarrow -3 = U_1 - U_2 + W_2$$
    $$\Rightarrow -3= -15 + W_2$$
    $$W_2 = 12J$$
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