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Kinetic Theory Test - 25

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Kinetic Theory Test - 25
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  • Question 1
    1 / -0

    A car tyre has air at 1.5 atm at 300 K.If P increases to 1.75 atm with volume same, the temperature will be ____

    Solution
    HINT - Use ideal gas equation PV = nRT for the the cases.

    $$\textbf{Step 1:  Since n and R are constant, we get}$$
     Use ideal gas equation PV = nRT
    here n is number of moles.
    P is pressure, V is volume, R is gas constant and T is temperature.
    $$\dfrac{PV}{T}$$ = constant
    so, $$\dfrac{P_{1}V_{1}}{T_{1}} = \dfrac{P_{2}V_{2}}{T_{2}}$$
    Here,
    $$P_{1} = 1.5atm$$
    $$V_{1} = V_{2}$$
    $$T_{1} = 300K$$
    $$P_{2} = 1.75atm$$
    $$T_{2} = ?$$
    $$\textbf{Step 2: Putting all the values, we get : }$$
    $$ T_2 = \left( \dfrac{P_2 V_2}{P_1 V_1 } \right) T_1$$

    $$T_2=\dfrac{1.75}{1.5}\times 300$$

    $$=350\ K$$

    $${\textbf{Correct option: B}}$$
  • Question 2
    1 / -0

    The volume of a gas is 5 litres at N.T.P. what will be its volume at 273$$^{0}$$ C and at a pressure of four atmospheres 

    Solution
    from ideal gas equation,
    $$\frac{P_{1}V_{1}}{T_{1}}= \frac{P_{2}V_{2}}{T_{2}}$$
    Here,
    $$P_{1} = 1 atm$$
    $$V_{1} = 5 L$$
    $$T_{1} = 273 K$$
    $$P_{2} = 4 atm$$
    $$V_{2} =  ?$$
    $$T_{2} = 546 K$$
    putting all the values, we get $$V_{2}$$ = 2.5 L
    So, D is the correct answer.
  • Question 3
    1 / -0

    A gas at 27$$^{0}$$C and pressure of 30atm is allowed to expand to atmospheric pressure and volume 15 times larger. The final temperature of gas is

    Solution
    from ideal gas equation, PV = nRT
    So, $$T = \frac{PV}{nR}$$
    Since, n is constant, and R is also constant, we can say that T is directly proportional to the product of P and V
    $$T \alpha PV$$
    volume is made 15 times and pressure is reduced to $$\frac{1}{30}$$ th of it's original value (initial pressure = 30 atm and final pressure = 1 atm)
    So, temperature becomes 15 x $$\frac{1}{30}$$ times = 0.5 times it's initial value
    Initial temperature = 27$$^{\circ}$$C = 300K
    So, final temperature = 0.5 x 300 K = 150 K = -123 $$^{\circ}$$C
    So, B is the correct answer.

  • Question 4
    1 / -0

    At 20$$^{o}C$$ temperature and 1atmosphere pressure if a gas has a volume of 293 ml .Its volume at NTP is

    Solution
    from ideal gas equation, 

    $$\dfrac{P_{1}V_{1}}{T_{1}}= \dfrac{P_{2}V_{2}}{T_{2}}$$

    Here,
    $$P_{1} = 1 $$ atm

    $$V_{1} = 293 $$ ml

    $$T_{1} = 293$$ K

    $$P_{2} = 1 $$ atm

    $$V_{2} = ?$$

    $$T_{2} = 273K$$

    putting all the values, we get $$V_{2}$$ = 273 ml
    Hence, option $$B$$ is the correct answer.
  • Question 5
    1 / -0

    A sample of an ideal gas occupies a volume V at pressure P and absolute temperature T. The mass of each molecule is m. The equation for density is

    Solution
    let us derive the expression for the density of an ideal gas
    density = $$\dfrac{Mass}{Volume} = \dfrac{w}{V}$$
    Now from ideal gas equation, $$PV = nRT$$
    And n = $$\dfrac{w}{M}$$ where w is the mass of the gas and M is the molar mass of the gas
    Putting this in ideal gas equation, we get
    $$PV = \dfrac{w}{M}RT$$
    Now substitute the value of V in the density expression to get
    $$d = \dfrac{PM}{RT}$$
    So, D is the correct answer.
  • Question 6
    1 / -0

    The pressure of a gas is increased four times and its absolute temperature two times. The ratio of its final volume to its initial volume is

    Solution
    From ideal gas equation, PV = nRT
    So, this gives $$V = \frac{nRT}{P}$$
    so, V is proportional to absolute temperature and inversely proportional to the pressure of the gas
    Now temperature is made four times and pressure is made 2 times
    So, clearly the volume becomes half of it's original value.
    So, A is the correct answer.
  • Question 7
    1 / -0

    A cylinder contains gas at a pressure of 2.5 atm. Due to leakage, the pressure falls to 2 atm, after sometime. The percentage of the gas which is leaked out is

    Solution
    $$\frac { { P }_{ 1 } }{ { d }_{ 1 } } =\frac { { P }_{ 2 } }{ { d }_{ 2 } } \\ \frac { 2.5 }{ { d }_{ 1 } } =\frac { 2 }{ { d }_{ 2 } } \\ { d }_{ 2 }=0.8\times { d }_{ 1 }$$
    Volume escaped= $$\Delta d=\left( 1-0.8 \right) { d }_{ 1 }=0.2{ d }_{ 1 }\\ Percentage\quad decrease,\\ \frac { \Delta d }{ { d }_{ 1 } } \times 100=20$$
  • Question 8
    1 / -0

    The diagram shows the graphs of pressure vs density for a given mass of an ideal gas at two temperatures T$$_{1}$$ and T$$_{2}$$ :

    Solution
    $$PV= nRT$$
    $$P \propto \frac{1}{V}$$  is equivalent to $$P$$ $$\propto$$  $$d$$.
    The slope of P-d curve is proportional to temp
    From the diagram, the slopes are equal
    $$ \therefore$$ temp T is equal for both.
  • Question 9
    1 / -0

    A given amount of gas is heated until both its pressure and volume are doubled. If initial temperature is 27$$^{0}$$ C, its final temperature is

    Solution
    from ideal gas equation, PV = nRT
    So, $$T = \frac{PV}{nR}$$
    Since, n is constant, and R is also constant, we can say that T is directly proportional to the product of P and V
    $$T \alpha PV$$
    Since both volume and pressure are doubled, absolute temperature of the gas will become 4 times
    Initial temperature = 27$$^{\circ}$$C = 300K
    So, final temperature = 4 x 300K = 1200 K
    So, C is the correct answer.
  • Question 10
    1 / -0

    One litre of helium under a pressure of 2 atm and at 27$$^{0}$$C is heated until its pressure and volume are doubled. The final temperature attained by the gas is

    Solution
    from ideal gas equation, PV = nRT
    So, $$T = \frac{PV}{nR}$$
    Since, n is constant, and R is also constant, we can say that T is directly proportional to the product of P and V
    $$T \alpha PV$$
    Since both volume and pressure are doubled, absolute temperature of the gas will become 4 times
    Initial temperature = 27$$^{\circ}$$C = 300K
    So, final temperature = 4 x 300K = 1200 K = 927 $$^{\circ}$$ C
    So, B is the correct answer.

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