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Kinetic Theory Test - 26

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Kinetic Theory Test - 26
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  • Question 1
    1 / -0

    The volume of a gas at $$27^o$$C and 2 atmospheric pressure is 2 litres. If the pressure is doubled and absolute temperature is made half, the new volume of gas is

    Solution
    from ideal gas equation, PV = nRT
    So, this gives $$V = \frac{nRT}{P}$$
    so, V is proportional to absolute temperature and inversely proportional to the pressure of the gas
    Now temperature is made half and pressure is made 2 times
    So, clearly the volume becomes one-fourth of it's original value.
    So, B is the correct answer.
  • Question 2
    1 / -0

    A closed vessesl contains 8 gms of oxygen and 7gm of Nitrogen. Total pressure at a certain temperature is 10 atm. When all the oxygen is removed from the system without chage in temperature then the pressure will be

    Solution
    $$\dfrac { { P }_{ 1 } }{ { P }_{ 2 } } =\dfrac { { m }_{ 1 }{ M }_{ 2 } }{ { m }_{ 2 }{ M }_{ 1 } } \\ \\ \dfrac { { P }_{ 1 } }{ { P }_{ 2 } } =\dfrac { 8\times 14 }{ 7\times 32 } \\ { P }_{ 1 }=10\times \dfrac { 8 }{ 16 } $$
  • Question 3
    1 / -0

    The volume occupied by 8 gm of oxygen at S.T.P. is

    Solution
    32 gm of oxygen = 1 mole = 22.4lit (standard result according to gas governing equation)
    8 gm of oxygen = 1/4 mole = 22.4/4 = 5.6lit
  • Question 4
    1 / -0

    An air bubble rises from bottom to top of a liquid of density 1.5 g/cm$$^{3}$$. If its volume is doubled, the depth of liquids is

    Solution
    In this case, $$(P + \rho g h) V$$ $$=$$  $$2V P$$
    where, $$P$$ $$=$$ atm pressure
    $$\rho$$ $$=$$ density of the liquid
    $$h$$ $$=$$ height of the lake
    $$V$$  $$=$$ volume of the bubble
    Solving we get,
    $$h$$  $$=$$ $$\dfrac{P}{\rho g}$$
    here, $$P$$ $$=$$ 76 X 13.6 X 9.8
    $$\rho$$  $$=$$ 1.5 $$gm/cm^{3}$$ $$=$$ 1500 $$kg/m^{3}$$
    Putting these values we get, $$h$$ $$=$$ 689 cm
  • Question 5
    1 / -0

    If pressure of an ideal gas contains in a closed vessel is increased by 0.5% the increase in temperature is 20k the initial temperature of the gas is

    Solution
    In this case,
    $$P_1 = P$$, $$P_2= 1.05P$$
    $${T_1} = T$$, $$T_2 = T+20$$
    Putting these values in $$\dfrac{P_1}{T_1}= \dfrac{P_2} {T_2}$$  we get, T = 400 or T = $$127^o$$C
  • Question 6
    1 / -0

    Two closed vessels of the equal volume contain air at 105kPa at 300K and are connected through a narrow tube. If one of the vessels is now maintained at 300K and the other at 400K then the pressure becomes.

    Solution
    In this case, let the initial pressure = P and final pressure = P'. Since (P/T) = constant, considering the system of two spheres of equal volume, we get,
    $$\dfrac{P}{300} + \dfrac{P}{300} = \dfrac{P'}{300} + \dfrac{P'}{400}$$
    here, P = 105k Pa
    Solving we get, $$P' = 120 kPa$$
      
  • Question 7
    1 / -0

    At the top of a mountain a thermo meter read 7$$^{0}$$ C and barometer reads 70 cm of Hg. At the bottom of the mountain the barometer reads 76cm of Hg and thermometer reads 27$$^{0}$$ C. The density of air at the top of mountains is ______ times the density at the bottom.

    Solution
    $$\dfrac{P_1}{d_1T_1}=\dfrac{P_2}{d_2T_2}$$ (Standard equation of governance)
    Dirctly putting up the value,
    $$ \therefore \dfrac{70}{d_1\times ( 7+273)} = \dfrac{76}{d_2\times(27+ 273)}$$
    $$\dfrac{d_1}{d_2} = \cfrac{75}{76}=0.987$$
  • Question 8
    1 / -0

    At a given temperature and pressure 64 gm of Oxygen and X gm of H$$_{2}$$ occupy the same volume. Then x= ......gm

    Solution
    Since they occupy same volume, the two gases should contain same number of molecules, i.e. they have same number of moles.
    Now 1 mole of oxygen = 32gm.
    Hence 64 gm = 2 mole of oxygen.
    $$\therefore $$ number of moles of hydrogen is 2.
    1 mole of hydrogen= 2gm
    Hence X= 4gm
  • Question 9
    1 / -0

    A one litre sphere and a two litre sphere are connected with a capillary tube of negligible volume. They contain an ideal gas at 27$$^{0}$$C at a pressure of 100cm of Hg. Keeping the temperature of one litre sphere constant at 27$$^{0}$$C, if temperature of two litre sphere is increased to 127$$^{0}$$C, then the final pressure is

    Solution
    Moles of gas in 1L sphere before increasing temperature $$=\dfrac{P_0 V}{RT}$$

    Moles of gas in 2L sphere before increasing temperature $$=\dfrac{P_0 (2V)}{RT}$$

    Moles of gas in 1L sphere after increasing temperature $$=\dfrac{PV}{RT}$$
    Moles of gas in 2L sphere after increasing temperature $$=\dfrac{P (2V)}{R(T+100)}$$
    Since the total number of moles remain the same,
    $$\dfrac{P_0V}{RT}+\dfrac{2P_0 V}{RT}=\dfrac{PV}{RT}+\dfrac{2PV}{R(T+100)}$$
    Hence, $$P=P_0 (\dfrac{3(T+100)}{3T+100})$$
    $$T=300K$$, $$P_0=100cm Hg$$
    $$\implies P=120cm Hg$$
  • Question 10
    1 / -0

    At the bottom of a lake where the temperature is $${7}^{0}\,C$$ the pressure is $$2.8$$ atmosphere. An air bubble of radius $$1\, cm$$ at the bottom rises to the surface. Where the temperature is $${27}^{0}\, C$$. The radius of the air bubble at the surface is

    Solution
     We know that, by gas law
    $$\dfrac { { P }_{ 1 }{ V }_{ 1 } }{ { T }_{ 1 } } =\dfrac { { P }_{ 2 }{ V }_{ 2 } }{ { T }_{ 2 } } $$
    $$\dfrac { 2.8{ \times V }_{ 1 } }{ 280 } =\dfrac { 1\times { V }_{ 2 } }{ 300 } $$
    $${ V }_{ 2 }=3{ V }_{ 1 }$$
    $$R\propto { V }^{ \dfrac { 1 }{ 3 }  }$$
    $$\therefore { R }_{ 2 }={ { 3 }^{ \dfrac { 1 }{ 3 }  }R }_{ 1 }$$
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