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Kinetic Theory Test - 29

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Kinetic Theory Test - 29
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  • Question 1
    1 / -0

    A flask is filled with 13 gm of an ideal gas at 27$$^{0}$$C its temperature is raised to 52$$^{0}$$C . The mass of the gas that has to be released to maintain the temperature of the gas in the flask at 52$$^{0}$$C and the pressure remaining the same is

    Solution
    Since P, V , M and R are constants,
    $${ m }_{ 1 }{ T }_{ 1 }={ m }_{ 2 }{ T }_{ 2 }\\ 13\times 300={ m }_{ 2 }\times 325\\ { m }_{ 2 }=12gm$$
    Hence mass to be removed = 13-12= 1gm
  • Question 2
    1 / -0

    At what temperature will the hydrogen molecules escape from Earth's surface?

    Solution
    We have the escape velocity as $$v_e=11.2  km/s$$, boltzmann constant as $$1.38\times 10^{-23}  m^2kgs^{-2}K^{-1}$$and molecular mass of hydrogen as $$2\times 1.66\times 10^{-27}  amu $$
    We have the formula as 
    $$\dfrac{3}{2}kT=\dfrac{1}{2}mv_e^2$$
    or
    $$T=\dfrac{mv_e^2}{3k}=\dfrac{2\times 1.66\times 10^{-27}\times 11.2^2\times 10^6}{3\times 1.38\times 10^{-23}}=10^4  K$$
  • Question 3
    1 / -0

    During an experiment an ideal gas is found to obey an additional gas law VT =constant. The gas is initially at temperature T and pressure P. When it is heated to the temperature 2T, the resulting pressure is

    Solution
    The gas follows VT=constant. But it also follows PV=nRT.
    Thus $$(\dfrac{nRT}{P})T=$$constant
    $$\implies \dfrac{T^2}{P}=$$constant
    Therefore $$\dfrac{T^2}{P}=\dfrac{(2T)^2}{P'}$$
    $$\implies P'=4P$$
  • Question 4
    1 / -0

    If the pressure of a gas contained in a closed vessel increases by x% when heated by 1$$^{0}$$C its initial temperature is

    Solution
    Let the initial pressure and temperature be P and T.
    From Ideal Gas Law,
    $$P\propto T$$
    $$\implies \dfrac{(1+\dfrac{x}{100})P}{P}=\dfrac{T+1}{T}$$
    • $$\implies T=\dfrac{100}{x}K$$
  • Question 5
    1 / -0

    The average kinetic energy of hydrogen molecule at NTP will be

    Solution
    Average kinetic  energy:
    $$KE_{avg}= \frac{3}{2}kT$$
    $$=\dfrac{3}{2}\times 1.38 \times 10^{-23} \times 293$$
    $$=0.40 \times 10^{-20}J$$
    where k is Boltzman's constant and $$T=(20 + 273)^{\circ}K= 293K$$
  • Question 6
    1 / -0

    The pressure of a certain mass of gas at 27$$^{0}$$is 84cm of Hg. If 25% of the gas is now introduced into the same vessel at the same temperature, the final pressure of the gas will be in cm of Hg

    Solution
    Pressure=$$h\rho g=\dfrac{nRT}{V}$$
    $$\implies h\propto n\propto m$$
    Therefore $$\dfrac{h_2}{h_1}=\dfrac{1.25m_{0}}{m_0}$$
    $$\implies h_2=1.25h_1=105cm$$
  • Question 7
    1 / -0
    A cycle tube has volume $$2000 cm^3$$. Initially the tube is filled to 3/4th of its volume by air at pressure of $$105 N/m^{2}$$. It is to be inflated to a pressure of $$6 \times 10^{5} N/m^{2}$$ under isothermal conditions. The number of strokes of pump, which gives $$500 cm^3$$ air in each stroke, to inflate the tube is
    Solution
    In this problem, let us conserve total number of moles before and after,

    $$(6X{ 10 }^{ 5 })(2000)=(105)(1500)+(101325)(500)n$$

    Where n is total number of strokes of pump.
    Solving this equation given $$n\approx21$$.
  • Question 8
    1 / -0

    If the number of degrees of freedom of a gas is f, then the value of $$\gamma $$ will be

    Solution
    $$\gamma= \dfrac{2+f}{f}=1 + \dfrac{2}{f}$$ where $$\gamma= \dfrac{C_p}{C_v}$$ and f is the no of degrees  of freedom.
  • Question 9
    1 / -0

    The total kinetic energy of $$8$$ litres of helium molecules at $$5 $$ atmosphere pressure will be

    Solution

  • Question 10
    1 / -0

    A uniform tube with piston in the middle and containing a gas at 0$$^{0}$$C is heated to 100$$^{0}$$C at one side . If the piston moves 5 cm, find the length of the tube containing the gas at 100$$^{0}$$C.

    Solution
    As $$\dfrac{PV}{T}$$ is constant for gas in both sections of the cylinder.
    Let the length and area of the tube be $$L$$ and $$A$$, respectively.
    For section with constant temperature,
    $$P_{0}V_{0}=P_1V_1$$
    $$\implies P_ (A\dfrac{L}{2})=P_1(A(\dfrac{L}{2}-5))$$
    Initial temperature  $$T_0 = 0^oC = 273 \textrm{K}$$
    Final temperature  $$T_1 = 100^oC = 100+273 = 373 \textrm{K}$$
    Similarly for section whose temperature increased,
    $$\dfrac{P_0V_0}{T_0}=\dfrac{P_1V_1}{T_1}$$
    $$\implies \dfrac{P_0(A\dfrac{L}{2})}{273}=\dfrac{P_1(A(\dfrac{L}{2}+5))}{373}$$
    $$\implies L=65cm$$
    So the length of tube containing gas at $$100^{\circ}$$ is $$\dfrac{L}{2}+5=37.5cm$$
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