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Kinetic Theory Test - 51

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Kinetic Theory Test - 51
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  • Question 1
    1 / -0
    An insulated box containing monatomic ideal gas of molar mass M is moving with a uniform speed v. The box suddenly stops and consequently the gas acquires a new temperature. Calculate the change in the temperature of the gas. Neglect heat absorbed by the box.
    Solution
    An insulated Box containing monoatomic ......... neglect heat absorbed by box
    molar mass$$=M$$
    speed $$=v$$
    Initial energy $$=KE=\dfrac{1}{2}MV^{2}$$
    Final energy = Temperature energy (or $$PE$$)
    $$=\dfrac{3}{2}RT$$
    For ideal conditions, $$\dfrac{1}{2}, mv^{2}=\dfrac{3}{2}RT$$
    $$\Delta T=\dfrac{mv^{2}}{3R}$$
  • Question 2
    1 / -0
    A gas molecule of mass $$M$$ at the surface of the earth has kinetic energy equivalent to $${0}^{o}C$$. If it were to go up straight without colliding with any other molecules, how high it would rise? Assume that the height attained is much less than radius of the earth. ($${k}_{B}$$ is Boltzmann constant)
    Solution

  • Question 3
    1 / -0
    An ideal gas having initial pressure P, volume V and temperature T is allowed to expand adiabatically until its volume becomes $$5.66$$V while its temperature falls to $$T/2$$. How many degrees of freedom do the gas molecules have?
    Solution
    Adiabatic equation of perfect gas is given as $$TV^{r-1}=$$ constant
    $$m=T_{1}V_{1}^{(r-1)}=T_{2}V_{2}^{(r-1)}$$
    $$T_{1}=T_{1}V_{1}=V_{1}V_{2}=5.66\ V$$
    and $$T_{2}=\dfrac{T}{2}$$
    $$TV^{r-1}=\dfrac{T}{2}(5.66\ V)^{r-1}$$
    $$2=5.66^{r-1}$$
    Taking $$\log$$ on both sides
    $$(r-1)\log 5.66=\log 2(r-1)$$
    $$r=\dfrac{\log 2}{\log 5.66}=1+0.3010/0.75$$
    $$r=1+0.4$$
    $$r=1.4$$ for $$r=1.4$$ Agree of freedom $$=5$$
  • Question 4
    1 / -0
    A gas performs Q work when it expand at constant pressure. During this process heat absorbed by the gas is 4Q. The average number of degrees of freedom for the gas is:
    Solution
    $$Given:$$ A gas performs $$Q $$ work when it expand at constant pressure. During this process heat absorbed by the gas is $$4Q.$$
    $$Solution:$$ In a isobaric process, 
    $$U=4 Q-Q=n C_{v} d T=3 Q$$
    Work = $$n R dT$$ So, U/Work $$=\mathrm{C}_{\mathrm{v}} / \mathrm{R}$$
    $$3=\mathrm{C}_{\mathrm{v}} / \mathrm{R}$$
    $$R=C_{p}-C_{v}$$
    $$3=\dfrac{C_{v}}{C_{p}-C_{v}}$$
    $$\dfrac{C_{p}}{C v}=4 / 3=\gamma$$
    $$\gamma=1+\frac{2}{f}$$
    where f is degree of freedom $$4 / 3=1+\frac{2}{f}$$
    $$f=6$$
    $$So, the$$ $$correct$$ $$option: B$$
  • Question 5
    1 / -0
    Two monatomic ideal gases $$1$$ and $$2$$ of molecular masses $$m_1$$ and $$m_2$$ respectively are enclosed in separate containers kept at the same temperature. The ratio of the speed of sound in gas $$1$$ to that in gas $$2$$ is given by.
    Solution
    $$V_{rm}=\sqrt {\dfrac {rRT}{m}}$$
    i.e $$vr\dfrac {1}{\sqrt m}$$
    which given $$v-1\times \dfrac {1}{\sqrt {m_1}}$$ and $$v_2\times \dfrac {1}{\sqrt {m_1}}$$
    $$\dfrac {v_1}{v_2}=\sqrt {\dfrac {m_2}{m_1}}$$
  • Question 6
    1 / -0
    An ideal gas is initially at $$P_1$$, $$V_1$$ is expanded to $$P_2, V_2$$ and then compressed adiabatically to the same volume $$V_1$$ and pressure $$P_3$$. If W is the net work done by the gas in the complete process which of the following is true.

    Solution
    Since work is done by the gas as area under the graph is $$-ve$$ ( anticlockwise) ie energy is lost by the gas and $$w<0$$ when $$P_3>P_1$$.
  • Question 7
    1 / -0
    One kg of a diatomic gas is at a pressure of $$8\times {10}^{4}N/{m}^{2}$$. The density of gas is $$4kg/{m}^{2}$$. What is the energy of the gas due to its thermal motion?
    Solution

  • Question 8
    1 / -0
    A gas thermometer measures the temperature from the variation of pressure of a sample of gas. If the pressure measured at the melting point of lead is $$2.20\ times$$ the pressure measured at the triple point of water find the melting point of lead.
    Solution

    $$\textbf{Correct option: Option (A).}$$

    $$\textbf{Explanation:}$$

    Given, the pressure at melting point is 2.20 times the pressure at triple point of water.

    $${{P}_{MP}}=2.20\times {{P}_{TP}}$$

    We know that, Melting point, $$MP=\dfrac{{{P}_{MP}}}{{{P}_{TP}}}\times 273.16K$$

    $$\Rightarrow MP=\dfrac{2.20\times {{P}_{TP}}}{{{P}_{TP}}}\times 273.16\approx 600K$$

    $$\textbf{So, correct option is (A).}$$
  • Question 9
    1 / -0
    Ratio of $$C_P$$ and $$C_V$$ of gas '$$X$$' is 1.4. The number of atoms of the gas '$$X$$' present in $$11.2$$ litres of at NTP will be:
    Solution
    $$\dfrac{C_p}{C_v} = \gamma = 1.4$$

    Hence, the gas is diatomic.
    Number of atoms $$=$$ atoms in one molecule of gas $$\times$$ mole$$\times N_A$$ 
                                  $$= 2 \times \dfrac{V}{22.4} \times N_A$$ 
                                  $$= 2 \times \dfrac{11.2}{22.4}\times 6.02\times 10^{23} = 6.02\times 10^{23}$$  
                                

  • Question 10
    1 / -0
    The average thermal energy of a oxygen atom at room temperature $$(27^{o}C)$$
    Solution
    Boltzman's constant is given as $$k=1.38 \times 10^{-23} J/k$$ 
    Average kinetic energy will be $$KE=\dfrac{FkT}{2}$$
    Where $$F$$ is degree of freedom which will be $$3$$ because $$O$$ is a mono-atomic molecule.
    Temperature, $$T=27+273=300K$$
    So energy=$$\dfrac{3 \times 1.38 \times 10^{-23} \times  300}{2}=6.2\times 10^{-21} Joule$$
    Option B is correct.
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