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Kinetic Theory Test - 52

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Kinetic Theory Test - 52
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  • Question 1
    1 / -0
    The kinetic energy of $$ 1g $$ molecule of a gas at normal temperature and pressure is :
    Solution

    There is no information about gas so the translational kinetic energy is given as,

    $$K = \dfrac{3}{2}RT$$

    $$ = \dfrac{3}{2} \times 8.31 \times \left( {273 + 0} \right)$$

    $$ = 3.4 \times {10^3}\;{\rm{J}}$$

    Thus, the kinetic energy of a gas molecule is $$3.4 \times {10^3}\;{\rm{J}}$$.

  • Question 2
    1 / -0

    In an experiment, 1.35 mol of oxygen (O2) are heated at constant pressure starting at 11.0ºC. How much heat must be added to the gas to double its volume?

    Solution
    Since oxygen $$(O_2)$$ is a diatomic gas
    $$\therefore C_v=5/2R$$
    So, $$C_p=C_v+R\\ \quad=5/2R+R\\ \quad =7/2R$$
    At constant pressure
    If we double the volume the temperature will be doubled.
    $$T_i=11.0°C=(11.0+273)K=284K$$
    So, $$T_p=2(284)K=568K$$
    To obtain heat, $$Q=nC_p(T_p-T_i)$$
    $$Q=(1.35mol)(7/2R)(508K-284K)\\Q=1.12\times10^4J$$

  • Question 3
    1 / -0
    $$m$$ grams of a gas of molecular weight $$M$$ is flowing in an insulated tube with velocity $$v$$. If the system is suddenly stopped then the rise in its temperature will be (γ= ratio of specific heats, R=universal gas constant, J=Mechanical equivalent of heat)
    Solution

  • Question 4
    1 / -0
    Two cylinders contain the same amount of ideal monatomic gas. The same amount of heat is given to two cylinders. If the temperature rise in cylinder A is $$T_0$$ then temperature rise in cylinder B will be :

    Solution
    $$Q=nC_vT_0$$
    $$Q_A=nC_p\triangle T_A$$
    $$Q_B=nC_v\triangle T_B$$
    $$Q_A=Q_B$$
    $$nC_pT_0=nC_v\triangle T$$
    $$\triangle T=T_0\times \dfrac{C_p}{C_v}$$
    $$=T_0\times \dfrac{5}{3}.$$
    Hence, the answer is $$\dfrac{5}{3}T_0.$$
  • Question 5
    1 / -0
    By the ideal gas law, the pressure of $$0.60$$ moles $${NH}_{3}$$ gas in a $$3.00\ L$$ vessel at $${25}^{o}C$$ is, given that $$R=0.082\ L$$ atm $${mol}^{-1}{k}^{-1}$$:
    Solution
    Pressure is given as $$P=\dfrac{nRT}{V}=\dfrac{0.6\times .082\times (25+273)}{3}=4.89atm$$
    Option B is correct.
  • Question 6
    1 / -0
    Mean kinetic energy (or average energy) per gm. of a molecule of a monoatomic  gas is given by :
    Solution

  • Question 7
    1 / -0
    Valency of carbon is 44. From this, we understand that there are ____chemical bond/bonds between the carbon atom and one oxygen atom in the compound-carbon dioxide.
    Solution
    there are 2 chemical bonds between the carbon atom and each oxygen atom
    in this way as the 2 oxygen atoms form 2 bonds each , the valency of oxygen is satisfied 
    as the carbon atom forms 4 bonds in total with the 2 oxygen atoms , its valency is also satisfied 
  • Question 8
    1 / -0
    If temperature of body increases by 10%, then increase in radiated energy of the body is :
    Solution

  • Question 9
    1 / -0
    RMS velocity of an ideal gas at $$27^o C$$ is $$500{m/s}$$, Temperature is increased four times, RMS velocity will become.
    Solution
    $$V_{rms}=\sqrt{\cfrac{3RT}{M}}=500$$ $${m/s}$$
    $$V_{rms}^{\prime}=\sqrt{\cfrac{3RT^{\prime}}{M}} =\sqrt{\cfrac{3R(4T)}{M}}$$
    $$V_{rms}^{\prime}=2\sqrt{\cfrac{3RT}{M}}=2V_{rms}=1000$$ $${m/s}$$
  • Question 10
    1 / -0
    The amount of heat energy required to raise the temperature of $$1\ g$$ of helium in a container of volume $$10L$$, from $$T_{1}\ K$$ to  $$T_{2}\ K$$ is ($$N_{a} =$$ Avogadros number, $$k_{B}=$$ Boltzmann constant)
    Solution
    The process is being completed at a constant volume because the volume of the container is fixed.
     so the heat energy required will be $$Q=nC_v \Delta T$$
    Where $$C_v$$ is specific heat at constant volume and $$n$$ is number of moles given by $$n=\dfrac{1gm}{4gm/mole}=\dfrac{1}{4}mole$$
    and the specific heat is given as $$C_v=\dfrac{fN_ak_B}{2}$$
    The degree of freedom, $$f$$ has value $$3$$ for a mono-atomic gas.
    $$N_a$$ is Avogadro Number and $$k_B$$ is Boltzman's constant 
    putting all above  values in the expression for $$Q$$ we get $$Q=\dfrac{3}{8}N_ak_B \Delta T=\dfrac{3}{8}N_ak_B(T_2 -T_1)$$
    Option D is correct.
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