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Kinetic Theory ...

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  • Question 1
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    Two blocks of the same metal having the same mass and at temperature $$T_1$$  and $$T_2$$, respectively. are brought in contact with each other and allowed to attain thermal equilibrium at constant pressure. The change in entropy, $$\Delta S$$, for this process is :

  • Question 2
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    An ideal gas in a container of volume $$500c.c.$$ is at a pressure of $$2\times 10^5Nm^{-2}$$. The average kinetic energy of each molecule $$6\times 10^{-21}J$$. The number of gas molecules in a container is:

  • Question 3
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    One mole of monoatomic gas is carried along process ABCDEA as shown in the diagram.Find the net work done by gas.

  • Question 4
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    At 323 K, the vapour pressure in millimeters of mercury of a methanol-ethanol solution is represented by the equation $$p=120{ x }_{ A }+140$$,where $${ x }_{ A }$$ is the mole fraction of methanol. Then the value of $$\lim _{ { X }_{ A }\rightarrow 1 }{ \frac { { P }_{ A } }{ { X }_{ A } }  } $$

  • Question 5
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    From the following data of $$\Delta H$$, of the following reactions, 


    $$C(s) + \dfrac{1}{2}O_2 (g) \rightarrow CO (g)$$         $$\Delta H = -110 kJ$$

    $$C(s) + H_2O (g) \rightarrow CO (g) + H_2 (g)$$    $$\Delta H = 132 kJ$$ 
     
    What is the mole composition of the mixture of steam and oxygen on being passed over a coke at 1273 K, keeping temperature constant?              

  • Question 6
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    Three lawn chairs, one made up of aluminium (heat capacity $$= 0.90\ J/K-g$$), one of iron (heat capacity $$= 0.45\ J/K-g$$) and one of tin (heat capacity$$ = 0.60\ J/K-g$$) are painted of the same colour. On a sunny day which chair will be hotter to sit?

  • Question 7
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    One kg of a diatomic gas is at a pressure of $$ 8\times 10^{4}\mathrm{N}/\mathrm{m}^{2}$$. The density of the gas is 4 $$\mathrm{k}\mathrm{g}/\mathrm{m}^{3}$$. The energy of the gas due to its thermal motion will be

  • Question 8
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    Three closed vessels A, B and C are at the same temperature T and contain gases which obey the Maxwellian distribution of velocities, Vessel A contains only $${ O }_{ 2 }$$ B only $${ N }_{ 2 }$$ and C a mixture of equal quantities of $${ O }_{ 2 }$$ and  $${ N }_{ 2 }$$ If the average speed of the $${ O }_{ 2 }$$ molecules in vessel A is $${ V }_{ 1 }$$, that of $$N_{ 2 }$$ molecules in vessel B is $$V_{ 2 }$$ the average speed of the $$O_{ 2 }$$ molecules in vessel C is ( where M is the mass of an oxygen molecule) 

  • Question 9
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    The value of universal gas constant is $$R=8.3$$ J/K - mol. The value of $$R$$ in atmosphere litre per kelvin mol

  • Question 10
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    For monoatomic gas the relation between pressure of a gas and temperature T is given by $$P_\alpha T^C$$. Then value of C will be : (For adiabatic process)

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