Hint: Those reactions in which the catalyst exists in the
same phase as reactants is called homogeneous catalysis.
Step 1: Ostwald’s Process:
In
Ostwald’s process ammonia gas reacts with oxygen in the presence of platinum
as a catalyst to produce nitric acid. Ammonia and oxygen both reactants
are present in the gaseous phase but platinum is present in the solid phase. Thus
the reactants and catalysts are present in different phases so it is an example
of heterogeneous catalysis
Step 2: Lead chamber process :
In the Lead chamber process sulfuric acid is produced by oxidizing sulfur dioxide with moist air in the presence of nitrogen oxide as a catalyst. So here $$SO_2$$ is present in the gaseous phase and
$$NO$$ is also present in the gas phase. Thus the reactants and catalysts are present
in the same phase so it is an example of homogeneous catalysis
Step 3: Haber's process :
In
Haber’s process nitrogen gas reacts with hydrogen gas in the presence of iron
as a catalyst to produce ammonia. So here nitrogen and hydrogen both reactants
are present in the gaseous phase but iron is present in the solid phase. Thus
the reactants and catalysts are present in different phases so it is an example
of heterogeneous catalysis.
Step 4: Contact process
In the Contact process, $$H_2SO_4$$ acid is produced by the reaction of sulphur dioxide
in the presence of $$V_2O_5$$ as the catalyst. So here Sulphur dioxide is present
in the gaseous phase and $$V_2O_5$$ is
present in the solid phase. Thus the reactants and catalysts are present in
different phases so it is an example of heterogeneous catalysis.
Final Step: Correct option is (B)-Lead Chamber process.