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The d- and f- B...

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  • Question 1
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    What would happen when a solution of potassium chromate is treated with an excess of dilute nitric acid?

  • Question 2
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    In $${Cr_{2}O_{7}}^{2-}$$ ion, the maximum number of bonds having the same Cr - O bond length is :

  • Question 3
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    Which of the following pairs has almost same colour?

  • Question 4
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    The increasing order of paramagnetism of the following compound is:

    (I)$$MnSO_{4}.4H_{2}O  $$

    (II)$$FeSO_{4}.7H_{2}O $$

    (III)$$   NiSO_{4}.6H_{2}O$$

    (IV)$$CuSO_{4}.5H_{2}O$$

  • Question 5
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    Directions For Questions

    The presence of incompletely filled d- and f-orbitals is mainly responsible for colour of transition metals and inner transition metals. The para and diamagnetic behaviour of the metals is again due to the presence or absence of unpaired electrons in their d or f levels. In some cases, colour may appear due to charge transfer rather than d-d transition.
    The energy gap between 4f and 5d subshells is large, while the same between 5f, 6d and 7s levels is relatively small.

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    Statements that are true of d-and f-block elements are:

    1. The colour of $$K_{2}Cr_{2}O_{7}$$ is due to d-d transition.

    2.  Actinides have larger number of oxidation states than lanthanides.

    3.  Tripositive ions of $$Pr(At. No. =59)$$ and $$Tm(At. No. =69)$$ have the same (green) colour.

    4.  Actinides have paramagnetic moments less than theoretically predicted values.

  • Question 6
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    Directions For Questions

    Lanthanides and actinides are strongly paramagnetic. Lanthanide ions have high charge (+3) but have large size resulting in small charge to size ratio (low charge density). In actinides 5f electrons are far too diffused than 4f electrons in lanthanides. There is a very small energy gap between 5f, 6d and 7s electrons. All these factors influence the physical and chemical properties of lanthanides and actinides.

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    Regarding the magnetic properties of lanthanides and actinides the correct statement is:

  • Question 7
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    The actinoids exhibit more number of oxidation states in general than lanthanoids because: 

  • Question 8
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    Dipositive and tripositive ions of A and B possess same number of electron pairs, but different number of unpaired electrons. Both are paramagnetic. Identify the atomic numbers of A and B.

  • Question 9
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    Atoms of the transition element are smaller than those of the s-block elements. This is because of  :

  • Question 10
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    The value of the magnetic moment of a particular ion is 2.83 Bohr magneton. The ion is :

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