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Coordination Compounds Test - 42

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Coordination Compounds Test - 42
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  • Question 1
    1 / -0
    $$[Co(NH_3)_4Cl_2]^+$$ exhibits 
    Solution
    $$[Co(NH_3)_4Cl_2]^+$$ is $$Ma_4b_2$$ type complex which show geometrical isomerism.

  • Question 2
    1 / -0
    Ferrous Oxide is 
    Solution
    Ferrous Oxide is $$FeO$$.
    Hence, Option "A" is the correct answer.
  • Question 3
    1 / -0
    Correct formula of Potassium Ferricyanide is
    Solution
    Potassium Ferricyanide is $$ K_3[Fe(CN)_6] $$.
    Hence, Option "B" is the correct answer.
  • Question 4
    1 / -0
    The complex compounds which result from the coordination of carbon monoxides are known as
    Solution
    The complex compounds which result from the coordination of carbon monoxides are known as carbonyl compound.

    Example: $$Fe(CO)_5, Ni(CO)_4, $$ etc.
  • Question 5
    1 / -0
    Mohr's salt is
    Solution
    Mohr's salt is $$ (NH_4)_2 SO_4 . FeSO_4 . 6H_2 O $$.
    Hence, Option "C" is the correct answer.
  • Question 6
    1 / -0
    Formula of ferric sulphate is 
    Solution
    Ferric Sulphate is Iron (III) Sulphate i.e $$ Fe_2(SO_4)_3 $$.
    Hence, Option "D" is the correct answer.
  • Question 7
    1 / -0
    $$[Co(NH_3)_4Cl_2]NO_2$$ and $$[Co(NH_3)_4Cl.NO_2]Cl$$ are ___________ isomers.
    Solution
    Both produce different ions in solution state so they are ionisation isomer.

    $$[Co(NH_3)_4Cl_2]NO_2 \rightleftharpoons [Co(NH_3)_4Cl_2]^+ +NO_2^-$$

    $$[Co(NH_3)_4Cl. NO_2]Cl \rightleftharpoons [Co(NH_3)_4Cl. NO_2]^+ +Cl^-$$
  • Question 8
    1 / -0
    The primary valence of the metal ion in the co-ordination compound $$K_2[Ni(CN)_4]$$ is
    Solution
    Primary valencies are also known as the oxidation state of the central metal atom.

    $$K_2[Ni(CN)_4]$$. Let $$x$$ be the oxidation state of Ni.

    Now, 

    $$2\times1+x+4\times(-1)=0;\quad \Rightarrow x=+2$$
  • Question 9
    1 / -0
    The number of neutral molecules or negative groups attached to the central metal atom in a complex ion is called
    Solution
    The number of neutral molecules or negative groups attached to the central metal atom in a complex ion is called coordination number.

    Example: In $$[Ni(CO)_4],$$ coordination number is 4.  
  • Question 10
    1 / -0
    In $$K_4 Fe(CN)_6$$
    Solution
    $$(CN)$$ are linked with secondary valency to the central Fe metal ion. Ligand (CN) is linked to the central atom via a dative bond.

    $$K_4[Fe(CN)_6]\to 4K^++[Fe(CN)_6]^{4-}$$
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