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Biomolecules Test - 6

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Biomolecules Test - 6
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  • Question 1
    1 / -0.25

     

    Glucose reacts with acetic anhydride to form:

     

    Solution

     

     

    It forms glucose pentaacetate. The acetic anhydride esterifies with all the alcohol groups on the glucose ring.

     

     

  • Question 2
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    What does the following reaction of glucose with HI elucidates about the structure of glucose?

     

    Solution

     

     

    Reaction of glucose with HI forms hexane. This reaction shows the presence of six carbons linked linearly in glucose.

     

     

  • Question 3
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    The Molisch test is a chemical test that determines the presence of:

     

    Solution

     

     

    The Molisch test uses concentrated sulphuric acid as the dehydrating acid. This acid dehydrates all  carbohydrates, so the test is used to distinguish between carbohydrates and non-carbohydrates. 

     

     

  • Question 4
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    What does the following reaction shows about the structure of glucose?

     

    Solution

     

     

    The correct answer is Option A.
     
    Glucose gets oxidized to cyanohydrin in reaction with HCN . This indicates that the carbonyl group is present as an aldehydic group.

     

     

  • Question 5
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    Which among the following is a non-reducing sugar?

     

    Solution

     

     

    Non-reducing sugars do not have an OH group attached to the anomeric carbon so they cannot reduce other compounds. All monosaccharides such as glucose are reducing sugars. A disaccharide can be a reducing sugar or a non-reducing sugar. Maltose and lactose are reducing sugars, while sucrose is a non-reducing sugar.

     

     

  • Question 6
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    Which of the following carbohydrates is called an invert sugar?

     

    Solution

     

     

    It is called invert sugar because the angle of the specific rotation of the plain polarized light changes from a positive to a negative value due to the presence of the optical  isomers  of the mixture of  glucose  and  fructosesugars.

     

     

  • Question 7
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    What is the relation between the following pairs of monosaccharides?

     

    Solution

     

     

    The pairs of optical isomers which differ in configuration around any other C atom other than C1   atom are called epimers. D-glucose and D-mannose are C2 epimers.

     

     

     

  • Question 8
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    Hydrolysis of sucrose is called:

     

    Solution

     

     

     

    Hydrolysis of sucrose to give glucose and fructose is called inversion. hydrolysis of sucrose brings about a change in the sign of rotation, from dextro (+) to laevo (–) and the product is named as invert sugar.

     

     

  • Question 9
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    Which of the following carbohydrate is an example of an oligosaccharide?

     

    Solution

     

     

    Lactose intolerance is the inability to break down a type of natural sugar called lactose. Lactose is commonly found in dairy products, such as milk and yogurt. A person becomes lactose intolerant when his or her small intestine stops making enough of the enzyme lactase to digest and break down the lactose.

     

     

  • Question 10
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    Sucrose is a non-reducing sugar because:​

     

    Solution

     

     

    Sucrose is a non-reducing sugar because the two monosaccharide units are held together by a glycosidic linkage between C1  of α-glucose and C2  of β-fructose. Since the reducing groups of glucose and fructose are involved in glycosidic bond formation, sucrose is a non-reducing sugar.

     

     

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