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Chemical Kinetics Test - 2

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Chemical Kinetics Test - 2
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  • Question 1
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    Direction (Q. Nos. 1-13) This section contains multiple choice questions. Each question has four choices (a), (b), (c) and (d), out of which ONLY ONE is correct

    Q. In the following reaction, which has maximum rate w.r.t. rate of disappearance of NH3 ?
    4NH3 + 502   → 4NO + 6H2 O

    Solution

    By stoichiometry of the reaction

  • Question 2
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    The rate of formation of NO(g) in the reaction, 2NOBr(g) →2NO(g) + Br2 (g) was reported as 1.6 x 10-4 Ms-1 . Thus, rate of the reaction is  

    Solution

  • Question 3
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    Rate of formation of SO3 in the  reaction below is 100 kg min-1 .
    2SO2 + O2  → 2SO3
    Hence, rate of disappearance of SO2 will be:

    Solution

    Rate of disappearance of SO2 = Rate of formation of SO3 But quantity is to be expressed in terms of moles.
    Rate of formation of SO3 = 100 kg SO3 min-1  

  • Question 4
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    The following reaction can take place in both directions:

    For the forward reaction, the rate varies with the concentration of A as and for the backward reaction,


    Hence, net reaction rate is:

    Solution

  • Question 5
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    For a reaction, xA →yB, rate of disappearance of ‘A ’is related to the rate of appearance of 'B 'by the equation  

    Thus, x and y respectively are

    Solution



  • Question 6
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    For the reaction,

    H2 (g) + A2 (g)   2H(g) + A2 (g)

    kf = 2.2 x 104 L mol-1 s-1  and Kc = 1.00 x 10-4  at 3000 K. Thus, kb is  

    Solution

  • Question 7
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    For a reaction,

     

    hen x, y and z are  

    Solution

    For the reaction: xA + yB →zC

    Given that,

    Multiplying equation 2 by  1/3, we get

    On comparing equation 1 and 3,
    x = 3, y = 3, z = 2.

  • Question 8
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    For the reaction,

    2N2 O5 (g) →4NO2 (g) + O2 (G)

    Thus,

    Solution

  • Question 9
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    The decomposition of acetaldehyde is given by the following reaction:

    CH3 CHO(g) →CH4 (g) + CO(g)

    Rate of the reaction with respect to the pressure of the reactant is  

    Solution

  • Question 10
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    For the reaction, 

     then rate law is

    Solution

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