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Chemical Kineti...

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  • Question 1
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    Direction : Each question has four choices (a), (b), (c) and (d), out of which ONLY ONE is correct.

    For a given reaction,

    A  →Product,

    rate = 1 x 10-4  Ms-1       at [A] = 0.01 M
    rate = 1.41 x 10-4    Ms-1  at [A] = 0.02 M

    Hence, rate law is  

     

  • Question 2
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    The rate law for a reaction between the substances A and 8 is given by

    rate = k[A]n [B]m

    If concentration of A is doubled and that of B is halved, the new rate as compared to the earlier rate would be  

  • Question 3
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    The rate equation for the reaction,

    2A + B  → C

    is found to be, rate = k[A] [B]

    Q. The correct statement in relation to this reaction is that the

  • Question 4
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    For the reaction,

    2 A+B →Product

    The half-life period was independent of concentration of B. On doubling the concentration A, rate increases two times. Thus, unit of rate constant for this reaction is

  • Question 5
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    Which of the following statements appears to the first order reaction?

    2N2 O5 (CCl4 ) → 4NO2 (CCl4 ) + O2 (g)




  • Question 6
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    For a reaction, time of 75% reaction is thrice of time of 50% reaction. Thus, order of the reaction is

  • Question 7
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    For nth order reaction,

    Graphs between log (rate) and log[A0 ] are of the type ([A0 ] is the initial concentration)

    Lines P, Q, R and S are for the order  

  • Question 8
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    nA  → Product

    For the reaction, rate constant and rate of the reaction are equal, then on doubling the concentration of A, rate becomes,

  • Question 9
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    For the simple reaction,

    A →B

    When [A] was changed from 0.502 mol dm-3 to 1.004 mol dm-3  half-life dropped  from 52 s to 26 s at 300 K. Thus, order of the reaction is  

  • Question 10
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    For the following reaction,

    Variation of T50 with [A] is shown

    Q.

    After 10 min volume of N2 (g) is 10 L and after complete reaction, volume of N2 (g) is 50 L. Thus, T50 is

  • Question 11
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    Kinetics of the following reaction,

    can be studied by

  • Question 12
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    Graph between [B] and time t of the reaction of the type I for the reaction, A →B

    Hence, graph between   and time t will be of the type

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