Concept:
The conductivity for a doped semiconductor is obtained as:
σ = q n0 μn = q p0 μp
where,
ni = Intrinsic carrier concentration.
μn = electron mobility
μp = Hole mobility
When a semiconductor crystal is optically excited, one hole is created for every electron, i.e. electron-hole pass are created.
Calculation:
Before Illumination:
NA = 1017 cm-3 and ni = 2.2 × 106 cm-3
Since NA ≫ ni, the excess hole concentration at thermal equilibrium will be:
p0 = NA = 1017 cm-3
The electron concentration using mass-action law is obtained as:
\({n_0} = \frac{{n_i^2}}{{{p_0}}}\)
\({n_0} = \frac{{{{\left( {2.2 \times {{10}^6}} \right)}^2}}}{{{{10}^{17}}}} = 4.8 \times {10^{ - 5}}c{m^{ - 3}}\)
The electron concentration before illumination is negligible.
Assuming room temperature, all dopants are ionized.
∴ po = NA = 1017 cm-3
Therefore, the electron concentration will be:
\({n_o} = \frac{{n_i^2}}{{{N_A}}} = \frac{{{{\left( {2.2 \times {{10}^6}} \right)}^2}}}{{{{10}^{17}}}} = 4.8 \times {10^{ - 5}}c{m^{ - 3}}\)
Here, we may notice that the electron contribution is negligible. So, we obtain the conductivity of the sample (in dark) as:
σo = q (μn no + μp po) ≅ qμppo
= (1.6 × 10-19)(230)(1017)
σ0 = 3.68 (Ω-cm)-1
When electrons are generated optically, one hole is also created with the generation of an electron. Therefore, the excess hole concentration and excess electron concentration are the same for this case, i.e.
Δp = Δn = 1016 cm-3
Now, the electron and hole concentration after illumination will be:
n = n0 + Δn
n = 4.8 × 10-5 + 1016
n = 1016
Similarly,
p = p0 + Δp
p = 1017 + 1016 cm-3
p = 11 × 1016 cm-3
∴ the conductivity of the given sample when the light is ON will be:
σ = q(n0 + Δn)μn + q(p0 + Δp)μp
σ = q[(1016)μn + (11 × 1016)μp]
= (1.6 × 10-19) (1016 × 5300 + (11 × 1016) (230))
= 1.6 × 10-19 (5.3 × 1019 + 2.53 × 1019)
= 1.6 × (5.3 + 2.53)
σ = 12.528 (Ω-cm)-1