The strength of acidity of an acid can be explained in terms of its ease with which it can release its proton and it is directly proportional to the no of ''-I '' groups attached to it.
When a chlorine atom, which is an electron-withdrawing group is present in the chain attached to a carboxyl group, It exerts -I effect and withdraws electrons from the carbon of the carboxyl group as well as from the oxygen of the O-H bond.
This decreases electron density at the oxygen atom of the O-H bond.
Consequently, the O-H bond gets weakened and the release of H+ ion is favoured.
Moreover, the negative charge present on the carboxylate ion gets dispersed and its stability is increased.
Thus, the acid strength of the acid increases.
So, now the H+ atom can easily come out and the stability of the carboxylate ion has also increased.
Hence both conditions make chloroacetic acid more acidic than acetic acid.
The inductive effect is responsible for the acidity of chloroacetic acid.
So, acidic strength will be in the order:
Trichloro acetic acid > Dichloro acetic acid > Monochloro acetic acid > Acetic acid.
