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Chemistry Test 220

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Chemistry Test 220
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Weekly Quiz Competition
  • Question 1
    4 / -1

    Identify the least stable ion.

    Solution

    This option is correct because the electronic configuration of Be = 1s2 2s2.

    Therefore, the electronic configuration of Be- = 1s2 2s2 2p1.

    So, the stable electronic configuration of Be has broken up and it is highly unstable.

     

  • Question 2
    4 / -1

    The reaction, 2SO2(g) + O2(g) → 2SO3(g) is carried out in a 1 dm3 vessel and a 2 dm3 vessel, separately. The ratio of the reaction velocities, respectively, will be

    Solution

     

     

  • Question 3
    4 / -1

    Cyanide process is used for the extraction of

    Solution

    Gold and silver are extracted from their native ores by MacArthur-Forrest cyanide process.

    4Au(s) + 8NaCN(aq) + O2(g) + 2H2O(l) → 4Na[Au(CN)2](aq) + 4NaOH(aq)

    2Na[Au(CN)2](aq) + Zn(s) → Na2[Zn(CN)4] + 2Au

     

  • Question 4
    4 / -1

    KO2 (potassium superoxide) is used in oxygen cylinders in space and submarines because it

    Solution

    Potassium superoxide is widely used as a CO2 scrubber and O2 generator in spacecrafts and submarines.

    The following reaction takes place:

    4KO2 + 2CO2 → 2K2CO3 + 3O2

     

  • Question 5
    4 / -1

    Which of the following dissolves in water but does not give any oxyacid solution?

    Solution

    In OF2, fluorine has negative oxidation state due to high electronegativity. Therefore, OF2 dissolves in water but does not give any oxyacid solution because unlike other halogens, fluorine cannot acquire a positive oxidation state. In oxyacids of halogens, all halogen atoms have positive oxidation states.

    SO2, SCI4 and SO4 give oxyacid solutions in water and acquire positive oxidation states as shown below.

     

  • Question 6
    4 / -1

    The actinoids exhibit more number of oxidation states in general than the lanthanoids. This is because

    Solution

    As the distance between the nucleus and 5f orbitals (in actinides) is more than the distance between the nucleus and 4f orbitals (lanthanides), therefore the hold of nucleus on valance electron decreases in actinides. For this reason, the actinoids exhibit more number of oxidation states in general.

     

  • Question 7
    4 / -1

    The correct stability order of the above species is

    Solution

    Stability of the carbocations depends upon the number of α-hydrogen, which can undergo hyperconjugation, as well as on their ability to exhibit resonance. Greater the number of α-hydrogen, the more will be the stability of the carbocation.

     

  • Question 8
    4 / -1

    Solution

    Ketones, with Grignard reagent, give tertiary alcohols. Here, 3°-alcohol obtained cyclises to give product given in option (3). The reactions involved are as follow

     

  • Question 9
    4 / -1

    Benzoylacetonato beryllium exhibits isomerism of which of the following types?

    Solution

    Benzoylacetonato beryllium or bis (benzoylacetonato) beryllium (II) complex exhibits optical isomerism as shown below.

     

  • Question 10
    4 / -1

    Aqueous solution of potassium acetate is electrolysed. Possible organic product(s) is/are

    Solution

     

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