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States of Matter: Gases and liquids Test - 2

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States of Matter: Gases and liquids Test - 2
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  • Question 1
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    The kinetic theory of gases predicts that the total kinetic energy of gaseous assembly depends on

    Solution

    K.E. ∝ T
    The kinetic theory of gases predicts that the total kinetic energy of gaseous assembly depends on temperature of the gas.
    K.E. = 3/2 RT

     

  • Question 2
    1 / -0

    Gases deviate from ideal behaviour because their molecules

    Solution

    Gases deviate from ideal behaviour because their molecules have forces of attraction between them and because of this the actual pressure of the gas is less than the ideal pressure.
    Moreover the volume of the individual gas molecules is also not negligible w.r.t the total volume of the gas.
    These are two reasons for the deviation from the ideal behaviour.

     

  • Question 3
    1 / -0

    The following question consists of an Assertion (A) and a Reason (R). Use the following options to mark the appropriate answer.

    (A): The pressure of a fixed amount of an ideal gas is proportional to its temperature at constant volume.
    (R): Ideal gas molecules neither attract nor repel each other.

    Solution

    Both the statements are correct as the pressure of a fixed amount of an ideal gas is proportional to its temperature at constant volume and ideal gas molecules neither attract nor repel each other.

     

  • Question 4
    1 / -0

    The following question consists of an Assertion (A) and a Reason (R). Use the following options to mark the appropriate answer.

    (A): SOgas is easily liquefied while H2 is not.
    (R): SOhas a high critical temperature, while H2 has a low critical temperature.

    Solution

    A gas with a higher critical temperature is easier to liquefy.
    SO2 has high critical temperature (157.5°C) and liquefies readily, while H2 has a very low (-239.95°C) critical temperature, does not easily liquefy.
    Hence, both (A) and (R) are correct and (R) is the correct explanation of (A).

     

  • Question 5
    1 / -0

    When a compressed real gas is allowed to expand through a porous plug at a temperature above its inversion temperature, there is

    Solution

    Since the temperature is greater than the inversion temperature of the gas, there will be heating effect, i.e. rise in temperature of the gas.

     

  • Question 6
    1 / -0

    The following question consists of an Assertion (A) and a Reason (R). Use the following options to mark the appropriate answer.

    (A): van der Waals equation is applicable only to non-ideal gases.
    (R): Ideal gases obey the equation PV = nRT.

    Solution

    van der Waals equation is applicable to all gases. Also, ideal gases obey the equation PV = nRT.

     

  • Question 7
    1 / -0

    The following question consists of an Assertion (A) and a Reason (R). Use the following options to mark the appropriate answer.

    (A): Helium shows only positive deviation from ideal behaviour.
    (R): Helium is an inert gas.

    Solution

    Helium shows only positive deviations from ideal behaviour, because helium is more compressible than ideal gases.
    However, the inert nature of helium is on account of its stable configuration of fully filled K-shell. It does not explain the positive deviation from ideal behaviour.
    Hydrogen and helium, on account of their lower mass, expand more and have a compressibility factor greater than 1.

     

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