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Chemical Equili...

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  • Question 1
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    When a reversible reaction is at equilibrium, one of its products' concentration is decreased. The equilibrium state

  • Question 2
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    If k1 and k2 are the respective equilibrium constants for the reactions (I) and (II), where (I) is 2NO and (II) is NO, then

  • Question 3
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    For PCl5 (g) PCl3 (g) + Cl2 (g); H = 22 k. cals, the dissociation of PCl5 will be more on

  • Question 4
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    The Haber's process for the manufacture of ammonia is usually carried out at 450–500°C. If the temperature of 250°C was used instead of 450–500°C, then

  • Question 5
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    Assertion: An increase in the volume of a system that results in a decrease in the total pressure will cause a shift to the side of the equilibrium with greater number of moles of the gas.
    Reason: This counters the decrease in the total pressure.

  • Question 6
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    Assertion: A net reaction can occur only if a system is not at equilibrium.
    Reason: All reactions occur to reach a state of equilibrium.

  • Question 7
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    What is the relation between Kp and Kc in the following reaction?

    N2(g) + 3H2(g) 2NH3(g)

  • Question 8
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    For the reaction: H2(g) + I2(g) ⇌ 2HI(g), the equilibrium constants expressed in terms of concentration Kc and partial pressure Kp are related as

  • Question 9
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    PCl3 (g) + Cl2 (g) PCl5 (g) Kc (250°C) for this reaction is 26. The value of Kp at the same temperature is

  • Question 10
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    Which of the following reactions will proceed in forward direction if the volume of the container is increased?

  • Question 11
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    Which of the following changes will shift the given reaction towards the product?

    l2 (g) ⇌ 2l (g), (298 K) = +150 kJ

  • Question 12
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    Two moles of PCl5 are heated in a closed vessel of 2 L capacity. When the equilibrium is attained, 40% of it is found to be dissociated. What is Kc in mol/dm3?

  • Question 13
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    The unit of Kc for the equilibrium reaction 2HIH2 + I2 is

  • Question 14
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    In the reaction 3A + 2B 2C, the equilibrium constant Kc is given by

  • Question 15
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    What is the equilibrium expression for the reaction P4 (s) + 5O2 (g) P4O10 (s)?

  • Question 16
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    One mole of a compound AB reacts with one mole of a compound CD according to the equation AB + CD AD + CB. When equilibrium was established, it was found that 3/4 mol each of reactants AB and CD had been converted to AD and CB, respectively. There was no change in volume. The equilibrium constant for the reaction is

  • Question 17
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    The equilibrium constant for the reaction 2NO2 (g) 2NO (g) + O2 (g) is 2 10-6. The equilibrium constant for the reaction 4NO(g) + 2O2 (g) 4NO2 (g) at the same temperature would be

  • Question 18
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    If = 46 V, then the equilibrium constant of the reaction Cu(s) + 2Ag+(aq) Cu2+(aq) + 2Ag(s) is given as

  • Question 19
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    The equilibrium constant Kp for thermal dissociation of PCl5 at 200°C is 1.6 atm. The pressure (in atm) at which it is 50% dissociated at the same temperature is

  • Question 20
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    Which of the following has/have equilibrium constant as one?

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