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Thermodynamics ...

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  • Question 1
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    for a forward reaction in the process A + B ⇌ C is -ve.

    What is the sign of in case of a backward reaction?

  • Question 2
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    For the reaction
    (g) (g)
    The signs of and are

  • Question 3
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    For the reaction

    C3H8 (g) + 5O2 (g) 3CO2 (g) + 4H2O ()

    At constant temperature, is

  • Question 4
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    The of CH4 is –74.8 kJ/mol. The additional information required for determining the average C – H bond energy is

  • Question 5
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    If 1 mole of NH3 and 1 mole of are mixed in a closed container to form (g), which of the following is correct?

  • Question 6
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    The amount of heat evolved when 500 cm3 of 0.1 M HCl is mixed with 200 ml of 0.2 M NaOH is

  • Question 7
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    If = 30 kJ/mol and = 75 J/K mol, then the temperature of vapours at 1 atm pressure is

  • Question 8
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    A reversible chemical reaction (g) ⇌ 2NO (g) + (g) is carried at 400 K with
    = 77.2 kJ/mol
    = 122 J/K/mol

    Which of the following is the correct value (x) for of the reaction?

  • Question 9
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    A reversible chemical reaction (g) ⇌ 2NO (g) + (g) is carried at 400 K with
    = 77.2 kJ/mol
    = 122 J/K/mol
    Using the value of x (from the previous question 8), the correct value of k (equilibrium constant) of the reaction is

  • Question 10
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    Thermochemical equation for the gaseous and solid rocket fuels are

    H2 (g) + O2 (g) H2O () = – 286 kJ
    + O2 (s) = – 1667.8 kJ

    If equal masses of H2 and are taken, the better rocket fuel is

  • Question 11
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    Thermochemical equations for the gaseous and solid rocket fuels are
    H2 (g) + O2 (g) H2O () = – 286 kJ
    + O2 (s) = – 1667.8 kJ

    For the reaction
    O3 (s) (g) + O2 (g)
    The value of is _______ kJ.

  • Question 12
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    Thermochemical equations for the combustion of some important fuels are
    H2(g) + O2 (g) H2O () = – 286.0 kJ
    C (g) + O2 (g) CO2 (g) = – 393.5 kJ
    C6H6 () + O2 (g) 6CO2 + 3H2O () = – 3267.6 kJ
    C2H5OH + 3O2 2CO2 + 3H2O = – 1368.0 kJ

    The amount of heat change, when 1 mole of C2H5OH is formed from its constituents, is

  • Question 13
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    Thermochemical equations for the combustion of some important fuels are
    H2(g) + O2 (g) H2O () = – 286.0 kJ
    C (g) + O2 (g) CO2 (g) = – 393.5 kJ
    C6H6 () + O2 (g) 6CO2 + 3H2O () = – 3267.6 kJ
    C2H5OH + 3O2 2CO2 + 3H2O = – 1368.0 kJ

    The standard enthalpy of formation of benzene is

  • Question 14
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    There are two crystalline forms of lead oxide (PbO) which are known as red and yellow oxides. The for these two oxides is – 219.0 kJ and – 217.3 kJ, respectively.

    What is the value of when yellow form of oxide undergoes solid-solid phase transition to form red oxide?

  • Question 15
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    There are two crystalline forms of lead oxide (PbO), which are named as Red and Yellow oxides.
    The for these two oxides are – 219.0 kJ and – 217.3 kJ, respectively.

    The , when 2 moles of red oxide undergo solid-solid phase transition to form 2 moles of yellow oxide, is

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