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  • Question 1
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    50 mL of 0.1M solution of a salt reacted with 25 mL of 0.1M solution of sodium sulphite. The half reaction for the oxidation of sulphite ion is:



    If the oxidation number of metal in the salt was 3, then what would be the new oxidation number of the metal?

  • Question 2
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    In the given reaction, [X] is

  • Question 3
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    The molecule/ion in which the central atom violates the octet rule is:

  • Question 4
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    Isostructural molecules among the following pairs are:

  • Question 5
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    Directions: In the following question, two statements are given. Examine these statements carefully and mark the correct answer accordingly.

    STATEMENT-1:
    Boat conformation of cyclohexane suffers from angle strain and torsional strain.
    STATEMENT-2: Boat conformation has bond angle 109028' and eclipsing of hydrogen takes place.

  • Question 6
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    The depression in freezing point for 10% (w/w) aqueous glucose (M.W: 180) is T (K). The freezing point of 10% (w/w) aqueous urea (M.W: 60) solution is:

  • Question 7
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    A hydrogenation reaction is carried out at 500 K. If the same reaction is carried out in the presence of a catalyst at the same rate, the temperature required is 400 K. The activation energy of the reaction if the catalyst lowers the activation barrier by 20 kJ/mol is

  • Question 8
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    Directions: In the following question, two statements are given. Examine these statements carefully and mark the correct answer accordingly.

    STATEMENT-1:
    Zn(OH)2 is amphoteric in water and Zn(NH2)2 is amphoteric in ammonia.
    STATEMENT-2: Liquid ammonia resembles the aqueous system quite closely.

  • Question 9
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    How much faster would a reaction proceed at 127oC than 27oC, if the activation energy is 92.12 J? (R = 8.3 J)

  • Question 10
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    In the reaction
    ,
    , then which of the following aryl halides is most reactive?

  • Question 11
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    Dibromosuccinic acid decomposes according to the following reaction:

    C2H2Br(COOH)2 C2HBr(COOH)2 + HBr

    When 50 ml of acid is titrated against standard NaOH at various time intervals, at t = 0, 30 ml of NaOH and at t = 200 min, 33 ml of NaOH were required. The extent of the reaction in mole % is

  • Question 12
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  • Question 13
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    The correct order of bond angles is:

  • Question 14
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    Which of the following reacts with excess methyl magnesium bromide followed by acid hydrolysis to produce 2,3,3-trimethyl-2-pentanol?

  • Question 15
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    What is the product of the reaction of 1-methylcyclopentanol with sodium dichromate and acetic acid?

  • Question 16
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    For the reaction at 184oC and 0.083 JK-1 mol-1, when Kp and Kc are compared at 184oC, it is found that

  • Question 17
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    A weak acid BOH has the dissociation constant 1 10-5 M. It forms a salt BCl on reaction with HCl. The degree of hydrolysis of 0.1 M solution of BCl is

  • Question 18
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    (I) rf = kf [A]2 [B] and rb = kb [C]3 [D]
    (II) If temperature is increased, then the reaction shifts in forward direction.
    (III) Keq(P) =
    (IV) On adding an inert gas at constant pressure, the reaction shifts in the forward direction.

  • Question 19
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    Solubility of BaF2 in a solution of Ba(NO3)2 will be represented by the concentration terms:

  • Question 20
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    Which of the following can act as a buffer?

  • Question 21
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    Kb for the hydrolysis reaction, B+ + H2O BOH + H+ is 1.0 10-6. The hydrolysis constant of the salt is

  • Question 22
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    A weak acid HX (Ka = 1 10-7) on reaction with NaOH gives NaX for 0.1M aqueous solution of NaX, the percentage hydrolysis is

  • Question 23
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    pH of water is 7.0 at 25oC. If water is heated to 70oC, then the

  • Question 24
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    The degree of hydrolysis of a salt of a weak acid and a weak base in its 0.1M solution is found to be 50%. If the molarity of the solution is 0.2M, then the percentage hydrolysis of the salt should be

  • Question 25
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    C is

  • Question 26
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    A solution of a substance containing 1.05 g per 100 mL was found to be isotonic with 3% glucose solution. The molecular mass of the substance is

  • Question 27
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    Consider two liquids A and B, having pure vapour pressures and respectively, forming an ideal solution. The plot of (when XA and YA are the mole fractions of A in liquid and vapour phases respectively) is linear with slope and intercepts

  • Question 28
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    In one of Bohr`s orbits of hydrogen atom, an electron possesses a wavelength of 13.32 A0. When it falls into an orbit, its wavelength is found to be 6.66 A0. The wavelength of spectral line emitted in this transition is nearly

  • Question 29
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    Estimate the difference in energy between first and second Bohr's orbits for a hydrogen atom. At what minimum atomic number would a transition from n = 2 to n = 1 energy level result in the emission of X-rays with = 3 × 108 m?

  • Question 30
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    Identify the reaction in which the given product is not correct.

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