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Thermodynamics Test - 35

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Thermodynamics Test - 35
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  • Question 1
    1 / -0
    A thermodynamics cycle takes in heat energy at a high temperature and rejects energy at a lower temperature. If the amount of energy rejected at the low temperature is 3 times the amount of work done by the cycle, the efficiency of the cycle is:
    Solution
    Let heat taken be $$ Q_1$$, heat rejected be $$Q_2$$, and work done be W
    Then $$Q_2=3W$$
    Also, $$Q_1=Q_2 + W$$
    $$\Rightarrow Q_1=4W$$
    Efficiency of cycle=work done/heat taken=$$\dfrac{W}{4W}=\dfrac{1}{4}=0.25$$
  • Question 2
    1 / -0
    Monoatomic , diatomic and triatomic gases whose initial volume and pressure are same , are compressed till their volume becomes half the initial volume.
    Solution
    For an adiabatic process, 
    $$ {P} {V}^{\gamma} = constant $$
    or
    $$\dfrac{P_1}{P_2}=(\dfrac{V_2}{V_1})^{\gamma}$$
    or
    $$P_2=2^{\gamma}P_1$$
    Now, for a monoatomic gas, the value of $$ \gamma $$ is the highest
    Thus, for the same change in volume, the monoatomic gas will have the maximum pressure.
  • Question 3
    1 / -0
    A reversible adiabatic path on a P-V diagram for an ideal gas passes through sate A where $$ P=0.7 \times 10^5 N/{m}^{-2} $$ and $$v=0.0049\ m^3$$. The ratio of specific heat of the gas is 1.4 . The slope of path at A is:
    Solution
    For reversible adiabat,
    $$Pv^\gamma=constant \Rightarrow vdP + P\gamma dv=0 \Rightarrow \dfrac{dP}{dv}=-\dfrac{\gamma P}{v}$$
    For $$P=0.7 \times 10^5Nm^{-2}, v=0.0049m^3, \gamma =1.4$$
    required slope= $$-\dfrac{1.4\times 0.7\times 10^5\ Nm^{-2}}{0.0049\ m^3}=-2\times 10^7Nm^{-5}$$
  • Question 4
    1 / -0
    $$1\ kg $$ of gas does $$20\ kJ$$ of work and receives $$16\ kJ$$ of heat when it is expanded between two states. A second kind of expansion can be found between the initial and final state which requires a heat input of $$9\ kJ$$. The work done by the gas in the second expansion is:
    Solution
    The change in the internal energy will remain the same, since the initial and final states are the same for both the processes.
    Thus, U = Q - W
    16 - 20 = 9 - W
    $$W = 13\ kJ$$
  • Question 5
    1 / -0
    On an isothermal process, there are two POINTs $$A$$ and $$B$$ at which pressures and volumes are $$(2P_o,\:V_o)$$ and $$(P_o,\:2V_o)$$ respectively. If $$A$$ and $$B$$ are connected by a straight line, the temperature of the isothermal process is how much lower the maximum temperature
    Solution
    Using symmetry, the temperature will be maximum at a point where the pressure and the volume attain the same value.
    Therefore, on a straight line, joining the 2 points A and B as given in the question, the temperature will be maximum at their midpoint. 
    Hence, the pressure will be $$ \dfrac{3 {P}_{o}}{2} $$ and the volume will be $$ \dfrac{3 {V}_{o}}{2} $$
    Thus, for n moles of a gas, the maximum temperature is,
    $$ T = \dfrac{9 {P}_{o} {V}_{o}}{4nR} $$
    However, the isothermal temperature is, 
    $$ T = \dfrac{2 {P}_{o} {V}_{o}}{nR} $$
    Thus, the difference in 2 temperatures will be, 
    $$ \dfrac{{P}_{o} {V}_{o}}{4nR} $$
  • Question 6
    1 / -0
    A vessel contains an ideal monoatomic gas which expands at constant pressure, when heat $$Q$$ is given to it. What is the work done?
    Solution
    For monoatomic gas,$$ C_p=\dfrac{5R}{2}, C_v=\dfrac{3R}{2}$$
    Hence for isobaric process, heat given=$$Q=\dfrac{5}{2}nR\Delta T=\dfrac{3}{2}nR\Delta T + W$$
    $$\Rightarrow W=nR\Delta T=\dfrac{2}{5}Q$$
  • Question 7
    1 / -0
    In an adiabatic process, $$\displaystyle R=\frac{2}{3}C_v$$. The pressure of the gas will be proportional to:
    Solution
    It is given that, $$ {C}_{v} = 1.5 R $$
    Using, $$ {C}_{p} = {C}_{v} + R $$,
    $$ {C}_{p} = 2.5 R $$
    Thus, $$ \gamma = \dfrac{2.5}{1.5} = 5/3$$

    Now,
    Using the condition of adiabaticity,
    $$ {P}^{1 - \gamma} {T}^{\gamma} = constant $$
    Substituting the value of $$ \gamma $$ , 
    Pressure is directly proportional to $$ {T}^{5/2} $$
  • Question 8
    1 / -0
    An ideal gas confined into an insulated chamber is allowed to enter into an evacuated insulated chamber. If Q,W and $$ \Delta E _{int} $$ have the usuak meanings, then
    Solution

  • Question 9
    1 / -0
    Certain perfect gas is found to obey $$ P{V} ^{3/2} = constant $$ during an adiabatic process. If such a gas at initial temperature T is adiabatically compressed to half the initial volume, its final temperature will be 
    Solution
    Using the ideal gas law, P is directly proportional to $$ \dfrac{T}{V} $$
    Substituting this value,
    $$ T {V}^{0.5} = constant $$
    Thus, when the volume is halved, we raise the temperature by $$ \sqrt 2 $$ times.
  • Question 10
    1 / -0
    One mol of a gas at NTP is suddenly expanded to three times its initial volume. If $$C_v =2 R$$, the ratio of initial to final pressure of gas will nearly be
    Solution
    $$P_1 V_1^{\gamma} = P_2 V_2^{\gamma}$$
    $$P_2 = P_1 \displaystyle \left ( \dfrac{V_1}{V_2} \right )^{\gamma} = 1 \left ( \dfrac{1}{3} \right )^{3/2}$$
    $$\displaystyle \dfrac{P_1}{P_2} = 3 \sqrt{3} =5.1$$
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