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Kinetic Theory Test - 27

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Kinetic Theory Test - 27
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  • Question 1
    1 / -0

    During an experiment an ideal gas is found to obey an additional law V$$^{2}$$P= constant. The gas is initially at a temperature T and volume V. When it expands to a volume 2V, the temperature becomes

    Solution
    $${ V }^{ 2 }P=Constant\\ { V }^{ 2 }\left( \dfrac { RT }{ V }  \right) =Constant\\ VT=Constant\\ \therefore \dfrac { { V }_{ 1 } }{ { T }_{ 2 } } =\dfrac { { V }_{ 2 } }{ { T }_{ 1 } } \\ \\  { T }_{ 2 }=\dfrac { { T }_{ 1 }{ V }_{ 1 } }{ 2{ V }_{ 1 } } \\ \\ { T }_{ 2 }=\dfrac { { T }_{ 1 } }{ 2 } $$
  • Question 2
    1 / -0

    Two gases A and B having same pressure P, volume V and temperature T are mixed. if the mixture has volume and temperature as V and T respectively the pressure of mixture is

    Solution
    PV=nRT,
    Since gas has same volume they contain same number of molecules and hence same number of moles.
    Now since V and T remains same only n changes to 2n
    Hence P=2P
  • Question 3
    1 / -0

    A vessel is filled with an ideal gas at a pressure of 200 atm and is at a temperature of 27$$^{0}$$ C. One half of the mass of the gas is removed from the vessel and the temperature of the remaining gas is increased to 87$$^{0}$$ C. At this temperature,the pressure of the gas will be

    Solution
    $${ P }_{ 1 }{ V }_{ 1 }=\dfrac { { m }_{ 1 } }{ M } R{ T }_{ 1 }\\ { P }_{ 2 }{ V }_{ 2 }=\dfrac { { m }_{ 2 } }{ M } R{ T }_{ 2 }\\ { V }_{ 1 }={ V }_{ 2 },{ \quad 2m }_{ 2 }={ m }_{ 1 }\\ \dfrac { { P }_{ 1 } }{ { P }_{ 2 } } =\dfrac { { m }_{ 1 }{ T }_{ 1 } }{ { { m }_{ 2 }T }_{ 2 } } \\ { P }_{ 2 }=\dfrac { 360\times 200 }{ 300\times 2 } \\ \\ { P }_{ 2 }=120atm$$
  • Question 4
    1 / -0

    If $$\rho $$ is the density, m is the mass of 1 molecule and K is the Boltzman constant for a gas then the pressure of the gas is:

    Solution
    $$PV=\dfrac { m }{ M } RT\\ P\dfrac { m }{ \rho  } =nkT\\ P=\dfrac { \rho nkT }{ m } ,\quad \\ if\quad n=1,\quad P=\dfrac { \rho kT }{ m } $$
  • Question 5
    1 / -0

    A gas is heated through $$1^{o}\ C$$ in a closed vessel. Its pressure is increased by $$0.4$$%. The initial emperature of the gas is

    Solution
    Since it is a closed system the volume remains constant.
    Hence,$$\dfrac { { P }_{ 1 } }{ { T }_{ 1 } } =\dfrac { { P }_{ 2 } }{ { T }_{ 2 } } $$
    $${ P }_{ 2 }=1.004{ P }_{ 1 }\\ \therefore { T }_{ 2 }=1.004{ T }_{ 1 }\\ but\quad { T }_{ 1 }+1={ T }_{ 2 }\\ \therefore { T }_{ 1 }=250K\\ { T }_{ 1 }=-{ 23 }^{ \circ  }$$
  • Question 6
    1 / -0

    A given amount of a gas is heated till the volume and pressure both increase by $$2\%$$ each the percentage change in temperature of the gas is  equal to nearly

    Solution
    $$\dfrac { dP }{ P } +\dfrac { dV }{ V } =\dfrac { dT }{ T } \\ Now\quad dP=0.02P,dV=0.02V\\ 0.02+0.02=\dfrac { dT }{ T } \\ \dfrac { dT }{ T } \times 100=4%=percentage\quad change\quad in\quad temperature$$
  • Question 7
    1 / -0

    Two sample of Hydrogen and Oxygen of same mass possess same pressure and volume. The ratio of their temperature is

    Solution
    $${ P }_{ 1 }{ V }_{ 1 }=\dfrac { { m }_{ 1 } }{ { M }_{ 1 } } R{ T }_{ 1 }\\ { P }_{ 2 }{ V }_{ 2 }=\dfrac { { m }_{ 2 } }{ { M }_{ 2 } } R{ T }_{ 2 }\\ \dfrac { { T }_{ 1 } }{ { T }_{ 2 } } =\dfrac { { M }_{ 1 } }{ { M }_{ 2 } } \\ \dfrac { { T }_{ 1 } }{ { T }_{ 2 } } =\dfrac { 1 }{ 16 } \left( { M }_{ 1 }=1gm,{ \ M }_{ 2 }=16gm \right) $$
  • Question 8
    1 / -0

    Two gases A&B having same pressure P, volume V and absolute temperature T are mixed. If the mixture has volume and temperature as V & T respectively then the pressure of mixture is

    Solution
    Moles of gas A $$=\dfrac{PV}{RT}$$

    Moles of gas B $$=\dfrac{PV}{RT}$$
    Moles of the gas mixture $$=\dfrac{P'V}{RT}$$
    Since the number of moles(mass) remains same before and after mixing,
    $$\dfrac{PV}{RT}+\dfrac{PV}{RT}=\dfrac{P'V}{RT}$$
    $$\implies P'=2P$$
  • Question 9
    1 / -0

    One litre of Helium gas at a pressure of 76 cm - Hg and temperature 27$$^{0}$$C is heated till its pressure and volume are doubled. The final temperature attained by the gas is

    Solution
    $$\dfrac { { P }_{ 1 }{ V }_{ 1 } }{ { T }_{ 1 } } =\dfrac { { P }_{ 2 }{ V }_{ 2 } }{ { T }_{ 2 } } \\ \dfrac { PV }{ 300 } =\dfrac { 2P\times 2V }{ { T }_{ 2 } } \\ { T }_{ 2 }=1200K\\ { T }_{ 2 }={ 927 }^{ \circ  }C$$
  • Question 10
    1 / -0

    The mass of oxygen gas occupy a volume of 11.2 lit at a temperature 27$$^{0}$$C and a pressure of 76 cm of mercury in kilogram is (molecular weight of oxygen =32)

    Solution
    $$PV=\dfrac { m }{ M } RT\\ 11.2\times { 10 }^{ -3 }\times 1.01\times { 10 }^{ 5 }=\dfrac { m }{ 32\times { 10 }^{ -3 } } \times 8.314\times 300\\ m=0.01456$$
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