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Some Basic Concepts of Chemistry Test - 28

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Some Basic Concepts of Chemistry Test - 28
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  • Question 1
    1 / -0
    $$10\ g$$ of a crystalline metal sulphate salt when heated generates approximately $$6.4\ g$$ of an anhydrous salt of the same metal. The molecular weight of the anhydrous salt is $$160\ g$$. The number of water molecules present in the crystal is
    Solution
    Consider that the salt contains $$\times$$ molecules of water.
    Molecular weight of anhydrous salt $$= 160 g$$
    so molecular weight of hydrated salt will be $$=160+18xg$$
    Then, no. of moles of water present in 10x gm of hydrated salt $$=\frac {10}{160+18x}\times x$$
    and weight of water present in 10 gm of hydrated salt $$=\frac {10x}{160+18x}\times 18$$
    $$\underset {10 g}{Hydrated} salt\rightarrow \underset {604 g}{Anhydrous} salt+\underset {3.6 g}{Water}$$
    $$\frac {180x}{160+18x}=3.6$$
    $$180x=576+64.8 x$$
    $$x=5$$
  • Question 2
    1 / -0
    3 g of a hydrocarbon on combustion in excess of oxygen produces 8.8 g of $$CO_2$$ and 5.4 g of $$H_2O$$. 

    The data illustrates the law of :
    Solution
    Mass of carbon in 8.8 g $$CO_2 = \dfrac {12}{44} \times 8.8 = 2.4 \ g$$

    Mass of hydrogen in 5.4 g $$H_2O = \dfrac{2}{18} \times5.4 = 0.6 \ g$$

    Total mass $$( C + H )= 2.4 + 0.6 = 3.0 \ g$$

    Mass of hydrocarbon = 3.0 g (given)

    These data illustrate the law of conservation of mass.

    Option (A) is correct.
  • Question 3
    1 / -0
    Temporary hardness is due to bicarbonates of $$Mg^{2+}\, and\, Ca^{2+}$$, it is removed by addition of CaO as follows:
    $$Ca(HCO_3)_2\,+\, CaO\, \rightarrow\, 2CaCO_3\,+\, H_2O$$
    Mass of $$CaO$$ required to precipitate 2 g $$CaCO_3$$ is:
    Solution
    $$Ca(HCO_3)_2 + CaO \rightarrow 2CaCO_3+H_2O$$
    Molecular mass of $$CaO=40+16=56 \ g$$
    Molecular mass of $$CaO_3=40+12(16 \times 3)=100 \ g$$
    Accoridng to the equation, $$2$$ moles of $$CaCO_3$$ i.e $$200 \ g$$ of $$CaCO_3$$ are formed from $$56 \ g \ CaO$$
    $$2 \ g$$ of $$CaCO_3$$ will be formed from $$=\cfrac {2 \times 56}{200}=0.56 \ grams$$
  • Question 4
    1 / -0
    $$3.01\times 10^{23}$$ molecules of elemental Sulphur will react with 0.5 mole of oxygen gas completely to produce
    Solution
    $$\underset {\underset {\frac {1}{2}mole}{1 mole}}{S}+\underset {\underset {\frac {1}{2}mole}{1 mole}}{O_2}\rightarrow \underset {\underset {\frac {1}{2}mole}{1 mole}}{SO_2}$$
    $$3.01\times 10^{23} {\;} 0.5 mole {\;} ?$$
    $$\therefore 3.01\times 10^{23}$$ molecules of $$SO_2$$ will be formed.
  • Question 5
    1 / -0
    A compound was found to contain 5.37% nitrogen. What is the minimum molecular weight of compound ?
    Solution
    $$5.37 g$$ of $$N$$ in $$100 g$$ compound.

    $$14 g N$$= $$\displaystyle\frac{100\times14}{5.37} = 260.7$$ g compound

    which is the minimum molecular wt as it should have at least one $$N.$$

    Hence (c) is the correct answer.
  • Question 6
    1 / -0
    Aluminium reduces manganese dioxide to manganese at high temperature. The amount of aluminium required to reduce one gram mole of manganese dioxide is
    Solution
    $$4AI + 3MnO_2 \rightarrow 3Mn + 2Al_2 O_3$$
    To reduce 3 moles of $$MnO_2$$ required moles of AI = 4
    So, for one mole of $$MnO_2$$ required moles of AI will be = 4/3
  • Question 7
    1 / -0
    The volume of $$0.5 M$$ aqueous $$NaOH$$ solution required to neutralize $$10 ml$$ of $$2 M$$ aqueous $$HCl$$ solution is
    Solution
    $$NaOH {\;} : HCl$$
    $$N_1V_1=N_2V_2$$
    $$0.5\times V=2\times 10$$
    $$V=40 mL$$
  • Question 8
    1 / -0
    Four 1-1 litre flasks are separately filled with the gases $$H_2,\, He,\, O_2$$ and ozone. The ratio of total number of atoms of these gases present in different flask would be : 
    Solution
    According to Avogadro's law, all gases at same temperature and pressure will contain same number of molecules. Hence, number of molecules of all gases will be same bt ration of atoms of each gases will $$2:1:2:3$$.
  • Question 9
    1 / -0
    Number of moles of 1 $$m^3$$ gas, at STP, are:
    Solution
    At STP , volume of 1 mol $$=$$ 22.7 L
    1 $$m^3$$ has 1000 L
    Then, n (no. of moles) in 1 $$m^3 $$ $$= \displaystyle\frac{1000}{22.7} $$ $$= 44.642 \ mol $$ .
  • Question 10
    1 / -0
    Which law stated that 'matter is neither created nor destroyed'?
    Solution
    The law of conservation of mass states that mass in an isolated system is neither created nor destroyed by chemical reactions or physical transformations. 

    According to the law of conservation of mass, the mass of the products in a chemical reaction must equal the mass of the reactants.
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