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Some Basic Concepts of Chemistry Test - 55

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Some Basic Concepts of Chemistry Test - 55
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  • Question 1
    1 / -0
    To convert molality into which of the following unit of concentration require density of the solution?
    Solution
    Percentage of volume depends on the volume of the solution which also depends on the density. So the correct option is B
  • Question 2
    1 / -0
    25.5g of $$H_{2}O_{2}$$ solution on decomposition gave 1.68L of $$O_{2}$$ at STP. The percentage strength by weight of the solution is:
    Solution
    Balanced equation for decomposition of $$H_2O_2$$ 

    $$2H_2O_2\rightarrow 2H_2O + O_2 $$

    2mol $$H_2O_2$$ will produce 1 mol $$O_2$$ 

    At STP 1 mol $$O_2$$ has volume = 22.4L 

    At STP 1.68L of $$O_2$$ = 1.68/22.4 = 0.075 mol $$O_2$$ 

    Therefore the solution contained $$0.075\times2 = 0.15$$  mol $$H_2O_2$$ 

    Molar mass $$H_2O_2 = 34g/mol$$ 

    Mass of $$H_2O_2$$ decomposed $$= 0.15\times34 = 5.1$$ g $$H_2O_2$$ in 25.5g solution 

    100g solution contains : $$100/25.5\times5.1 = 20% $$

    The original solution contains $$20% m/m H_2O_2$$

    Hence, the correct option is $$C$$
  • Question 3
    1 / -0
    $$100$$gm of an aq. solution of sugar contains $$40\%$$ sugar by mass. How much water should be evaporated get $$50\%$$ sugar solution by mass?
    Solution
    $$\underline{\text{Initial condition}}:-$$ $$40\%$$ sugar (by mass),
    Therefore, In $$100gm$$ of an aqueous solution, $$40g$$ sugar and $$60g$$ water is present.
    $$\underline{\text{Final condition}}:-$$ $$50\%$$ sugar (by mass),
    Therefore, In $$100gm$$ of an aqueous solution, $$50g$$ sugar and $$50g$$ water is present.
    Amount of water to be evaporated $$=60-50=10\text{ }grams$$
  • Question 4
    1 / -0
    According to percentage weight arrange the following in descending order in the earth crust ?
    Solution
    Oxygen is present in maximum concentration in earth's crust while $$s$$ has less abundance,
    So, abundance of availability of elements $$O_2>Ca>Mg>S.$$
  • Question 5
    1 / -0
    Calculate the mass percent of carbon in $${ C }_{ 2 }H_{ 5 }OH$$ (Molar mass of ethanol=46.068g)
    Solution
    Given : Mass of $$C_2H_5OH=46.08g$$
    Molecular mass$$=46.08g$$
    Percentage of carbon$$=\cfrac{\text{Mass of carbon}}{\text{Molecular mass}}\times 100\\=\cfrac{24}{46.08}\times 100\\=52.14\%$$
  • Question 6
    1 / -0
    One mole sample of $$FeO$$ is heated in air until it is completely converted into $$Fe_2O_3$$. The percentage increase in weight of the sample is?
    [Given: Atomic mass of Fe = 56]
    Solution
    Mass of $$1$$ mol of $$FeO=(56+16)=72g$$

    $$FeO+\cfrac{3}{4}O_2\longrightarrow \cfrac{1}{2}Fe_2O_3$$

    $$1$$ mol of $$FeO$$ gives $$\cfrac{1}{2}$$ mol $$Fe_2O_3$$.

    $$\therefore$$ Mass of sample after conversion $$=\cfrac{1}{2}\times M_{Fe_2O_3}=\cfrac{1}{2}\times 160=80g$$

    $$\therefore \%$$ increase in weight $$=\cfrac{80-72}{72}\times 100=11.11\%$$

    Hence, the correct option is $$\text{D}$$
  • Question 7
    1 / -0
    Aqueous urea solution is 20% by mass of solution. Calculate percentage by mass of solvent.
    Solution
    Let mass of the solution= $$100g$$
    Given $$20$$% urea= $$20g$$ urea and $$80g$$ of water
    $$\therefore$$ Mass of urea by solvent$$=\cfrac {20}{80}\times 100$$
                                                $$=25$$%
  • Question 8
    1 / -0
    A gaseous mixture contains $$CH_4$$ and $$C_2H_6$$ in equimolecular proportion. The weight of 2.27 litres of this mixture at STP is:
    Solution
    Mol wt of $$CH_4=16\;g/mol$$

    Mol wt of $$C_2H_6=30\;g/mol$$

    Total $$=46\;g/mol$$

    $$\Rightarrow 1$$ Mol wt of $$CH_4=22.4L$$

         $$1$$ Mol wt of $$C_2H_6=22.4L$$

    $$\Rightarrow 46\;g/mol$$ of $$CH_4+C_2H_6=22.4+22.4$$

                                                         $$=44.8L$$

    $$\Rightarrow 46\;g/mol=44.8L$$

    $$\Rightarrow x=2.27L$$

    $$\Rightarrow x=\dfrac{46\times 2.27}{44.8}=2.33g$$

    Hence, the answer is $$2.33g.$$

    Hence, the correct option is $$D$$
  • Question 9
    1 / -0
    Which of the following is the best example of law of conservation of mass?
    [n and m are the masses of reactants and p and q are the masses of products formed.]
    Solution
    Law of conservation of mass:- Mass is neither created nor destroyed it just from one compound to other.

    $$n+m\rightarrow$$ $$p+q$$

    Hence, the mass of reactants is equal to the mass of products formed.
    Option $$B$$ is correct.
  • Question 10
    1 / -0
    $$27\ gm\ Al$$ is heated with $$49\ ml$$ of $$H_{2}SO_{4}$$ (specific gravity $$=2$$) produces $$H_{2}$$ gas. Percentage of $$Al$$ reacted with $$H_{2}SO_{4}$$ is:
    Solution
    $$2Al+3H_2SO_4\longrightarrow Al_2{(SO_4)}_3+3H_2\uparrow$$
    $$2$$ moles of $$Al$$ reacts with $$3$$ moles of $$H_2SO_4$$.
    i.e. $$2\times 27g$$ reacts with $$3\times 98g$$ $$H_2SO_4$$.
    Mass of $$H_2SO_4$$ present $$=49\times 2=98g$$
    $$\therefore $$ Mass of $$Al$$ reacted $$=\cfrac{2}{3}\times 27=18g$$
    $$\therefore \%$$ $$Al$$ reacted $$=\cfrac{18}{27}\times 100=66.66\%$$ 
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