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Structure of Atom Test - 55

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Structure of Atom Test - 55
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  • Question 1
    1 / -0
    According to Bohr's atomic theory, which of the following is correct?
    Solution
    Potential energy of an electron is given by,
    $$P.E=-\dfrac{2\pi^2 mZ^2 e^4}{n^2h^2}$$
    Therefore, $$P.E$$ $$ \alpha$$ $$\dfrac{Z^2}{n^2}$$
    velocity of an electron is given by,
    $$v=\dfrac{2\pi Ze^2}{nh}$$
    Therefore,
    $$(v\times n)$$ $$\alpha$$ $$Z$$
    Frequency of an electron is given by,
    $$f=\dfrac{4\pi^2 Z^2 e^4}{n^3 h^3}$$
    $$f$$ $$\alpha$$ $$\dfrac{Z^2}{n^3}$$
    Coloumbic force of attraction is given by,
    Coloumbic force of attraction of an electron $$\alpha$$ $$\dfrac{Z^3}{n^4}$$
  • Question 2
    1 / -0
    What atomic number of an element $$X$$ would have to become so that the $$4th$$ orbit around $$X$$ would fit inside the $$1st$$ Bohr orbit of $$H-$$atom?
    Solution
    By definition of Bohr radius $$a_o$$,
    $$r=n^2\left(\cfrac {a_o}{Z}\right), r=$$ radical distance from the nucleus of a $$H$$-like atom
    So, if we want $$r=a_o$$,
    $$Z=n^2\left(\cfrac {a_o}{r}\right)=n^2\left(\cfrac {a_o}{a_o}\right)=n^2$$
    For the $$4^{th}$$ Bohr orbit, $$n=4$$,
    $$\Rightarrow Z= 4^2= 16$$
  • Question 3
    1 / -0
    What is the seperation energy (in eV) for $$Be^{3+}$$ in the first excited state in eV?
    Solution
    Separation Energy= $$13.6 \times \cfrac {Z^2}{n^2}$$
    For $$Be$$, $$Z=4$$
    For $$1^{st}$$ excited state $$n=2$$
    $$\therefore 13.6 \times \cfrac {4^2}{2^2}= 54.4eV$$
  • Question 4
    1 / -0
    For Hydrogen atom the ratio of time required to complete $$1$$ revolution of electron in $$I^{st},II^{nd}$$ and $$III^{rd}$$ orbit respectively is:
    Solution
    Time required to complete $$1$$ revolution $$=\cfrac{2\pi r}{v}$$
    $$\because r\propto n^2$$ and $$v\propto \cfrac{1}{n}$$
    $$\therefore $$ $$Time$$ $$required\propto n^3$$
    $$\therefore$$Ratio of time required in $$I^{st},II^{nd}$$ and $$III^{rd}$$ orbit is, $$(1)^3:(2)^3:(3)^3$$ i.e. $$1:8:27$$ 
  • Question 5
    1 / -0
    The sulphate of a metal $$M$$ contains $$9.87\%$$ of $$M$$. This sulphate is isomorphous with $$ZnSO_{4}.7H_{2}O$$. The atomic weight of $$M$$ is:
    Solution

    1) Consider the molecular weight of the metal be M

    Now as it is isomorphous with $$ZnSO_4.7H_2O$$ it would be of the formula $$MSO_4.7H_2O$$

    Percentage of M in the compound would be

    $$M \times \cfrac{100}{M}+$$ weight of $$SO_4+7\times $$ weight of $$H_2O$$

    $$=\cfrac{M\times 100}{M+96+126}$$

    $$=9.87$$

  • Question 6
    1 / -0
    Which of the following frequencies is associated with the visible region of a spectrum?
    Solution
    Frequency range of visible region $$430-770$$
    $$TH_{2}$$
    $$430\times 10^{12}-770\times 10^{12}Hz$$
    $$6\times 10^{14}$$ cycle/second associated with visible region
  • Question 7
    1 / -0
    The percentage of an element $$M$$ is $$53$$ percentage in its oxide of molecular formula $${ M }_{ 2 }{ O }_{ 3 }$$. Its atomic mass is about: 
    Solution
    Assume atomic mass of $$M$$ is $$x$$
    Molecular weight of compound $$=2x + 16\times 3$$
    $$=2x + 48$$
    % of weight of M $$=\dfrac{2x}{2x+48}\times 100=53(given)$$
    Solve for $$x$$,
    $$x=27.06=27$$
  • Question 8
    1 / -0
    Atomic number of the central atom in $${ MCl }_{ 2 }$$ is $$50$$. The shape of gaseous $${ MCl }_{ 2 }$$ is given as: 
    Solution

    $$MC{{L}_{2}}$$ have $$ 50$$ atomic number so $$ M$$ will be $$ 16$$ atomic number.

    $$ C{{l}_{2}}=17+17 $$

     atomic number is $$34+16=50$$.

    And molecule will be $$SC{{l}_{2}}$$ and according to this shape of the molecule is bent.

    And $$S$$ have two lone pair.

  • Question 9
    1 / -0
    The ratio of the radius of $$1st$$ orbit of $$H$$ atom to that of its $$4$$th excited state is:
    Solution
    Bohr radius r $$\propto \dfrac{n^{2}}{2}$$

     $$\dfrac{r_{1st} \, orbit }{r _{4th} \, excited \, state} = \dfrac{1^{2}}{4^{2}}$$

                             = $$\dfrac{1}{16}$$

     Option D is the correct answer.
  • Question 10
    1 / -0
    The atomic masses of two elements A and B are 20 and 40 respectively. If x gm of A contains Y atoms, how many atoms are present in 2x gm of B? 
    Solution
    According to Avogadro's law, $$1$$ mole of every substance weighs equal to the molecular mass and contains Avogadro's number, $$6.023 \times 10^{23} $$ of particles.

    Moles $$= \dfrac{Given \ mass}{Molar \ mass}$$

    Moles of $$A = \dfrac{x}{20} = 0.05 \times x moles$$

    Thus, $$0.05 \times x$$ moles of A contain $$= y$$ atoms

    Moles of $$B = \dfrac{2x}{40} = 0.05 \ x$$ moles

    Thus $$0.05 \times x$$ moles of B contains $$= y$$ atoms

    As equal mole contains equal atoms.

    Thus, the correct answer is $$'y'$$
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