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Classification of Elements and Periodicity in Properties Test - 47

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Classification of Elements and Periodicity in Properties Test - 47
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  • Question 1
    1 / -0

    For AX ionic crystal to exist in bcc structure, the ratio of $$\left( \dfrac{r_{cation}}{r_{anion}} \right)$$ should be:

    Solution
    For bcc structure, the radius ratio should be greater than $$0.73$$ because the radius ratio lies between $$0.732$$ to $$1.00.$$

    Hence, option B is correct.
  • Question 2
    1 / -0
    Ionisation energy of $$F^{-}$$ is $$320\ kJ\ mol^{-1}$$. The electron gain enthalpy of fluorine would be:
    Solution
    Electron gain enthalpy is the opposite of ionisation energy.

    $$\therefore Electron \, Gain\, Enthalphy=-IE$$ 

    $$\therefore EGE \ (F^-)=-320\ kJ/mol$$
  • Question 3
    1 / -0
    Which one of the following arrangements represents the correct order of electron gain enthalpy (with negative sign) of the given atomic species.
    Solution
    Correct option is $$B:O<S<F<Cl$$
    $$F$$ and $$Cl$$ have high tendency to gain an $$e^-$$ and stabilize themselves by fulfilling outermost shell. $$F$$ being small in size & more electronegative than $$Cl$$, $$Cl$$ accepts $$e^-$$ more readily than $$F$$. On the other hand $$O$$ with more electronegativity than $$S$$ and is small in size has less $$e^-$$ gaining tendency than $$O$$. Hence the order $$O<S<F<Cl$$.
  • Question 4
    1 / -0
    Flourine is the best oxidising agent because it has:
    Solution

    Oxidizing agent means element, which oxidizes others by itself getting reduced.
    Oxidation occurs by loss of $$e^-$$
    For eg:-
    $$\overset {0} H\longrightarrow \overset {+1} {H^+}+e^-$$
       loss of $$e^-$$
    $$ {F+e^-\longrightarrow F^-}$$
    Here $$F$$ oxidizes $$H$$ and itself gets reduced.
    (Refer to Image)
    $$\because F$$ has high tendency to gain $$e^-$$ and to stabilize itself, i.e. have high $$EGE$$ or $$e^-$$ affinity. Hence accepts $$e^-$$ from $$H$$ and oxidized $$H$$ and act as good oxidizing agent.

  • Question 5
    1 / -0
    Select the group where $$EN$$ increases down the group.
    Solution
    Generally, electronegativity increases as we move from left to right across a period and decreases as we move down a group. But in the case of Zn, Cd and Hg which belong to  3d, 4d  and  5d  series of transition elements (group 12),  EN  increases down the group. This is due to the imperfect screening effect of d and f-orbitals in transition elements. 

     Hence, option D is correct.
  • Question 6
    1 / -0
    Which of the following electronic configurations corresponds to elements with largest negative electron gain enthalpy?
    Solution
    Electron gain enthalpy is the amount of energy released when an electron is added to a isolated gaseous atom.
    Halogens have greater electron gain enthalpy values. So, $${ 1S }^{ 2 }{ 2S }^{ 2 }{ 2P }^{ 6 }{ 3S }^{ 2 }{ 3P }^{ 5 }$$ has greater value.
  • Question 7
    1 / -0
    Which of the following species has the highest electron affinity?
    Solution
    Energy is released when an electron is added to the atom. Hence 1st electron affinity $$\left( E{ A }_{ 1 } \right) $$ is always taken as negative. The addition of second electron to the negativity charged ions is opposed by Coulombic repulsion, hence energy has to be supplied for the addition of second electron. Hence $$\left( E{ A }_{ 2 } \right) $$ is taken as positive. 

    Addition of an electron to $${F}^{-}$$ and $${O}^{-}$$ ions will involve repulsions, hence their $$\left( E{ A }_{ 2 } \right) $$ will be positive.
    Due to stable fully filled configuration of $${Na}^{+}$$ $$\left( 1{ s }^{ 2 }2{ s }^{ 2 }2{ p }^{ 6 } \right) $$ it has lower value of electron affinity than $$O$$. Hence $$O$$ has highest electron affinity.
  • Question 8
    1 / -0
    If periodic table would have contained 10 period, maximum elements in that periodic table would be:
    Solution
    For, even no. of period $$=\cfrac {(n+2)^2}{2}$$

    So, $$10$$ periods $$=\cfrac {(10+2)^2}{2}$$
                              $$=\cfrac {144}{2}=72$$

    $$\therefore$$ Number of elements $$=72$$
  • Question 9
    1 / -0
    The chemical activity of an atom is dependent on the number of __________.
    Solution
    The chemical activity of an atom is dependent on the number of valence electrons.
    An atom with octet configuration does not participate in chemical reactions and is known as chemically inert.
  • Question 10
    1 / -0
    Few general names are given along with their valence shell configurations. Mark the incorrect name.
    Solution
    Chalcogens are group 16 elements with valence shell electronic configuration $$ns^2np^4$$. They belong to oxygen family.  Group 14 element (Carbon family) have valence shell electronic configuration $$ns^2np^2$$.
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