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  • Question 1
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    Which of the following species has the highest electron affinity ?

  • Question 2
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    The order of first electron affinity of $$O, S$$ and $$Se$$ is:

  • Question 3
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    There are four elements p, q, r and s having atomic numbers $$Z-1$$, $$Z$$, $$Z+1$$ and $$Z+2$$ respectively. If the element q is an inert gas, select the correct statements:
    (i) p has most negative electron gain enthalpy in the respective period.
    (ii) r is an alkali metal.
    (iii) s exists in +2 oxidation state.

  • Question 4
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    Statement-1 : Electron affinity of fluorine is less than that of chlorine.
    Statement-2 : Chlorine can accommodate an electron by utilising its vacant 3d-orbital.

  • Question 5
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    The species among the following having the highest electron affinity is:

  • Question 6
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    The electron gain enthalpies of halogens in kJ mol$$^{-1}$$ are as given as F = -332, Cl = -349, Br = -324, I = -295. The less negative value for F as compared to that of Cl is due to :

  • Question 7
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    The correct order of electron affinity is :

  • Question 8
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    Directions For Questions

    The periodicity is related to the electronic configuration. That is, all chemical and physical properties are a manifestation of the electronic configurations of the elements.
    The atomic and ionic radii generally decrease in a period from left to right. As a consequence, the ionization enthalpies generally increase the electron gain enthalpies become more negative across a period. In other words, the ionization enthalpy of the extreme left element in a period is the least and the electron gain enthalpy of the element on the extreme right is the highest negative. This results into high chemical reactivity at the two extremes and the lowest in the center. Similarly down the group, the increase in atomic and ionic radii result in a gradual decrease in ionization enthalpies and a regular decrease (with an exception in some third-period elements) in electron gain enthalpies in the case of main group elements.
    These properties can be related to the:
    (i) Reducing and oxidizing behaviour of the elements.
    (ii) The metallic and non-metallic character of an element.
    (iii) The acidic, basic, amphoteric and neutral character of the oxides of the elements.

    ...view full instructions

    Among $$Al_2O_3, SiO_2, P_2O_3$$ and $$SO_2$$ the correct order of acid strength is:

  • Question 9
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    Which of the following order(s) for electron affinity is(are) correct?


    (a)$$\displaystyle S> O< Se$$ 
    (b)$$\displaystyle CI> F$$ 
    (c)$$\displaystyle S> O$$ 
    (d)$$\displaystyle O> S$$ 
    (e)$$\displaystyle N> P$$ 
    (f)$$\displaystyle C> N$$

  • Question 10
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    The correct sequence of the electron affinity of $$C, N, O$$ and $$F$$ is:

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