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Classification of Elements and Periodicity in Properties Test - 8

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Classification of Elements and Periodicity in Properties Test - 8
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  • Question 1
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    Which of the following characteristic is not correct regarding alkali metals?

    Solution

    Alkali metals have lowest ionization energy value in the respective period.

  • Question 2
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    The correct statement with regard to H2+ and H2 is

    Solution

    H2+ is more stable than H2since,according to MOT,there are no any anti bonding electrons are present in the H2+. In simple words when the two s-orbitals of the H atoms combine (overlap), there are two possible combinations - essentially they either add together (bonding MO), or they subtract (antibonding MO). The additive combination is called a (sigma) bonding orbital, while the subtractive combination is called an antibonding orbital (sigma*). Putting electrons into a bonding orbital helps to hold the atoms together (stabilizes the bond), whereas putting them into an antibonding orbital tends to drive them apart (destabilizes the bond). H2+ has one electron shared between the two H nuclei, and it goes into the lowest energy orbital available... the bonding orbital. That helps to hold the H's together. Hhas two electrons, and both can go into the bonding orbital (with opposite spins) and contibute to stability. That's better than only one electron in the bonding orbital, so H2 is more stable than H2+. Whereas in H2-, there are three electrons. The first two goes into the bonding orbital, but the third has to go into the antibonding orbital, which weakens the bond.

  • Question 3
    1 / -0

    The formula for Xenon  compounds  containing  σ bonds = 5 and π bonds = 3  is 

    Solution

    The presence of  five σ bonds and three π bondsfive σ bonds and three π bonds in compound  XeF2O3 has been  confirmed  by  its  IR spectra . 

  • Question 4
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    Dmitri Mendeleev (1834-1907) and the German chemist, Lothar Meyer (1830-1895) proposed arranging elements in

    Solution

    When they arranged elements in the increasing order of their atomic weights, both of them observed that the chemical and physical properties of the elements repeated after a regular interval.

  • Question 5
    1 / -0

    A transition metal ion exists in its highest oxidation state. It is expected to behave as

    Solution

    The transiiton metal in its highest oxidation state will have no desire to further loose electrons. It will act as an oxidizing agent where it will accept electrons and is reduced in a chemical reaction.

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