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Thermodynamics ...

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  • Question 1
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    For the process :

       $$\\ \mathrm{H}_{2}\mathrm{O}(l)$$ ($$1$$ bar, $$373$$ $$\mathrm{K}$$) $$\rightleftharpoons \mathrm{H}_{2}\mathrm{O}(\mathrm{g})$$ ( $$1$$ bar, $$373 \mathrm{K}$$),

    the correct set of thermodynamic parameters is

  • Question 2
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    A gas mixture consists of $$2$$ moles of $$O_2$$ and $$4$$ moles of Ar at temperature $$T$$. Neglecting all vibrational modes, the total internal energy of the system is 

  • Question 3
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    For vaporization of water at $$ 1$$ atmospheric pressure, the values of $$\Delta$$H and $$\Delta$$S are $$40.63 kJ mol^{-1}  and $$108.8 JK$$^{-1}$$mol$$^{-1}$$, respectively. The temperature when Gibb's energy change ($$\Delta$$G) for this transformation will be zero, is : 

  • Question 4
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    The following two reactions are known 

    $$Fe_2O_{3(s)} + 3CO_{(g)}\rightarrow 2Fe(s) + 3CO_{2(g)}$$ ; $$\Delta \ H = -26.8\ kJ$$

    $$FeO_{(s)} + CO_{(g)}\rightarrow Fe_{(s)} + CO_{2(g)}\Delta H = -16.5\ kJ$$

    The value of $$\Delta\ H$$ for the following reaction is:

    $$Fe_2O_{3(s)} + CO_{(g)}\rightarrow 2FeO_{(s)} + CO_{2(g)}$$

  • Question 5
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    For a given reaction, $$\triangle H = 35.5\ kJmol^{-1}$$ and $$\triangle S = 83.6\ JK^{-1} mol^{-1}$$. The reaction is spontaneous at: (Assume that $$\triangle H$$ and $$\triangle S$$ do not vary with temperature)

  • Question 6
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    Consider the following processes:
                                                      $$\Delta H\left({kJ}/{mol}\right)$$
    $$\dfrac{1}{2} A \rightarrow B$$                               $$+150$$

    $$3B \rightarrow 2C + D$$                       $$-125$$

    $$E + A \rightarrow 2D$$                          $$+350$$

    For $$B + D \rightarrow E + 2C,   \Delta H$$ will be:

  • Question 7
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    For the reaction, $$X_2O_4(i)\rightarrow 2XO_2(g)$$, $$\Delta U=2.1k cal, \Delta s=20 cal K^{-1}$$ at 300 K. 

    Hence, $$\Delta G$$ is:

  • Question 8
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    One mole of an ideal diatomic gas undergoes a transition from A to B along a path AB as shown in the figure, The change in internal energy of the gas during the transition is:

  • Question 9
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    Which law of the thermodynamics helps in calculating the absolute entropies of various substances at different temperatures?

  • Question 10
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    Assertion (A) : Zeroth law of thermodynamics gives us the concept of energy
    Reason (R) : Internal energy is dependent on temperature

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