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Thermodynamics ...

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  • Question 1
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    $$H_2(g) + \frac{ 1 }{ 2 }O_2(g)\longrightarrow 2H_2O(l);   \Delta H = -286  kJ$$
    $$2H_2(g) + O_2(g)\longrightarrow 2H_2O(l)......... kJ(\pm?)$$

  • Question 2
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    The heat released when the requisite amount of ions in the gaseous state combine to give 1 mol of crystal lattice is known as:

  • Question 3
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    Directions For Questions

    The industrial preparation of a polymer, PTFE, is based on the synthesis of the monomer $${ CF }_{ 2 }={ CF }_{ 2 }$$, which is produced according to reaction (i) below
    $${ 2CHClF }_{ 2 }$$(g) $$\longrightarrow $$ $${ CF }_{ 2 }$$ = $${ CF }_{ 2 }(g)$$ $$+ 2HCl$$
    The monomer $${ CF }_{ 2 }$$ = $${ CF }_{ 2 }$$ is also obtained by reaction (ii) below
    $${ 2CF }_{ 3 }$$(g) $$\longrightarrow $$ $${ CF }_{ 2 }$$ = $${ CF }_{ 2 }(g)$$ + $$2HF(g)$$ ; $$\Delta $$H = 198.1 kJ/mol

    ...view full instructions

    The enthalpy change for reaction (i) is:

  • Question 4
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    Gibbs- Helmholtz equation is

  • Question 5
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    The relationship between the free energy change $$(\Delta G)$$ and entropy change $$(\Delta S)$$ at constant temperature $$(T)$$ is 

  • Question 6
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    What can be concluded about the values of $$\Delta H$$ and $$\Delta S$$ from this graph ?

  • Question 7
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    The Born Haber cycle below represents the energy changes occurring at 298K when KH is formed from its elements
    v : $${ \Delta H }_{ atomisation }$$ K = 90 kJ/mol
    w : $${ \Delta H }_{ ionisation }$$ K = 418 kJ/mol
    x : $${ \Delta H }_{ dissociation }$$ H = 436 kJ/mol
    y : $${ \Delta H }_{ electron affinity }$$ H = 78 kJ/mol
    z : $${ \Delta H }_{ lattice }$$ KH = 710 kJ/mol

    In terms of the letters v to z the expression for
    $${ \Delta H }_{ i }$$ of K is $${ \Delta H }_{ i }$$ = $$w/2$$.
    If true enter 1, else enter 0.

  • Question 8
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    The Born Haber cycle below represents the energy changes occurring at 298K when $$KH$$ is formed from its elements
    v : $${ \Delta H }_{ atomisation }$$ $$K = 90 kJ/mol$$
    w : $${ \Delta H }_{ ionisation }$$ $$K = 418 kJ/mol$$
    x : $${ \Delta H }_{ dissociation }$$ $$H = 436 kJ/mol$$
    y : $${ \Delta H }_{ electron affinity }$$ $$H = 78 kJ/mol$$
    z : $${ \Delta H }_{ lattice }$$ $$KH = 710 kJ/mol$$

    Calculate the value of $$\Delta $$$$H$$ showing all your working.

  • Question 9
    1 / -0

    The Born Haber cycle below represents the energy changes occurring at 298K when KH is formed from its elements
    v : $${ \Delta H }_{ atomisation }$$ K = 90 kJ/mol
    w : $${ \Delta H }_{ ionisation }$$ K = 418 kJ/mol
    x : $${ \Delta H }_{ dissociation }$$ H = 436 kJ/mol
    y : $${ \Delta H }_{ electron affinity }$$ H = 78 kJ/mol
    z : $${ \Delta H }_{ lattice }$$ KH = 710 kJ/mol

    In terms of the letters v to z the expression for
    $${ \Delta H }_{ electron affinity }$$ of H is $${ \Delta H }_{ electron affinity }$$  is __.
    I

  • Question 10
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    What is the free energy change $$(\Delta G)$$ when 1.0 mole of water at $$100^{\circ}\! C$$ and 1 atm pressure is converted into steam at $$100^{\circ}\! C$$ and 1 atm pressure?

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