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Thermodynamics Test - 23

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Thermodynamics Test - 23
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  • Question 1
    1 / -0
    Mark the point where the temperature of $$H_2O$$ is changing at $$4.18 J/g^o$$C(or $$1$$ $$cal/g^oC$$)?

    Solution
    At  point (C) the temperature of the water is changing at $$ 4.18J/g ^ oC$$

    The specific heat of liquid water is $$4.18J/g ^ oC$$. 

    Thus the section (C) of the curve corresponds to the region where the temperature of the water is heated from $$0^0 C$$ to $$100^0 C$$.

    Hence, the correct option is C.
  • Question 2
    1 / -0
    According to Hess's law, the heat of reaction depends upon
    Solution
    According to Hess's law, the heat of reaction depends upon Initial and final conditions of reactants. The the heat of reaction is independant of the intermediate path of the reaction. For example, the heat of the reaction for the reaction $$\displaystyle A \rightarrow D$$ is equal to the sum of the heats of the reactions $$\displaystyle A \rightarrow B \\ B \rightarrow C \\ C \rightarrow D$$
  • Question 3
    1 / -0
    If $$C+{O}_{2}.\longrightarrow  {CO}_{2}+94.2kcal$$
    $${H}_{2}+\cfrac{1}{2}{O}_{2}\longrightarrow  {H}_{2}+68.3kcal$$
    $${CH}_{4}+2{O}_{2}\longrightarrow  {CO}_{2}+2{H}_{2}O+210.8kcal$$
    Then, the heat of formation of methane will be
    Solution
    $$C+{O}_{2}\longrightarrow {CO}_{2}+94.3kcal.........(i)$$
    $${H}_{2}+\cfrac{1}{2}{O}_{2}\longrightarrow {H}_{2}O+68.3kcal.......(ii)$$
    On multiplying Eq.$$(ii)$$ by $$2$$ and then adding in Eq.$$(i)$$, we get
    $$C+2{H}_{2}+2{O}_{2}\longrightarrow {CO}_{2}+2{H}_{2}O+230.8kcal.....(iii)$$
    On substracting, adding the following equation from Eq. $$(iii)$$
    $${CH}_{4}+2{O}_{2}\longrightarrow {CO}_{2}+2{H}_{2}O+210.8kcal$$
    we get
    $$C+2{H}_{2}\longrightarrow {CH}_{4}+20kcal$$
  • Question 4
    1 / -0
    10 g of liquid at 300K is heated to 350 K. The liquid absorbs 6 kcals. What is the specific heat of the liquid (in $$cal/ \displaystyle { g }^{ \circ  }C$$)?
    Solution
    $$Q=nC\triangle T$$ where $$C$$=specific heat of the liquid
    $$6KCal=Q$$

    $$6\times 10^3 Cal=Q$$

    So, $$6 \times 10^3=10\times C\times (350-300)K$$

    $$\Rightarrow \cfrac {6\times 10^3}{10\times 50}=C$$

    $$\Rightarrow C=12$$.
  • Question 5
    1 / -0
    Statement I
    As ice absorbs heat and begins to melt, its temperature remains constant
    Because
    Statement II
    Changes of state bring about changes in a substances potential energy, not in its kinetic energy
    Solution
    As ice absorbs heat and begins to melt, its temperature remains constant, this statement is true because phase change from solid to liquid occurs at constant temperature. This is because change of state brings about changes in a substance's potential energy, not in its kinetic energy,so both statements are correct and second statement is correct explanation of first.
  • Question 6
    1 / -0
    If 100.0 J of energy is added to 50.0 g of Cu, initially at $$25.0^o C$$, what will be the final temperature? (Specific heat capacity = 0.382 J/ C.g )
    Solution
    let T deg C be the final temperature.
    $$\displaystyle  q = mS \Delta T$$
    $$\displaystyle  q = 100.0 $$  J = energy added
    $$\displaystyle  m = 50.0$$  g =  mass of Cu
    $$\displaystyle  S = 0.382$$  J/C.g = the specific heat of Cu
    $$\displaystyle  \Delta T = T - 25.0$$  = temperature difference.
    Substite values in the above equation.
    $$\displaystyle  100.0 = 50.0 \times 0.382 \times (T-25.0)  $$
    $$\displaystyle   5.235= T-25.0$$
    $$\displaystyle  T = 30.24 ^oC $$
  • Question 7
    1 / -0
    Two substances P and Q when brought together, form substance R with the evolution of heat. The properties of R are different from both P and Q. What is substance R?
    Solution
    Since the substance $$R$$ is a mixture of two substances, it may either be a mixture or a compound
    In a mixture the constituents retain their properties while in a compound, they lose their properties.
    Since the question mentions that $$R$$ has different property from both $$P$$ and $$Q$$, hence it must be a compound
  • Question 8
    1 / -0
    Which statement is correct about heat?
    Solution
    All answers about heat are correct
    It is a measure of the transfer of energy due a temperature difference. When two bodies have different temperatures, heat will be exchanged till thermal equilibrium is attained.
    B
    The heat transfer is always from hot to cold. Thus the body at higher temperature will lose heat and the body at lower temperature will gain heat.
    C
    The heat absorbed by the surroundings equals the heat released by the system
    For example, if system releases 500 J heat, the surrounding will absorb 500 J heat.
    D
    The amount of heat lost or gained during a reaction is directly related to the enthalpy change of the reaction. The enthalpy change is the difference between the heat content of products and the heat content of reactants.
  • Question 9
    1 / -0
    Hess's Law is used
    Solution
    All of these options are correct.
    Hess's Law is used

    A) When a directly measured enthalpy change of reaction is not available
    B) To calculate an enthalpy change value through multiple steps
    C) Because enthalpy is a State Function
    E) As an easy way to calculate the enthalpy change of a reaction

    According to Hess Law, the change in enthalpy for a reaction is the same whether the reaction takes place in one or more steps. The Hess's law can also be stated as the enthalpy change for a chemical reaction is the same regardless of the path followed by the reaction.
  • Question 10
    1 / -0
    A spontaneous reaction occurs:
    Solution
     A spontaneous reaction occurs by itself but it has no effect on how fast the reaction takes. A spontaneous reaction may be very fast but another spontaneous reaction may be very slow.
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