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Thermodynamics ...

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  • Question 1
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    The value of $$\Delta H$$ and $$\Delta S$$ for a reaction are respectively $$30kJ$$ $${mol}^{-1}$$ and $$100J{K}^{-1}$$ $${mol}^{-1}$$. Then temperature above which the reaction will become spontaneous is:

  • Question 2
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    Which of the following thermodynamics relation is correct?

  • Question 3
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    $$\Delta H$$ and$$\Delta S$$ for the reaction
    $${ Br }_{ 2 }(l)+{ Cl }_{ 2 }(l)\longrightarrow 2BrCl(g)$$
    are $$29.37\ kJ$$ and $$104.0\ J{ K }^{ -1 }$$ respectively. Above that temperature will this reaction become spontaneous?

  • Question 4
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    A $$1g$$ sample of substance $$A$$ at $${100}^{o}C$$ is added to $$100mL$$ of $${H}_{2}O$$ at $${25}^{o}C$$. Using separate $$100mL$$ portion of $${H}_{2}O$$ the procedure is repeated with substance $$B$$ then with substance $$C$$. How will the final temperatures of the water compare?

    SubstanceSpecific heat
    $$A$$$$0.6{g}^{-1}$$ $$^{ o }{ { C }^{ -1 } }$$
    $$B$$$$0.4{g}^{-1}$$ $$^{ o }{ { C }^{ -1 } }$$
    $$C$$$$0.2{g}^{-1}$$ $$^{ o }{ { C }^{ -1 } }$$

  • Question 5
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    The Haber's process for production of ammonia involves the equilibrium:
    $${N}_{2}(g)+3{H}_{2}(g)\rightleftharpoons  2{NH}_{3}(g)$$
    Assuming $$\Delta {H}^{o}$$ and $$\Delta {S}^{o}$$ for the reaction do not change with temperature, which of the statements is true?
    ($$\Delta {H}^{o}=-95kJ$$ and $$\Delta {S}^{o}=-190J{ K }^{ -1 }$$)

  • Question 6
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    For a particular reaction, $$\Delta { H }^{ o }=-38.3\ kJ$$ and $$\Delta { S }^{ o }=-113\ J{ K }^{ -1 }{ mol }^{ -1 }$$. This reaction is:

  • Question 7
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    Following enthalpy changes are given:


    $$\alpha -D\quad glucose(s)\longrightarrow \alpha -D\quad glucose(aq.);\quad \Delta H=10.72kJ$$

    $$\beta -D\quad glucose(s)\longrightarrow \beta -D\quad glucose(aq.);\quad \Delta H=4.68kJ$$

    $$\alpha -D\quad glucose(aq.)\longrightarrow \beta -D\quad glucose(aq.);\quad \Delta H=1.16kJ$$

    Calculate the enthalpy change in,

    $$\alpha -D\quad glucose(s)\longrightarrow \beta -D\quad glucose(s)$$

  • Question 8
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    For which process will $$\Delta { H }^{ o }$$ and $$\Delta { G }^{ o }$$ be expected to be most similar?

  • Question 9
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    Consider the values of $$\Delta { H }^{ o }$$ (in $$kJ{ mol }^{ -1 }$$) and for $$\Delta { S }^{ o }$$ (in $$J{ mol }^{ -1 }{ K }^{ -1 }$$) given for four different reactions. For which reaction will $$\Delta { G }^{ o }$$ increase the most positive) when temperature is increased from $${0}^{o}C$$ to $${25}^{o}C$$?

  • Question 10
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    The standard Gibbs free energy $$\Delta { G }^{ o }$$ is related to equilibrium constant $${K}_{P}$$ as:

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