Self Studies

Thermodynamics ...

TIME LEFT -
  • Question 1
    1 / -0

    $$\Delta_f H^{ \ominus }$$ of hypothetical $$MgCl$$ is $$-125  kJ  mol^{ -1 }$$ and for $$MgCl_2$$ is $$-642  kJ  mol^{ -1 }$$. The enthalpy of disproportionation of $$MgCl$$ is $$-49x$$. Find the value of x.

  • Question 2
    1 / -0

    Calculate $$\Delta_f H^{ \ominus }ICl(g)$$ from the data
    $$\Delta H_{dissociation}Cl_2(g) = 57.9  Kcal  mol^{ -1 }$$
    $$\Delta H_{dissociation}I_2(g) = 36.1  Kcal  mol^{ -1 }$$
    $$\Delta H_{dissociation}ICl(g) = 50.5  Kcal  mol^{ -1 }$$
    $$\Delta H_{dissociation}I_2(g) = 15.0  Kcal  mol^{ -1 }$$ 

  • Question 3
    1 / -0

    Using the enthalpies of formation, calculate the energy (kJ) released when $$3.00  g$$ of $$N{ H }_{ 3\left( g \right)  }$$ reacts according to the following equation?
    (Atomic weights: $$N = 14.00,  H = 1.008$$).
              $$4N{ H }_{ 3 }\left( g \right) +5{ O }_{ 2 }\left( g \right) \longrightarrow 4NO\left( g \right) +6{ H }_{ 2 }O\left( g \right) $$
    $$\Delta HN{ H }_{ 3 }\left( g \right) =-46.1   { kJ }/{ mole }$$
    $$\Delta HNO\left( g \right) =+90.2   { kJ }/{ mole }$$
    $$\Delta H{ H }_{ 2 }O\left( g \right) =-241.8   { kJ }/{ mole }$$

  • Question 4
    1 / -0

    a) Calculate heat of dissociation for Acetic acid from the following data:


    $$CH_3COOH + NaOH\longrightarrow CH_3COONa + H_2O .... \Delta H = -13.2  Kcal$$

    $$H^{ \oplus } + \overset { \ominus }{ O }H\longrightarrow H_2O; .... \Delta H = -13.7  Kcal$$.

    b) calculate heat of dissociation for $$NH_4OH$$ if 

    $$HCl + NH_4OH\longrightarrow NH_4Cl + H_2O; \Delta H = -12.27  Kcal$$.

  • Question 5
    1 / -0

    $$\Delta_f H^{ \ominus }$$ of Cyclohexene $$(l)$$ and benzene at $$25^{ \circ}C$$ is $$-156$$ and $$+46  kJ  mol^{ -1 }$$, respectively. 
    $$\Delta_{ hydrogenation }H^{ \ominus }$$ of Cyclohexene $$(l)$$ at $$25^{ \circ }C$$ is $$-119  kJ  mol^{ -1 }$$.

    Resonance energy of benzene is found to be $$-38x  kJ  mol^{ -1 }$$. Find the value of x.

  • Question 6
    1 / -0

    For the reaction $$X_2O_4(l)\rightarrow 2XO_2(g)$$

    $$\Delta U = 2.1\,Kcal, \Delta S = 20\,cal\,K^{ -1 }\,at\, 300\,K$$ 

    Hence $$\Delta G$$ is:

  • Question 7
    1 / -0

    Determine $${ \Delta H }/{ kJ }$$ for the following reaction using the listed enthalpies of reaction:
    $$4CO\left( g \right) +8{ H }_{ 2 }\left( g \right) \longrightarrow 3C{ H }_{ 4 }\left( g \right) +C{ O }_{ 2 }\left( g \right) +2{ H }_{ 2 }O\left( l \right) $$


    $$C\left( graphite \right) +{ 1 }/{ 2 }{ O }_{ 2 }\left( g \right) \longrightarrow CO\left( g \right) ;                           { \Delta H }/{ kJ }=-110.5kJ$$

    $$CO\left( g \right) +{ 1 }/{ 2 }{ O }_{ 2 }\left( g \right) \longrightarrow C{ O }_{ 2 }\left( g \right)         ;                 { \Delta H }/{ kJ }=-282.9kJ$$

    $${ H }_{ 2 }\left( g \right) +{ 1 }/{ 2 }{ O }_{ 2 }\left( g \right) \longrightarrow { H }_{ 2 }O\left( l \right)        ;                   { \Delta H }/{ kJ }=-285.8kJ$$

    $$C\left( graphite \right) +2{ H }_{ 2 }\left( g \right) \longrightarrow C{ H }_{ 4 }\left( g \right)           ;                       { \Delta H }/{ kJ }=-74.8kJ$$

  • Question 8
    1 / -0

    Use the given standard enthalpies of formation to determine the heat of reaction of the following reaction:
                   $$2LiOH+C{ O }_{ 2 }\left( g \right) \longrightarrow { Li }_{ 2 }C{ O }_{ 3 }\left( s \right) +{ H }_{ 2 }O\ (l)$$
    $$\Delta { H }_{ f }^{ }LiOH\left( s \right) =-487.23{ kJ }/{ mole }$$
    $$\Delta { H }_{ f }^{ }{ Li }_{ 2 }C{ O }_{ 3 }\left( s \right) =-1215.6{ kJ }/{ mole }$$
    $$\Delta { H }_{ f }^{ }{ H }_{ 2 }O\ (l) =-285.85{ kJ }/{ mole }$$
    $$\Delta { H }_{ f }^{ }C{ O }_{ 2 }\left( g \right) =-393.5{ kJ }/{ mole }$$

  • Question 9
    1 / -0

    Determine $$\Delta H$$ of the following reaction using the listed heats of formation:
                   $$4HN{ O }_{ 3 }\left( I \right) +{ P }_{ 4 }{ O }_{ 10 }\left( s \right) \longrightarrow 2{ N }_{ 2 }{ O }_{ 5 }\left( s \right) +4HP{ O }_{ 3 }\left( s \right) $$
    $$\Delta { H }_{ f }^{ }HN{ O }_{ 3 }\left( I \right) =-174.1{ kJ }/{ mole }$$
    $$\Delta { H }_{ f }^{ }{ N }_{ 2 }{ O }_{ 5 }\left( s \right) =-43.1{ kJ }/{ mole }$$
    $$\Delta { H }_{ f }^{ }{ P }_{ 4 }{ O }_{ 10 }\left( s \right) =-2984.0{ kJ }/{ mole }$$
    $$\Delta { H }_{ f }^{ }HP{ O }_{ 3 }\left( s \right) =-948.5{ kJ }/mole$$

  • Question 10
    1 / -0

    Calculate the value of $${ \Delta H }{\ ( kJ) }$$ for the following reaction using the listed thermochemical equations $$2C(s) + H_2(g) \rightarrow C_2H_ 2 (g)$$.

    $$2{ C }_{ 2 }{ H }_{ 2 }\left( g \right) +5{ O }_{ 2 }\left( g \right) \longrightarrow 4C{ O }_{ 2 }\left( g \right) +2{ H }_{ 2 }O\left( l \right)$$ ;     $$\Delta H^o= -2600\ kJ$$
    $$C\left( s \right) +{ O }_{ 2 }\left( g \right) \longrightarrow C{ O }_{ 2 }\left( g \right)$$ ;                                      $$\Delta H^o=-390\ kJ$$
    $$2{ H }_{ 2 }\left( g \right) +{ O }_{ 2 }\left( g \right) \longrightarrow 2{ H }_{ 2 }O\left( l \right)$$ ;                                $$\Delta H^o =-572\ kJ$$

Submit Test
Self Studies
User
Question Analysis
  • Answered - 0

  • Unanswered - 10

  • 1
  • 2
  • 3
  • 4
  • 5
  • 6
  • 7
  • 8
  • 9
  • 10
Submit Test
Selfstudy
Selfstudy
Self Studies Get latest Exam Updates
& Study Material Alerts!
No, Thanks
Self Studies
Click on Allow to receive notifications
Allow Notification
Self Studies
Self Studies Self Studies
To enable notifications follow this 2 steps:
  • First Click on Secure Icon Self Studies
  • Second click on the toggle icon
Allow Notification
Get latest Exam Updates & FREE Study Material Alerts!
Self Studies ×
Open Now