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Thermodynamics ...

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  • Question 1
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    For a particular reaction $$\triangle H^0 = -76.6 KJ$$ and $$\Delta S^0 = 226 JK^{-1}$$. This reaction is:

  • Question 2
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    Given the following data:

    Substance$$\Delta H^{o}(kJ/mol)$$$$\Delta S^{o}(kJ/mol)$$
    $$\Delta G^{o}(kJ/mol)$$
    $$FeO(s)$$$$-266.3$$$$57.49$$$$-245.12$$
    $$C$$(Graphite)$$0$$$$5.74$$$$0$$
    $$Fe(s)$$$$0$$$$27.28$$$$0$$
    $$CO(g)$$$$-110.5$$$$197.6$$$$-137.15$$
    Determine at what temperature the following reaction is spontaneous?
    $$FeO(s)+C(Graphite)\rightarrow Fe(s)+CO(g)$$

  • Question 3
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    For the following concentration cell,to be spontaneous $$Pt({H}_{2}){P}_{1} atm |HCl\ || \ Pt({H}_{2}), {P}_{2} atm$$.

    Which of the following is correct?

  • Question 4
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    The change in entropy of $$2$$ moles of an ideal gas upon isothermal expansion at $$243.6K$$ from $$20$$ litre until the pressure becomes $$1atm$$ is:

  • Question 5
    1 / -0

    Given the following data:

    Substance$$\triangle H^0 (kJ/mol)$$ $$S^0 (J/molK)$$$$\triangle G^0(kJ/mol)$$
    FeO(s)$$-266.3$$$$57.49$$$$-245.12$$
    C(Graphite)0$$5.74$$0
    Fe(s)0$$27.28$$0
    CO(g)$$-110.5$$$$197.6$$$$-137.15$$

    Determine at what temperature the following reaction is spontaneous?
    $$FeO(s) + C(Graphite) \rightarrow Fe(s) + CO(g) $$ 

  • Question 6
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    An intimate of ferric oxide $$({Fe}_{2}{O}_{3})$$ and aluminum (Al) is used as solid rocket fuel. Calculate fuel value per gram of the mixture Heats of formation are as follows: $$\triangle { H }_{ f }\left( { Al }_{ 2 }{ O }_{ 3 } \right) =399\quad kcal/mole$$
    $$\triangle { H }_{ f }\left( { Fe }_{ 2 }{ O }_{ 3 } \right) =199\quad kcal/mole$$

  • Question 7
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    The lattice energy of $$CsI(s)$$ and the enthalpy of solution is $$33\ kJ/mol$$. Calculate the enthalpy of hydration $$(kJ)$$ of 0.65 moles of $$CsI$$.

  • Question 8
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    Heat of reaction for, $$CO(g)+\dfrac{1}{2}{O}_{2}(g)\rightarrow {CO}_{2}(g)$$ at constant $$V$$ is $$-67.71Kcal$$ at $${17}^{o}C$$. The heat of reaction at constant $$P$$ at $${7}^{o}C$$ is :

  • Question 9
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    When two mole of an ideal gas $$\left( { C }_{ p.m }=\cfrac { 5 }{ 2 } R \right) $$ heated from $$300K$$ to $$600K$$ at constant pressure. The change in entropy of gas ($$\Delta S$$) is:

  • Question 10
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    A system changes its state irreversibly at $$300\ K$$ in which it absorbs $$300\ cals$$ of heat. When the same change is carried out reversibly the amount of heat absorbed is $$900\ cals$$. The change in entropy of the system is equal to?

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