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Thermodynamics ...

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  • Question 1
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    $$\Delta { G }^{ o }$$ of the cell reaction $$AgCl(s)+\cfrac { 1 }{ 2 } { H }_{ 2 }(g)=Ag(s)+{ H }^{ + }+{ Cl }^{ - }$$ is $$-21.52kJ$$. $$\Delta { G }^{ o }$$ of
    $$2AgCl(s)+{ H }_{ 2 }(g)=2Ag(s)+2{ H }^{ + }+2{ Cl }^{ - }$$

  • Question 2
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    In which case is a reaction impossible at any temperature?

  • Question 3
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    The equilibrium partial pressure of $$N_2, H_2$$ and $$NH_3$$ are $$4, 4$$ and $$8$$ atm respectively. The value of $$K_p$$ for the Haber's process in $$atm^{-1}$$ is:

  • Question 4
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    For the expression : $$dG = Vdp - SdT,$$ which of the following is correct?

  • Question 5
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    The Gibbs energy for decomposition of $$Al_2O_3$$ at $$500^oC$$ is as follows:
    $$\dfrac {2}{3}Al_2O_3\to \dfrac {4}{3}Al+O_2$$; $$\quad \Delta G=+966\ kJ$$
    The potential difference needed for electrolysis reduction of $$Al_2O_3$$ at $$500^oC$$ is at least 

  • Question 6
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    Directions For Questions

    The contributions of both heat (enthalpy) and randomness (entropy) shall be considered to the overall spontaneity of a process .When deciding about the spontaneity of a chemical reaction or other process, we define a quantity called the Gibb's energy change $$(\Delta G)$$
    $$\Delta G = \Delta H-T\Delta S$$
    where, $$\Delta H$$=Enthalpy change; $$\Delta S$$=Entropy change; T=Temperature in kelvin.
    If $$\Delta G < 0$$,Process is spontaneous; $$\Delta G=0$$, Process is at equilibrium, $$\Delta G > 0$$ , Process is non-spontaneous.

    ...view full instructions

    For the change $$H_2O(s), (273  K, 2 atm) \rightarrow H_2O(l), (273 K, 2 atm)$$, choose the correct option.

  • Question 7
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    $$10 l t$$ box contains $$O_3$$ and $$O_2$$ at equilibrium at $$2000 K$$. The $$\triangle G^o = -534.52 kJ$$ at $$8$$ atm equilibrium pressure. The following equilibrium is present in the container
    $$2O_3(g) \rightleftharpoons 3O_2(g)$$. The partial pressure of $$O_3$$ will be (ln $$10 = 2.3, R = 8.3 J \;\ mole^{-1} K^{-1}$$.

  • Question 8
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    Hess law is based on: 

  • Question 9
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    In a thermodynamic system working subtance is ideal gas, its internal energy is in the from of

  • Question 10
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    For the reaction, $$A_{\left ( s \right )}+3B_{\left ( g \right )}\rightarrow 4C_{\left ( s \right )}+D_{\left ( l \right )}$$.
    $$\Delta H$$ and $$\Delta U$$ are related as:

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