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Equilibrium Test - 3

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Equilibrium Test - 3
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  • Question 1
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    At a given temperature equilibrium is possible only in a system which is a

    Solution

    Equilibrium is possible only in a closed system at a given temperature for physical processes. When equilibrium is attained for a physical process, it is characterized by constant value of one of its parameters at a given temperature.

  • Question 2
    1 / -0

    For liquid ⇌ vapour equilibrium, at a given temperature, the constant is

    Solution

    The vapour pressure is constant at a given temperature for liquid ⇌ vapour equilibrium. The equilibrium vapour pressure of a compound at a given temperature is an intrinsic property of the compound, meaning it does not depend on variables like volume, quantity of the compound, etc.

  • Question 3
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    The aqueous solution of sugar does not conduct electricity. However, when sodium chloride is added to water, it conducts electricity. How will you explain this statement on the basis of ionisation and how is it affected by concentration of sodium chloride?

    Solution

    Sugar being a non-electroyte, does not ionize in water, whereas NaCl ionizes completely in water and produce Na+ and Cl- ions, which help in the conduction of electricity and when concentration of NaCl is increased , more Na+ and Cl- ions will be produced, hence conductance increases.

  • Question 4
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    For dissolution of solids in liquids, at a given temperature, the constant is

    Solution

    It is because at a particular temperature only a certain amount of solute can be dissolved. But it may be increased after increasing the temperature, so the solubility is constant at a given temperature.

  • Question 5
    1 / -0

    For dissolution of gases in liquids, the concentration of a gas in liquid is.

    Solution

    For dissolution of gases in liquids, Henry's Law is applicable i.e. the mass of the gas dissolved in a given solvent at any temperature is proportional to the pressure of the gas above the solvent.

  • Question 6
    1 / -0

    the concentrations in an equilibrium mixture are related by the following equilibrium equation, Kc = [C][D] / [A][B] Where Kc is called as

    Solution

    Let us consider a general reversible reaction:
    A + B ⇌ C + D        
    where A and B are the reactants, C and D are the products in the balanced chemical equation. A + B ⇌ C + D
    On the basis of experimental studies of many reversible reactions, oposed in 1864 that the concentrations in an equilibrium mixture are related by the following equilibrium equation, Kc = [C] [D] /[A] [B]
    Where Kc is the equilibrium constant and the expression on the right side is called the equilibrium constant expression

  • Question 7
    1 / -0

    If the Kc is neither too small nor too large, one of the following will happen

    Solution

    A High value of K is high concentration of products.

    If Kc > 103 , products predominate over reactants,

    • If Kc < 10–3, reactants predominate over products, i.e., if Kc is very small, the reaction proceeds rarely.
    • If Kc is in the range of 10– 3 to 103 , appreciable concentrations of both reactants and products are present.

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