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Equilibrium Tes...

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  • Question 1
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    For the reaction $$PCl_{5}(g) \rightleftharpoons PCl_{3}(g)+Cl_{2}(g)$$, the forward reaction at constant temperature is favoured by: 

  • Question 2
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    The solubility of $$AgI$$ in $$NaI$$ solution is less than that in pure water because

  • Question 3
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    The exothermic formation of $$ ClF_{3}$$ is represented by the equation: $$\displaystyle Cl_{2}(g)+3F_{2}(g)\rightleftharpoons 2ClF_{3}(g), \Delta H=-329$$ kJ
    Which of the following will increase the quantity of $$ClF_{3}$$ in an equilibrium mixture of $$Cl_{2},F_{2}$$ and $$ClF_{3}$$?

  • Question 4
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    What is the percent ionization $$(\alpha)$$ of a $$0.01M$$ $$HA$$ solution?
    (Given that $$K_a = 10^{-4}$$)

  • Question 5
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    What is the effect of the reduction of the volume of the system for the following equilibrium?

    $$2C(s)+O_{2}(g)\rightleftharpoons 2CO(g)$$

  • Question 6
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    The value of the ion product constant for water, $$(K_w)$$ at $$60^{\small\circ}C$$ is $$9.6\times10^{-14}\, M^2$$. What is the $$[H_3O^+]$$ of a neutral aqueous solution at $$60^{\small\circ}C$$ and the nature of an aqueous solution with a $$pH = 7.0$$ at $$60^{\small\circ}C$$ are respectively?

  • Question 7
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    Following two equilibrium is simultaneously established in a container: $$\displaystyle PCl_{5}(g)\rightleftharpoons PCl_{3}(g)+ Cl_{2}(g)$$ and  $$CO(g)+ Cl_{2}(g) \rightleftharpoons COCl_{2}(g)$$
    If some Ni(s) is introduced in the container forming 
    $$Ni(CO)_{4}$$(g), then at new equilibrium:

  • Question 8
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    If first dissociation of $$X(OH)_3$$ is $$100\mbox{%}$$ whereas second dissociation is $$50\mbox{%}$$ and third dissociation is negligible then the $$pH$$ of $$4\times10^{-3}\space M\space X(OH)_3$$ is :

  • Question 9
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    Which of the following expressions for $$\mbox{%}$$ ionization of a monoacidic base $$(BOH)$$ in aqueous solution is not correct at appreciable concentration?

  • Question 10
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    For the equilibrium,
    $$LiCl\cdot { 3NH }_{ 3 }(s)\rightleftharpoons LiCl\cdot { NH }_{ 3 }(s)+2{ NH }_{ 3 }(g)\quad $$ $${ K }_{ p }=9{ atm }^{ 2 }$$ at $${ 37 }^{ o }C$$. 

    A $$5$$ litre vessel contains $$0.1$$ mole of $$LiCl\cdot { 3NH }_{ 3 }$$. How many moles of $${ NH }_{ 3 }$$ should be added to the flask at this temperature to derive the backward reaction for completion?
    $$R=0.082 \ atm.L/molK$$

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