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Equilibrium Tes...

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    Directions For Questions

    Physical and chemical equilibrium can respond to a change in their pressure, temperature, and concentration of reactants and products. To describe the change in the equilibrium we have a principle named Le Chatelier's principle. According to this principle, even if we make some changes in equilibrium, then also the system even re-establishes the equilibrium by undoing the effect.

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    Consider the following equilibrium: $$2NO_2\rightleftharpoons 2NO_3; \Delta H=-ve$$ If $$O_2$$ is added and volume of there action vessel is reduced, the equilibrium

  • Question 2
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    If the equilibrium constant of $$BOH \rightleftharpoons B^{\oplus}+\overset{\circleddash}{O}H$$ at $$25^oC$$ is $$2.5\times 10^{-6}$$, then equilibrium constant for $$BOH + H^{\oplus} \rightleftharpoons  B^{\oplus}+H_2O$$ at the same temperature is

  • Question 3
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    $$16.6  mg$$ of solid silver chromate (molar mass = $$332$$) when put into $$500  mL$$ water, silver ion and chromate ion are obtained. On adding more solid, the concentration of ions does not increase. If $$100 mg$$ of solid is put into 2 litres of water, then the amount of solid remained undissociated would be :

  • Question 4
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    Which statement/relationship is correct?

  • Question 5
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    Which of the following factor shifted the reaction, $$PCl_3 + Cl_2\rightleftharpoons PCl_5$$ at left side?

  • Question 6
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    If $$0.00050$$ mol $$NaH{CO}_{3}$$ is added to $$1$$ litre of a buffered solution of $$pH\ 8$$, then how much material will exist in each of the three forms $${H}_{2}{CO}_{3},H{CO}_{3}^{-}$$ and $${CO}_{3}^{2-}$$? 

    For $${H}_{2}{CO}_{3}$$, $${K}_{1}=5\times {10}^{-7}$$; $${K}_{2}=5\times {10}^{-13}$$

  • Question 7
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    The equilibrium, $$SO_2Cl_2 \:(g)\rightleftharpoons SO_2 \:(g) + Cl_2 \:(g)$$ is attained at $$25 ^{\circ}\! C$$ in a closed container and an inert gas, helium, is introduced. Which of the following statements is correct?

  • Question 8
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    Calculate the $${OH}^{-}$$ concentration and the $${H}_{3}{PO}_{4}$$ concentration of a solution prepared by dissolving $$0.1$$ mol of $${Na}_{3}{PO}_{4}$$ in sufficient water to make $$1L$$ of solution.

    $${K}_{1}=7.1\times {10}^{-3}$$, $${K}_{2}=6.3\times {10}^{-8}$$; $${K}_{3}=4.5\times {10}^{-13}$$

  • Question 9
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    Ammonia is the weak base that reacts with water according to the equation:

    $$NH_3(aq)+H_2O(l)⇌NH_4^+(aq)+OH^-(aq) $$

    Will any of the following increase the per cent of ammonia that is converted to the ammonium ion in water?

  • Question 10
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    $$EDTA,$$ often abbreviated as $${H}_{4}Y$$, forms very stable complexes with almost all metal ions. Calculate the fraction of EDTA in the fully protonated form, $${H}_{4}Y$$ in a solution obtained by dissolving $$0.1$$ mol $${Na}_{4}Y$$ in $$1$$ litre. 

    Given, the acid dissociation constants of $${H}_{4}Y$$ are as follows:
    $${k}_{1}=1.02\times {10}^{-2}$$, $${k}_{2}=2.13\times {10}^{-3}$$, $${k}_{3}=6.92\times {10}^{-7}$$; $${k}_{4}=5.50\times {10}^{-11}$$

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