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Equilibrium Tes...

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  • Question 1
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    (A) If water is heated to 350 K, then pOH will increase to 8.
    (R) $$K_w$$ increases with increase in temperature.

  • Question 2
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    Which of the following is not true for the equilibrium reaction? $$N_2(h)+O_2(g)\rightleftharpoons 2NO(g); \Delta H=180$$kJ $$mol^{-1}$$.

  • Question 3
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    Consider the following equilibrium system; $$SO_2(g)+\displaystyle\frac{1}{2}O_2(g)\rightleftharpoons SO_3(g)$$; set up in a cylinder fitted with a piston. Some inert gas is added and the piston is moved outwards to keep the total gaseous pressure constant. Predict which of the following is true?

  • Question 4
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    Which of the following would dissolve $$Pb(OH)_{2}$$ more than pure water?

  • Question 5
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    The exothermic formation of $$ClF_{3}$$ is represented by the equation:
    $$Cl_{2}(g) + 3F_{2}(g) \rightleftharpoons 2ClF_{3}(g); \triangle H_{r} = -329\ kJ$$

    which of the following will increase the quantity of $$ClF_{3}$$ in an equilibrium mixture of $$Cl_{2}, F_{2}$$ and $$ClF_{3}$$?

  • Question 6
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    Which of the following does not contribute towards the formation of photochemical smog ?

  • Question 7
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    Solid ammonium carbonate dissociates as:$${ NH }_{ 2 }COO{ NH }_{ 4 }(s)\rightleftharpoons 2{ NH }_{ 3 }(g)+{ CO }_{ 2 }(g)$$. In a closed vessel solid ammonium carbonate is in equilibrium with its dissociation products. At equilibrium, ammonia is added such that the partial pressure of $${NH}_{3}$$ at new equilibrium now equals the original total pressure. Calculate the ratio of total pressure at new equilibrium to that of original total pressure.

  • Question 8
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    The exothermic formation of $$Cl{F}_{3}$$ is represented by the equation:

    $${ Cl }_{ 2(g) }+2{ F }_{ 2(g) }\rightleftharpoons 2Cl{ F }_{ 3(g) };\Delta { H }_{ r }=-329kJ\quad $$

    Which of the following will increase the quantity of $$Cl{F}_{3}$$ in an equilibrium mixture of $${Cl}_{2},{F}_{2}$$ and $$Cl{F}_{3}$$?

  • Question 9
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    The reaction, $$ZnO(s)+CO(g)\rightleftharpoons Zn(g)+{ CO }_{ 2 }(g)$$ has an equilibrium constant of $$1$$ atm at $$1500K$$. The equilibrium partial pressure of zinc vapour in a reaction vessel if an equimolar mixture of $$CO$$ and $${CO}_{2}$$ is brought into contact with solid $$ZnO$$ at $$1500K$$ and the equilibrium is achieved at $$1$$ atm is?

  • Question 10
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    In which one of the following equilibria, the increase of pressure over the equilibrium will favour the backward reaction?

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